New Optically Active <i>tert</i>-Butylarylthiophosphinic Acids and Their Selenium Analogues as the Potential Synthons of Supramolecular Organometallic Complexes: Syntheses and Crystallographic Structure Determination
The aim of the research described in this publication is two-fold. The first is a detailed description of the synthesis of a series of compounds containing a stereogenic heteroatom, namely the optically active <i>P</i>-stereogenic derivatives of <i>tert</i>-butylarylphoshinic...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-05-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/28/11/4298 |
| _version_ | 1797597106139037696 |
|---|---|
| author | Jarosław Błaszczyk Bogdan Bujnicki Patrycja Pokora-Sobczak Grażyna Mielniczak Lesław Sieroń Piotr Kiełbasiński Józef Drabowicz |
| author_facet | Jarosław Błaszczyk Bogdan Bujnicki Patrycja Pokora-Sobczak Grażyna Mielniczak Lesław Sieroń Piotr Kiełbasiński Józef Drabowicz |
| author_sort | Jarosław Błaszczyk |
| collection | DOAJ |
| description | The aim of the research described in this publication is two-fold. The first is a detailed description of the synthesis of a series of compounds containing a stereogenic heteroatom, namely the optically active <i>P</i>-stereogenic derivatives of <i>tert</i>-butylarylphoshinic acids bearing sulfur or selenium. The second is a detailed discussion dedicated to the determination of their structures by an X-ray analysis. Such a determination is needed when considering optically active hetero-oxophosphoric acids as new chiral solvating agents, precursors of new chiral ionic liquids, or ligands in complexes serving as novel organometallic catalysts. |
| first_indexed | 2024-03-11T03:02:06Z |
| format | Article |
| id | doaj.art-e1aa0a88dce745d7876b0f43ffce7442 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-11T03:02:06Z |
| publishDate | 2023-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-e1aa0a88dce745d7876b0f43ffce74422023-11-18T08:14:43ZengMDPI AGMolecules1420-30492023-05-012811429810.3390/molecules28114298New Optically Active <i>tert</i>-Butylarylthiophosphinic Acids and Their Selenium Analogues as the Potential Synthons of Supramolecular Organometallic Complexes: Syntheses and Crystallographic Structure DeterminationJarosław Błaszczyk0Bogdan Bujnicki1Patrycja Pokora-Sobczak2Grażyna Mielniczak3Lesław Sieroń4Piotr Kiełbasiński5Józef Drabowicz6Division of Organic Chemistry, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, PolandDivision of Organic Chemistry, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, PolandDivision of Organic Chemistry, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, PolandDivision of Organic Chemistry, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, PolandInstitute of General and Ecological Chemistry, Lodz University of Technology, Żeromskiego 116, 90-924 Łódź, PolandDivision of Organic Chemistry, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, PolandDivision of Organic Chemistry, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, PolandThe aim of the research described in this publication is two-fold. The first is a detailed description of the synthesis of a series of compounds containing a stereogenic heteroatom, namely the optically active <i>P</i>-stereogenic derivatives of <i>tert</i>-butylarylphoshinic acids bearing sulfur or selenium. The second is a detailed discussion dedicated to the determination of their structures by an X-ray analysis. Such a determination is needed when considering optically active hetero-oxophosphoric acids as new chiral solvating agents, precursors of new chiral ionic liquids, or ligands in complexes serving as novel organometallic catalysts.https://www.mdpi.com/1420-3049/28/11/4298thioacidsphosphinothioic acidsselenoacidsphosphinoselenoic acidschiral solvating agentscrystal structure |
| spellingShingle | Jarosław Błaszczyk Bogdan Bujnicki Patrycja Pokora-Sobczak Grażyna Mielniczak Lesław Sieroń Piotr Kiełbasiński Józef Drabowicz New Optically Active <i>tert</i>-Butylarylthiophosphinic Acids and Their Selenium Analogues as the Potential Synthons of Supramolecular Organometallic Complexes: Syntheses and Crystallographic Structure Determination Molecules thioacids phosphinothioic acids selenoacids phosphinoselenoic acids chiral solvating agents crystal structure |
| title | New Optically Active <i>tert</i>-Butylarylthiophosphinic Acids and Their Selenium Analogues as the Potential Synthons of Supramolecular Organometallic Complexes: Syntheses and Crystallographic Structure Determination |
| title_full | New Optically Active <i>tert</i>-Butylarylthiophosphinic Acids and Their Selenium Analogues as the Potential Synthons of Supramolecular Organometallic Complexes: Syntheses and Crystallographic Structure Determination |
| title_fullStr | New Optically Active <i>tert</i>-Butylarylthiophosphinic Acids and Their Selenium Analogues as the Potential Synthons of Supramolecular Organometallic Complexes: Syntheses and Crystallographic Structure Determination |
| title_full_unstemmed | New Optically Active <i>tert</i>-Butylarylthiophosphinic Acids and Their Selenium Analogues as the Potential Synthons of Supramolecular Organometallic Complexes: Syntheses and Crystallographic Structure Determination |
| title_short | New Optically Active <i>tert</i>-Butylarylthiophosphinic Acids and Their Selenium Analogues as the Potential Synthons of Supramolecular Organometallic Complexes: Syntheses and Crystallographic Structure Determination |
| title_sort | new optically active i tert i butylarylthiophosphinic acids and their selenium analogues as the potential synthons of supramolecular organometallic complexes syntheses and crystallographic structure determination |
| topic | thioacids phosphinothioic acids selenoacids phosphinoselenoic acids chiral solvating agents crystal structure |
| url | https://www.mdpi.com/1420-3049/28/11/4298 |
| work_keys_str_mv | AT jarosławbłaszczyk newopticallyactiveitertibutylarylthiophosphinicacidsandtheirseleniumanaloguesasthepotentialsynthonsofsupramolecularorganometalliccomplexessynthesesandcrystallographicstructuredetermination AT bogdanbujnicki newopticallyactiveitertibutylarylthiophosphinicacidsandtheirseleniumanaloguesasthepotentialsynthonsofsupramolecularorganometalliccomplexessynthesesandcrystallographicstructuredetermination AT patrycjapokorasobczak newopticallyactiveitertibutylarylthiophosphinicacidsandtheirseleniumanaloguesasthepotentialsynthonsofsupramolecularorganometalliccomplexessynthesesandcrystallographicstructuredetermination AT grazynamielniczak newopticallyactiveitertibutylarylthiophosphinicacidsandtheirseleniumanaloguesasthepotentialsynthonsofsupramolecularorganometalliccomplexessynthesesandcrystallographicstructuredetermination AT lesławsieron newopticallyactiveitertibutylarylthiophosphinicacidsandtheirseleniumanaloguesasthepotentialsynthonsofsupramolecularorganometalliccomplexessynthesesandcrystallographicstructuredetermination AT piotrkiełbasinski newopticallyactiveitertibutylarylthiophosphinicacidsandtheirseleniumanaloguesasthepotentialsynthonsofsupramolecularorganometalliccomplexessynthesesandcrystallographicstructuredetermination AT jozefdrabowicz newopticallyactiveitertibutylarylthiophosphinicacidsandtheirseleniumanaloguesasthepotentialsynthonsofsupramolecularorganometalliccomplexessynthesesandcrystallographicstructuredetermination |