{4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ2N′,O}dimethyltin(IV)
Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH3)2(C18H12N2O3)]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C2NO2 donor set defines a coordination geometry i...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810027078 |
| _version_ | 1819279920049684480 |
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| author | Md. Abu Affan Norrihan B. Sam Fasihuddin B. Ahmad Edward R. T. Tiekink |
| author_facet | Md. Abu Affan Norrihan B. Sam Fasihuddin B. Ahmad Edward R. T. Tiekink |
| author_sort | Md. Abu Affan |
| collection | DOAJ |
| description | Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH3)2(C18H12N2O3)]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C2NO2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-pyramidal, with a small tendency towards the former. Zigzag chains running along the a axis mediated by O—H...N hydrogen bonding characterize the crystal packing. These are connected into layers in the ab plane by a combination of C—H...N and π–π [centroid–centroid distances = 3.658 (2) and 3.6740 (18) Å] interactions. The layers are connected along the c axis via C—H...O interactions. |
| first_indexed | 2024-12-24T00:35:34Z |
| format | Article |
| id | doaj.art-e138e76fda60452ea5ae27d5db98e6c5 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:35:34Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e138e76fda60452ea5ae27d5db98e6c52022-12-21T17:24:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m924m92410.1107/S1600536810027078{4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ2N′,O}dimethyltin(IV)Md. Abu AffanNorrihan B. SamFasihuddin B. AhmadEdward R. T. TiekinkTwo independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH3)2(C18H12N2O3)]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C2NO2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-pyramidal, with a small tendency towards the former. Zigzag chains running along the a axis mediated by O—H...N hydrogen bonding characterize the crystal packing. These are connected into layers in the ab plane by a combination of C—H...N and π–π [centroid–centroid distances = 3.658 (2) and 3.6740 (18) Å] interactions. The layers are connected along the c axis via C—H...O interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536810027078 |
| spellingShingle | Md. Abu Affan Norrihan B. Sam Fasihuddin B. Ahmad Edward R. T. Tiekink {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ2N′,O}dimethyltin(IV) Acta Crystallographica Section E |
| title | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ2N′,O}dimethyltin(IV) |
| title_full | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ2N′,O}dimethyltin(IV) |
| title_fullStr | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ2N′,O}dimethyltin(IV) |
| title_full_unstemmed | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ2N′,O}dimethyltin(IV) |
| title_short | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ2N′,O}dimethyltin(IV) |
| title_sort | 4 hydroxy n amp 8242 2 oxido 1 naphthyl amp 954 o methylidene benzohydrazidato amp 954 2n amp 8242 o dimethyltin iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810027078 |
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