Regulating Circularly Polarized Light Detection via Polar‐Phase Transition in Alternating Chiral‐Achiral Cations Intercalation‐Type Hybrid Perovskites
Abstract Circularly polarized light (CPL) detection has wide applications in many fields, where the anisotropy factor (gIph) is an important indicator to characterize the CPL detection performance. So far, many materials with high gIph have been reported, however, the exploration of the regulation o...
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| Format: | Article |
| Language: | English |
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Wiley
2024-02-01
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| Series: | Advanced Science |
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| Online Access: | https://doi.org/10.1002/advs.202307593 |
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| author | Zeng‐Kui Zhu Tingting Zhu Shihai You Panpan Yu Jianbo Wu Ying Zeng Yuhang Jiang Xitao Liu Lina Li Chengmin Ji Junhua Luo |
| author_facet | Zeng‐Kui Zhu Tingting Zhu Shihai You Panpan Yu Jianbo Wu Ying Zeng Yuhang Jiang Xitao Liu Lina Li Chengmin Ji Junhua Luo |
| author_sort | Zeng‐Kui Zhu |
| collection | DOAJ |
| description | Abstract Circularly polarized light (CPL) detection has wide applications in many fields, where the anisotropy factor (gIph) is an important indicator to characterize the CPL detection performance. So far, many materials with high gIph have been reported, however, the exploration of the regulation of gIph is still in its infancy. Herein, two novel alternating chiral‐achiral cations intercalation‐type chiral hybrid perovskites (CHPs), named (R/S‐1‐phenylpropylamine)(propylamine)PbBr4 (1‐R/S), exhibit above room‐temperature (RT) polar‐phase transition, which greatly regulates the gIph value. The gIph of 1‐R is 0.04 in high‐temperature phase chiral non‐polar (P212121) by applying 5 V bias, interestingly, with the temperature decrease, the gIph value in low‐temperature phase chiral polar (P21) gradually increases (0.22@360K, 0.40@340K, 0.47@320K), and finally reaches a maximum of 0.5 at RT. Such value is not only the highest among 2D CHPs to date, but presents a 12.5‐fold amplification compared with 0.04. Further, this rare phenomenon should be attributed to the built‐in electric field induced by the polar photovoltaic effect, which sheds light on further obtaining CHPs with large gIph. |
| first_indexed | 2024-03-08T04:04:08Z |
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| institution | Directory Open Access Journal |
| issn | 2198-3844 |
| language | English |
| last_indexed | 2024-03-08T04:04:08Z |
| publishDate | 2024-02-01 |
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| series | Advanced Science |
| spelling | doaj.art-e186cefa0076441592865bfc739e62612024-02-09T08:26:35ZengWileyAdvanced Science2198-38442024-02-01116n/an/a10.1002/advs.202307593Regulating Circularly Polarized Light Detection via Polar‐Phase Transition in Alternating Chiral‐Achiral Cations Intercalation‐Type Hybrid PerovskitesZeng‐Kui Zhu0Tingting Zhu1Shihai You2Panpan Yu3Jianbo Wu4Ying Zeng5Yuhang Jiang6Xitao Liu7Lina Li8Chengmin Ji9Junhua Luo10State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 ChinaState Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 ChinaState Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 ChinaSchool of Chemistry and Chemical Engineering; Key Laboratory of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education Jiangxi Normal University Nanchang 330022 ChinaState Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 ChinaSchool of Chemistry and Chemical Engineering; Key Laboratory of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education Jiangxi Normal University Nanchang 330022 ChinaSchool of Chemistry and Chemical Engineering; Key Laboratory of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education Jiangxi Normal University Nanchang 330022 ChinaState Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 ChinaState Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 ChinaState Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 ChinaState Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 ChinaAbstract Circularly polarized light (CPL) detection has wide applications in many fields, where the anisotropy factor (gIph) is an important indicator to characterize the CPL detection performance. So far, many materials with high gIph have been reported, however, the exploration of the regulation of gIph is still in its infancy. Herein, two novel alternating chiral‐achiral cations intercalation‐type chiral hybrid perovskites (CHPs), named (R/S‐1‐phenylpropylamine)(propylamine)PbBr4 (1‐R/S), exhibit above room‐temperature (RT) polar‐phase transition, which greatly regulates the gIph value. The gIph of 1‐R is 0.04 in high‐temperature phase chiral non‐polar (P212121) by applying 5 V bias, interestingly, with the temperature decrease, the gIph value in low‐temperature phase chiral polar (P21) gradually increases (0.22@360K, 0.40@340K, 0.47@320K), and finally reaches a maximum of 0.5 at RT. Such value is not only the highest among 2D CHPs to date, but presents a 12.5‐fold amplification compared with 0.04. Further, this rare phenomenon should be attributed to the built‐in electric field induced by the polar photovoltaic effect, which sheds light on further obtaining CHPs with large gIph.https://doi.org/10.1002/advs.202307593alternating chiral‐achiral cations intercalation‐type hybrid perovskitescircularly polarized light detectionpolar phase transitionpolar photovoltaic effectregulate anisotropy factor |
| spellingShingle | Zeng‐Kui Zhu Tingting Zhu Shihai You Panpan Yu Jianbo Wu Ying Zeng Yuhang Jiang Xitao Liu Lina Li Chengmin Ji Junhua Luo Regulating Circularly Polarized Light Detection via Polar‐Phase Transition in Alternating Chiral‐Achiral Cations Intercalation‐Type Hybrid Perovskites Advanced Science alternating chiral‐achiral cations intercalation‐type hybrid perovskites circularly polarized light detection polar phase transition polar photovoltaic effect regulate anisotropy factor |
| title | Regulating Circularly Polarized Light Detection via Polar‐Phase Transition in Alternating Chiral‐Achiral Cations Intercalation‐Type Hybrid Perovskites |
| title_full | Regulating Circularly Polarized Light Detection via Polar‐Phase Transition in Alternating Chiral‐Achiral Cations Intercalation‐Type Hybrid Perovskites |
| title_fullStr | Regulating Circularly Polarized Light Detection via Polar‐Phase Transition in Alternating Chiral‐Achiral Cations Intercalation‐Type Hybrid Perovskites |
| title_full_unstemmed | Regulating Circularly Polarized Light Detection via Polar‐Phase Transition in Alternating Chiral‐Achiral Cations Intercalation‐Type Hybrid Perovskites |
| title_short | Regulating Circularly Polarized Light Detection via Polar‐Phase Transition in Alternating Chiral‐Achiral Cations Intercalation‐Type Hybrid Perovskites |
| title_sort | regulating circularly polarized light detection via polar phase transition in alternating chiral achiral cations intercalation type hybrid perovskites |
| topic | alternating chiral‐achiral cations intercalation‐type hybrid perovskites circularly polarized light detection polar phase transition polar photovoltaic effect regulate anisotropy factor |
| url | https://doi.org/10.1002/advs.202307593 |
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