[Bis(quinolin-2-ylcarbonyl)amido-κ3N,N′,N′′]bromido(N,N-dimethylformamide-κO)copper(II)
In the mononuclear title complex, [CuBr(C20H12N3O2)(C3H7NO)], synthesized from the quinoline-derived reduced Schiff base 4-(quinolin-2-ylmethyl)aminophenol, the coordination geometry around Cu2+ is distorted square-pyramidal, comprising a bromide anion at the apex [Cu—Br = 2.4671 (5) Å]. The base of...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814010058 |
| _version_ | 1819004521361178624 |
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| author | Md. Serajul Haque Faizi Pratik Sen |
| author_facet | Md. Serajul Haque Faizi Pratik Sen |
| author_sort | Md. Serajul Haque Faizi |
| collection | DOAJ |
| description | In the mononuclear title complex, [CuBr(C20H12N3O2)(C3H7NO)], synthesized from the quinoline-derived reduced Schiff base 4-(quinolin-2-ylmethyl)aminophenol, the coordination geometry around Cu2+ is distorted square-pyramidal, comprising a bromide anion at the apex [Cu—Br = 2.4671 (5) Å]. The base of the pyramid is built up from one dimethylformamide O-atom donor [Cu—O = 2.078 (2) Å] and three N-atom donors from the monoanionic, tridentate bis(quinolin-2-ylcarbonyl)diimide ligand [Cu—Ndiimide = 1.941 (3) Å, and Cu—Nquinolyl = 2.060 (3) and 2.049 (3) Å]. An intramolecular C—H...O occurs. In the crystal, weak methyl and aromatic C—H...Br and formyl C—H...Ocarbonyl hydrogen-bonding interactions generate an overall layered structure lying parallel to (001). |
| first_indexed | 2024-12-20T23:38:13Z |
| format | Article |
| id | doaj.art-e189ca56b35143ff96d2090bcee6c01e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:38:13Z |
| publishDate | 2014-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e189ca56b35143ff96d2090bcee6c01e2022-12-21T19:23:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706m206m20710.1107/S1600536814010058zs2296[Bis(quinolin-2-ylcarbonyl)amido-κ3N,N′,N′′]bromido(N,N-dimethylformamide-κO)copper(II)Md. Serajul Haque Faizi0Pratik Sen1Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, IndiaDepartment of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, IndiaIn the mononuclear title complex, [CuBr(C20H12N3O2)(C3H7NO)], synthesized from the quinoline-derived reduced Schiff base 4-(quinolin-2-ylmethyl)aminophenol, the coordination geometry around Cu2+ is distorted square-pyramidal, comprising a bromide anion at the apex [Cu—Br = 2.4671 (5) Å]. The base of the pyramid is built up from one dimethylformamide O-atom donor [Cu—O = 2.078 (2) Å] and three N-atom donors from the monoanionic, tridentate bis(quinolin-2-ylcarbonyl)diimide ligand [Cu—Ndiimide = 1.941 (3) Å, and Cu—Nquinolyl = 2.060 (3) and 2.049 (3) Å]. An intramolecular C—H...O occurs. In the crystal, weak methyl and aromatic C—H...Br and formyl C—H...Ocarbonyl hydrogen-bonding interactions generate an overall layered structure lying parallel to (001).http://scripts.iucr.org/cgi-bin/paper?S1600536814010058 |
| spellingShingle | Md. Serajul Haque Faizi Pratik Sen [Bis(quinolin-2-ylcarbonyl)amido-κ3N,N′,N′′]bromido(N,N-dimethylformamide-κO)copper(II) Acta Crystallographica Section E |
| title | [Bis(quinolin-2-ylcarbonyl)amido-κ3N,N′,N′′]bromido(N,N-dimethylformamide-κO)copper(II) |
| title_full | [Bis(quinolin-2-ylcarbonyl)amido-κ3N,N′,N′′]bromido(N,N-dimethylformamide-κO)copper(II) |
| title_fullStr | [Bis(quinolin-2-ylcarbonyl)amido-κ3N,N′,N′′]bromido(N,N-dimethylformamide-κO)copper(II) |
| title_full_unstemmed | [Bis(quinolin-2-ylcarbonyl)amido-κ3N,N′,N′′]bromido(N,N-dimethylformamide-κO)copper(II) |
| title_short | [Bis(quinolin-2-ylcarbonyl)amido-κ3N,N′,N′′]bromido(N,N-dimethylformamide-κO)copper(II) |
| title_sort | bis quinolin 2 ylcarbonyl amido κ3n n n bromido n n dimethylformamide κo copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814010058 |
| work_keys_str_mv | AT mdserajulhaquefaizi bisquinolin2ylcarbonylamidok3nnnbromidonndimethylformamidekocopperii AT pratiksen bisquinolin2ylcarbonylamidok3nnnbromidonndimethylformamidekocopperii |