Advances and Challenges in the Creation of Porous Metal Phosphonates
In the expansive world of porous hybrid materials, a category of materials that has been rather less explored than others and is gaining attention in development is the porous metal phosphonates. They offer promising features towards applications which demand control over the inorganic–organic netwo...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-11-01
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| Series: | Materials |
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| Online Access: | https://www.mdpi.com/1996-1944/13/23/5366 |
| _version_ | 1797546736743350272 |
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| author | Bharadwaj Mysore Ramesha Vera Meynen |
| author_facet | Bharadwaj Mysore Ramesha Vera Meynen |
| author_sort | Bharadwaj Mysore Ramesha |
| collection | DOAJ |
| description | In the expansive world of porous hybrid materials, a category of materials that has been rather less explored than others and is gaining attention in development is the porous metal phosphonates. They offer promising features towards applications which demand control over the inorganic–organic network and interface, which is critical for adsorption, catalysis and functional devices and technology. The need to establish a rationale for new synthesis approaches to make these materials in a controlled manner is by itself an important motivation for material chemists. In this review, we highlight the various synthetic strategies exploited, discussing various metal phosphonate systems and how they influence the properties of porous metal phosphonates. We discuss porous metal phosphonate systems based on transition metals with an emphasis on addressing challenges with tetravalent metals. Finally, this review provides a brief description of some key areas of application that are ideally suited for porous metal phosphonates. |
| first_indexed | 2024-03-10T14:33:28Z |
| format | Article |
| id | doaj.art-e0d7bf3ef7b4446a8e4234bb286814cf |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-10T14:33:28Z |
| publishDate | 2020-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-e0d7bf3ef7b4446a8e4234bb286814cf2023-11-20T22:25:54ZengMDPI AGMaterials1996-19442020-11-011323536610.3390/ma13235366Advances and Challenges in the Creation of Porous Metal PhosphonatesBharadwaj Mysore Ramesha0Vera Meynen1Laboratory of Adsorption and Catalysis (LADCA), Department of Chemistry, University of Antwerp, Universiteitsplein 1, 2610 Wilrijk, BelgiumLaboratory of Adsorption and Catalysis (LADCA), Department of Chemistry, University of Antwerp, Universiteitsplein 1, 2610 Wilrijk, BelgiumIn the expansive world of porous hybrid materials, a category of materials that has been rather less explored than others and is gaining attention in development is the porous metal phosphonates. They offer promising features towards applications which demand control over the inorganic–organic network and interface, which is critical for adsorption, catalysis and functional devices and technology. The need to establish a rationale for new synthesis approaches to make these materials in a controlled manner is by itself an important motivation for material chemists. In this review, we highlight the various synthetic strategies exploited, discussing various metal phosphonate systems and how they influence the properties of porous metal phosphonates. We discuss porous metal phosphonate systems based on transition metals with an emphasis on addressing challenges with tetravalent metals. Finally, this review provides a brief description of some key areas of application that are ideally suited for porous metal phosphonates.https://www.mdpi.com/1996-1944/13/23/5366hybrid porous materialslayered metal phosphonatesphosphonate MOFssupramolecular-templated porous metal phosphonatesseparation and extractionheterogeneous catalysis |
| spellingShingle | Bharadwaj Mysore Ramesha Vera Meynen Advances and Challenges in the Creation of Porous Metal Phosphonates Materials hybrid porous materials layered metal phosphonates phosphonate MOFs supramolecular-templated porous metal phosphonates separation and extraction heterogeneous catalysis |
| title | Advances and Challenges in the Creation of Porous Metal Phosphonates |
| title_full | Advances and Challenges in the Creation of Porous Metal Phosphonates |
| title_fullStr | Advances and Challenges in the Creation of Porous Metal Phosphonates |
| title_full_unstemmed | Advances and Challenges in the Creation of Porous Metal Phosphonates |
| title_short | Advances and Challenges in the Creation of Porous Metal Phosphonates |
| title_sort | advances and challenges in the creation of porous metal phosphonates |
| topic | hybrid porous materials layered metal phosphonates phosphonate MOFs supramolecular-templated porous metal phosphonates separation and extraction heterogeneous catalysis |
| url | https://www.mdpi.com/1996-1944/13/23/5366 |
| work_keys_str_mv | AT bharadwajmysoreramesha advancesandchallengesinthecreationofporousmetalphosphonates AT verameynen advancesandchallengesinthecreationofporousmetalphosphonates |