Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy Monitoring

Conventional wastewater treatment generates large amounts of organic matter–rich sludge that requires adequate treatment to avoid public health and environmental problems. The mixture of wastewater sludge and some bulking agents produces a biosolid to be composted at adequate composting facilities....

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Main Authors: Beatriz Temporal-Lara, Ignacio Melendez-Pastor, Ignacio Gómez, Jose Navarro-Pedreño
Format: Article
Language:English
Published: MDPI AG 2016-11-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/16/11/1919
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author Beatriz Temporal-Lara
Ignacio Melendez-Pastor
Ignacio Gómez
Jose Navarro-Pedreño
author_facet Beatriz Temporal-Lara
Ignacio Melendez-Pastor
Ignacio Gómez
Jose Navarro-Pedreño
author_sort Beatriz Temporal-Lara
collection DOAJ
description Conventional wastewater treatment generates large amounts of organic matter–rich sludge that requires adequate treatment to avoid public health and environmental problems. The mixture of wastewater sludge and some bulking agents produces a biosolid to be composted at adequate composting facilities. The composting process is chemically and microbiologically complex and requires an adequate aeration of the biosolid (e.g., with a turner machine) for proper maturation of the compost. Adequate (near) real-time monitoring of the compost maturity process is highly difficult and the operation of composting facilities is not as automatized as other industrial processes. Spectroscopic analysis of compost samples has been successfully employed for compost maturity assessment but the preparation of the solid compost samples is difficult and time-consuming. This manuscript presents a methodology based on a combination of a less time-consuming compost sample preparation and ultraviolet, visible and short-wave near-infrared spectroscopy. Spectroscopic measurements were performed with liquid compost extract instead of solid compost samples. Partial least square (PLS) models were developed to quantify chemical fractions commonly employed for compost maturity assessment. Effective regression models were obtained for total organic matter (residual predictive deviation—RPD = 2.68), humification ratio (RPD = 2.23), total exchangeable carbon (RPD = 2.07) and total organic carbon (RPD = 1.66) with a modular and cost-effective visible and near infrared (VNIR) spectroradiometer. This combination of a less time-consuming compost sample preparation with a versatile sensor system provides an easy-to-implement, efficient and cost-effective protocol for compost maturity assessment and near-real-time monitoring.
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spelling doaj.art-e15c50e3e16f4b7e9c6061a9b58e8dfa2022-12-22T04:21:08ZengMDPI AGSensors1424-82202016-11-011611191910.3390/s16111919s16111919Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy MonitoringBeatriz Temporal-Lara0Ignacio Melendez-Pastor1Ignacio Gómez2Jose Navarro-Pedreño3Department of Agrochemistry and Environment, University Miguel Hernández of Elche (UMH), Avenida Universidad s/n Edificio Alcudia, 03202 Elche, SpainDepartment of Agrochemistry and Environment, University Miguel Hernández of Elche (UMH), Avenida Universidad s/n Edificio Alcudia, 03202 Elche, SpainDepartment of Agrochemistry and Environment, University Miguel Hernández of Elche (UMH), Avenida Universidad s/n Edificio Alcudia, 03202 Elche, SpainDepartment of Agrochemistry and Environment, University Miguel Hernández of Elche (UMH), Avenida Universidad s/n Edificio Alcudia, 03202 Elche, SpainConventional wastewater treatment generates large amounts of organic matter–rich sludge that requires adequate treatment to avoid public health and environmental problems. The mixture of wastewater sludge and some bulking agents produces a biosolid to be composted at adequate composting facilities. The composting process is chemically and microbiologically complex and requires an adequate aeration of the biosolid (e.g., with a turner machine) for proper maturation of the compost. Adequate (near) real-time monitoring of the compost maturity process is highly difficult and the operation of composting facilities is not as automatized as other industrial processes. Spectroscopic analysis of compost samples has been successfully employed for compost maturity assessment but the preparation of the solid compost samples is difficult and time-consuming. This manuscript presents a methodology based on a combination of a less time-consuming compost sample preparation and ultraviolet, visible and short-wave near-infrared spectroscopy. Spectroscopic measurements were performed with liquid compost extract instead of solid compost samples. Partial least square (PLS) models were developed to quantify chemical fractions commonly employed for compost maturity assessment. Effective regression models were obtained for total organic matter (residual predictive deviation—RPD = 2.68), humification ratio (RPD = 2.23), total exchangeable carbon (RPD = 2.07) and total organic carbon (RPD = 1.66) with a modular and cost-effective visible and near infrared (VNIR) spectroradiometer. This combination of a less time-consuming compost sample preparation with a versatile sensor system provides an easy-to-implement, efficient and cost-effective protocol for compost maturity assessment and near-real-time monitoring.http://www.mdpi.com/1424-8220/16/11/1919wastewater sludgebiosolid compostspectroscopyPLS
spellingShingle Beatriz Temporal-Lara
Ignacio Melendez-Pastor
Ignacio Gómez
Jose Navarro-Pedreño
Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy Monitoring
Sensors
wastewater sludge
biosolid compost
spectroscopy
PLS
title Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy Monitoring
title_full Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy Monitoring
title_fullStr Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy Monitoring
title_full_unstemmed Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy Monitoring
title_short Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy Monitoring
title_sort wastewater biosolid composting optimization based on uv vnir spectroscopy monitoring
topic wastewater sludge
biosolid compost
spectroscopy
PLS
url http://www.mdpi.com/1424-8220/16/11/1919
work_keys_str_mv AT beatriztemporallara wastewaterbiosolidcompostingoptimizationbasedonuvvnirspectroscopymonitoring
AT ignaciomelendezpastor wastewaterbiosolidcompostingoptimizationbasedonuvvnirspectroscopymonitoring
AT ignaciogomez wastewaterbiosolidcompostingoptimizationbasedonuvvnirspectroscopymonitoring
AT josenavarropedreno wastewaterbiosolidcompostingoptimizationbasedonuvvnirspectroscopymonitoring