Aqua[1,3-bis(benzimidazol-2-yl)-2-oxapropane]diethanolmanganese(II) dipicrate ethanol disolvate
In the title complex, [Mn(C16H14N4O)(C2H5OH)2(H2O)](C6H2N3O7)2·2C2H5OH, the MnII ion is in a distorted octahedral coordination environment, defined by an MnN2O4 donor set. The 1,3-bis(benzimidazol-2-yl)-2-oxapropane ligand is tridentate. In the crystal structure, intermolecular N&am...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-09-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810030357 |
| Summary: | In the title complex, [Mn(C16H14N4O)(C2H5OH)2(H2O)](C6H2N3O7)2·2C2H5OH, the MnII ion is in a distorted octahedral coordination environment, defined by an MnN2O4 donor set. The 1,3-bis(benzimidazol-2-yl)-2-oxapropane ligand is tridentate. In the crystal structure, intermolecular N—H...O and O—H...O hydrogen bonds link the components into a three-dimensional network. The O atoms of one of the nitro groups are disordered over two sets of sites with refined occupancies of 0.577 (11) and 0.423 (11). |
|---|---|
| ISSN: | 1600-5368 |