Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H<sub>2</sub>SO<sub>4</sub> Solutions

Titanium alloys have been used in aerospace, aeronautic, automotive, biomedical, structural, and other applications because titanium alloys have less density than materials like steel and support higher stress than Al-alloys. However, components made of titanium alloys are exposed to corrosive envir...

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Bibliographic Details
Main Authors: Jesús Manuel Jáquez-Muñoz, Citlalli Gaona-Tiburcio, Jose Cabral-Miramontes, Demetrio Nieves-Mendoza, Erick Maldonado-Bandala, Javier Olguín-Coca, Luis Daimir López-Léon, Juan Pablo Flores-De los Rios, Facundo Almeraya-Calderón
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Metals
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Online Access:https://www.mdpi.com/2075-4701/11/1/105
Description
Summary:Titanium alloys have been used in aerospace, aeronautic, automotive, biomedical, structural, and other applications because titanium alloys have less density than materials like steel and support higher stress than Al-alloys. However, components made of titanium alloys are exposed to corrosive environments, the most common being industrial and marine atmospheres. This research shows the corrosion behavior of three titanium alloys, specifically Ti-CP2, Ti-6Al-2Sn-4Zr-2Mo, and Ti-6Al-4V with α, near α, and α + β alloys phases. Alloys were exposed in two electrolytes to a 3.5 wt. % H<sub>2</sub>SO<sub>4</sub> and NaCl solution at room temperature, and their electrochemical behavior was studied by electrochemical noise technique (EN) according to ASTM ASTM-G199 standard. EN signal was filtered by three different methods, and the polynomial method was employed to obtain <i>R<sub>n</sub></i>, kurtosis, skew, and the potential spectral density analysis (PSD). The wavelets method was used, from which energy dispersion plots were obtained. The last method was Hilbert–Huang Transform (HHT), where Hilbert Spectra were analyzed. Results indicated that <i>R<sub>n</sub></i> compared with PSD showed that Ti-6Al-2Sn-4Zr-2Mo presented less dissolution in both electrolytes. Statistical methods showed that the passive layer created on Ti alloys’ surfaces is unstable; this condition is notable for Ti-6Al-2Sn-4Zr-2Mo in NaCl solution.
ISSN:2075-4701