Effect of the Heating Rate on the Spark-Plasma-Sintering (SPS) of Transparent Y<sub>2</sub>O<sub>3</sub> Ceramics: Microstructural Evolution, Mechanical and Optical Properties

High strength transparent Y<sub>2</sub>O<sub>3</sub> ceramics were fabricated from commercial powders using spark plasma sintering (SPS) technique by optimizing the heating rate. The heating rate significantly influenced the microstructures and the optical/mechanical properti...

Full description

Bibliographic Details
Main Authors: Lihong Liu, Koji Morita, Tohru S. Suzuki, Byung-Nam Kim
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Ceramics
Subjects:
Online Access:https://www.mdpi.com/2571-6131/4/1/6
Description
Summary:High strength transparent Y<sub>2</sub>O<sub>3</sub> ceramics were fabricated from commercial powders using spark plasma sintering (SPS) technique by optimizing the heating rate. The heating rate significantly influenced the microstructures and the optical/mechanical properties of the Y<sub>2</sub>O<sub>3</sub> ceramics. Grain growth was limited accordingly with increasing the heating rate. The ball milling process of the commercial Y<sub>2</sub>O<sub>3</sub> powders is likely to further enhance the sinterability during the SPS processing. The dense Y<sub>2</sub>O<sub>3</sub> ceramics, which were sintered by SPS with 100 °C/min, showed good transmittance range from visible to near infrared (IR). For a high heating rate of 100 °C/min, the in-line transmittance at a visible wavelength of 700 nm was 66%, whereas for a slow heating rate of 10 °C/min, it reduced to 46%. The hardness <i>H<sub>v</sub></i> tends to increase with increasing the heating rate and rigorously followed the Hall–Petch relationship; that is, it is enhanced with a reduction of the grain size. The toughness <i>K<sub>IC</sub></i>, on the other hand, is less sensitive to both the heating rate and the grain size, and takes a similar value. This research highlighted that the high heating rate SPS processing can fabricate fully dense fine-grained Y<sub>2</sub>O<sub>3</sub> ceramics with the excellent optical and mechanical properties.
ISSN:2571-6131