A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates
Abstract Metalloligands provide a potent strategy for manipulating the surface metal arrangements of metal nanoclusters, but their synthesis and subsequent installation onto metal nanoclusters remains a significant challenge. Herein, two atomically precise silver nanoclusters {Ag14[(TC4A)6(V9O16)](C...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2023-08-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-023-41050-x |
| _version_ | 1797557906443337728 |
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| author | Zhi Wang Yan-Jie Zhu Bao-Liang Han Yi-Zhi Li Chen-Ho Tung Di Sun |
| author_facet | Zhi Wang Yan-Jie Zhu Bao-Liang Han Yi-Zhi Li Chen-Ho Tung Di Sun |
| author_sort | Zhi Wang |
| collection | DOAJ |
| description | Abstract Metalloligands provide a potent strategy for manipulating the surface metal arrangements of metal nanoclusters, but their synthesis and subsequent installation onto metal nanoclusters remains a significant challenge. Herein, two atomically precise silver nanoclusters {Ag14[(TC4A)6(V9O16)](CyS)3} (Ag14) and {Ag43S[(TC4A)2(V4O9)]3(CyS)9(PhCOO)3Cl3(SO4)4(DMF)3·6DMF} (Ag43) are synthesized by controlling reaction temperature (H4TC4A = p-tert-butylthiacalix[4]arene). Interestingly, the 3D scaffold-like [(TC4A)6(V9O16)]11- metalloligand in Ag14 and 1D arcuate [(TC4A)2(V4O9)]6 - metalloligand in Ag43 exhibit a dual role that is the internal polyoxovanadates as anion template and the surface TC4A4- as the passivating agent. Furthermore, the thermal-induced structure transformation between Ag14 and Ag43 is achieved based on the temperature-dependent assembly process. Ag14 shows superior photothermal conversion performance than Ag43 in solid state indicating its potential for remote laser ignition. Here, we show the potential of two thiacalix[4]arene modified polyoxovanadates metalloligands in the assembly of metal nanoclusters and provide a cornerstone for the remote laser ignition applications of silver nanoclusters. |
| first_indexed | 2024-03-10T17:23:51Z |
| format | Article |
| id | doaj.art-e0e88301398b49c3a2d9644ad0c4e43c |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-03-10T17:23:51Z |
| publishDate | 2023-08-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-e0e88301398b49c3a2d9644ad0c4e43c2023-11-20T10:16:40ZengNature PortfolioNature Communications2041-17232023-08-0114111010.1038/s41467-023-41050-xA route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadatesZhi Wang0Yan-Jie Zhu1Bao-Liang Han2Yi-Zhi Li3Chen-Ho Tung4Di Sun5School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong UniversitySchool of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong UniversitySchool of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong UniversitySchool of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong UniversitySchool of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong UniversitySchool of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong UniversityAbstract Metalloligands provide a potent strategy for manipulating the surface metal arrangements of metal nanoclusters, but their synthesis and subsequent installation onto metal nanoclusters remains a significant challenge. Herein, two atomically precise silver nanoclusters {Ag14[(TC4A)6(V9O16)](CyS)3} (Ag14) and {Ag43S[(TC4A)2(V4O9)]3(CyS)9(PhCOO)3Cl3(SO4)4(DMF)3·6DMF} (Ag43) are synthesized by controlling reaction temperature (H4TC4A = p-tert-butylthiacalix[4]arene). Interestingly, the 3D scaffold-like [(TC4A)6(V9O16)]11- metalloligand in Ag14 and 1D arcuate [(TC4A)2(V4O9)]6 - metalloligand in Ag43 exhibit a dual role that is the internal polyoxovanadates as anion template and the surface TC4A4- as the passivating agent. Furthermore, the thermal-induced structure transformation between Ag14 and Ag43 is achieved based on the temperature-dependent assembly process. Ag14 shows superior photothermal conversion performance than Ag43 in solid state indicating its potential for remote laser ignition. Here, we show the potential of two thiacalix[4]arene modified polyoxovanadates metalloligands in the assembly of metal nanoclusters and provide a cornerstone for the remote laser ignition applications of silver nanoclusters.https://doi.org/10.1038/s41467-023-41050-x |
| spellingShingle | Zhi Wang Yan-Jie Zhu Bao-Liang Han Yi-Zhi Li Chen-Ho Tung Di Sun A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates Nature Communications |
| title | A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates |
| title_full | A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates |
| title_fullStr | A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates |
| title_full_unstemmed | A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates |
| title_short | A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates |
| title_sort | route to metalloligands consolidated silver nanoclusters by grafting thiacalix 4 arene onto polyoxovanadates |
| url | https://doi.org/10.1038/s41467-023-41050-x |
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