Optimal Condition of DME Production Through Syngas Hydrogenation in Dual Membrane Reactor
Typically, supporting the dimethyl ether synthesis reactor by hydrogen and steam permselective membrane modules and optimization of operating conditions are practical solutions to shift the equilibrium conversion of reactions toward dimethyl ether synthesis and CO2 conversion. In this regard, the ai...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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University of Tehran
2023-06-01
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| Series: | Journal of Chemical and Petroleum Engineering |
| Subjects: | |
| Online Access: | https://jchpe.ut.ac.ir/article_91144.html |
| _version_ | 1797736106829021184 |
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| author | Farsi,Mohammad Hallajsani, Ahmad |
| author_facet | Farsi,Mohammad Hallajsani, Ahmad |
| author_sort | Farsi,Mohammad |
| collection | DOAJ |
| description | Typically, supporting the dimethyl ether synthesis reactor by hydrogen and steam permselective membrane modules and optimization of operating conditions are practical solutions to shift the equilibrium conversion of reactions toward dimethyl ether synthesis and CO2 conversion. In this regard, the aim of this research is to calculate the desired condition of hydrogen and steam Selective membrane reactors to improve dimethyl ether productivity. At first, the mass and energy conservation laws are applied to the membrane supported reactor to develop a heterogeneous model. After model validation, an optimization problem is programmed to calculate the optimal value of manipulated variables considering the limitations and constraints of the problem. Then, the main parameters of conventional and optimized membrane supported reactor including carbon monoxide and carbon dioxide conversion, dimethyl ether productivity, and temperature profiles are presented at steady-state conditions. The results of the simulation prove that dimethyl ether productivity is 0.0211 and 0.0262 mole s-1 in conventional and optimized membrane reactors, respectively. In general, operating at optimal conditions increases DME production by up to 24.2%. |
| first_indexed | 2024-03-12T13:08:49Z |
| format | Article |
| id | doaj.art-e0f66be1b18f4e538bf241c32e248fd0 |
| institution | Directory Open Access Journal |
| issn | 2423-673X 2423-6721 |
| language | English |
| last_indexed | 2024-03-12T13:08:49Z |
| publishDate | 2023-06-01 |
| publisher | University of Tehran |
| record_format | Article |
| series | Journal of Chemical and Petroleum Engineering |
| spelling | doaj.art-e0f66be1b18f4e538bf241c32e248fd02023-08-28T10:19:59ZengUniversity of TehranJournal of Chemical and Petroleum Engineering2423-673X2423-67212023-06-01571117810.22059/JCHPE.2023.314400.1338Optimal Condition of DME Production Through Syngas Hydrogenation in Dual Membrane Reactor Farsi,Mohammad0https://orcid.org/0000-0003-2531-5693 Hallajsani, Ahmad1https://orcid.org/0000-0003-3793-9129Department of Chemical Engineering, School of Chemical and Petroleum Engineering, Shiraz University, Shiraz, Iran.School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran.Typically, supporting the dimethyl ether synthesis reactor by hydrogen and steam permselective membrane modules and optimization of operating conditions are practical solutions to shift the equilibrium conversion of reactions toward dimethyl ether synthesis and CO2 conversion. In this regard, the aim of this research is to calculate the desired condition of hydrogen and steam Selective membrane reactors to improve dimethyl ether productivity. At first, the mass and energy conservation laws are applied to the membrane supported reactor to develop a heterogeneous model. After model validation, an optimization problem is programmed to calculate the optimal value of manipulated variables considering the limitations and constraints of the problem. Then, the main parameters of conventional and optimized membrane supported reactor including carbon monoxide and carbon dioxide conversion, dimethyl ether productivity, and temperature profiles are presented at steady-state conditions. The results of the simulation prove that dimethyl ether productivity is 0.0211 and 0.0262 mole s-1 in conventional and optimized membrane reactors, respectively. In general, operating at optimal conditions increases DME production by up to 24.2%.https://jchpe.ut.ac.ir/article_91144.htmldmedual membrane reactorheterogeneous modelingprocess optimization |
| spellingShingle | Farsi,Mohammad Hallajsani, Ahmad Optimal Condition of DME Production Through Syngas Hydrogenation in Dual Membrane Reactor Journal of Chemical and Petroleum Engineering dme dual membrane reactor heterogeneous modeling process optimization |
| title | Optimal Condition of DME Production Through Syngas Hydrogenation in Dual Membrane Reactor |
| title_full | Optimal Condition of DME Production Through Syngas Hydrogenation in Dual Membrane Reactor |
| title_fullStr | Optimal Condition of DME Production Through Syngas Hydrogenation in Dual Membrane Reactor |
| title_full_unstemmed | Optimal Condition of DME Production Through Syngas Hydrogenation in Dual Membrane Reactor |
| title_short | Optimal Condition of DME Production Through Syngas Hydrogenation in Dual Membrane Reactor |
| title_sort | optimal condition of dme production through syngas hydrogenation in dual membrane reactor |
| topic | dme dual membrane reactor heterogeneous modeling process optimization |
| url | https://jchpe.ut.ac.ir/article_91144.html |
| work_keys_str_mv | AT farsimohammad optimalconditionofdmeproductionthroughsyngashydrogenationindualmembranereactor AT hallajsaniahmad optimalconditionofdmeproductionthroughsyngashydrogenationindualmembranereactor |