Metal–Organic Polyhedra as Building Blocks for Porous Extended Networks
Abstract Metal–organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid‐state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2022-04-01
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| Series: | Advanced Science |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/advs.202104753 |
| _version_ | 1818061715691012096 |
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| author | Akim Khobotov‐Bakishev Laura Hernández‐López Cornelia von Baeckmann Jorge Albalad Arnau Carné‐Sánchez Daniel Maspoch |
| author_facet | Akim Khobotov‐Bakishev Laura Hernández‐López Cornelia von Baeckmann Jorge Albalad Arnau Carné‐Sánchez Daniel Maspoch |
| author_sort | Akim Khobotov‐Bakishev |
| collection | DOAJ |
| description | Abstract Metal–organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid‐state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have awakened the latent potential of MOPs to be used as building blocks for the synthesis of extended porous networks. This review article focuses on exploring the key developments that make the extension of MOPs possible, highlighting the most remarkable examples of MOP‐based soft materials and crystalline extended frameworks. Finally, the article ventures to offer future perspectives on the exploitation of MOPs in fields that still remain ripe toward the use of such unorthodox molecular porous platforms. |
| first_indexed | 2024-12-10T13:52:43Z |
| format | Article |
| id | doaj.art-e1ac3fcad3ca4bc2b09cf1d014938e2c |
| institution | Directory Open Access Journal |
| issn | 2198-3844 |
| language | English |
| last_indexed | 2024-12-10T13:52:43Z |
| publishDate | 2022-04-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj.art-e1ac3fcad3ca4bc2b09cf1d014938e2c2022-12-22T01:46:07ZengWileyAdvanced Science2198-38442022-04-01911n/an/a10.1002/advs.202104753Metal–Organic Polyhedra as Building Blocks for Porous Extended NetworksAkim Khobotov‐Bakishev0Laura Hernández‐López1Cornelia von Baeckmann2Jorge Albalad3Arnau Carné‐Sánchez4Daniel Maspoch5Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology Campus UAB, Bellaterra Barcelona 08193 SpainCatalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology Campus UAB, Bellaterra Barcelona 08193 SpainCatalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology Campus UAB, Bellaterra Barcelona 08193 SpainCatalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology Campus UAB, Bellaterra Barcelona 08193 SpainCatalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology Campus UAB, Bellaterra Barcelona 08193 SpainCatalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology Campus UAB, Bellaterra Barcelona 08193 SpainAbstract Metal–organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid‐state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have awakened the latent potential of MOPs to be used as building blocks for the synthesis of extended porous networks. This review article focuses on exploring the key developments that make the extension of MOPs possible, highlighting the most remarkable examples of MOP‐based soft materials and crystalline extended frameworks. Finally, the article ventures to offer future perspectives on the exploitation of MOPs in fields that still remain ripe toward the use of such unorthodox molecular porous platforms.https://doi.org/10.1002/advs.202104753gelsmembranesmetal–organic frameworksmetal–organic polyhedraporous networksreticular chemistry |
| spellingShingle | Akim Khobotov‐Bakishev Laura Hernández‐López Cornelia von Baeckmann Jorge Albalad Arnau Carné‐Sánchez Daniel Maspoch Metal–Organic Polyhedra as Building Blocks for Porous Extended Networks Advanced Science gels membranes metal–organic frameworks metal–organic polyhedra porous networks reticular chemistry |
| title | Metal–Organic Polyhedra as Building Blocks for Porous Extended Networks |
| title_full | Metal–Organic Polyhedra as Building Blocks for Porous Extended Networks |
| title_fullStr | Metal–Organic Polyhedra as Building Blocks for Porous Extended Networks |
| title_full_unstemmed | Metal–Organic Polyhedra as Building Blocks for Porous Extended Networks |
| title_short | Metal–Organic Polyhedra as Building Blocks for Porous Extended Networks |
| title_sort | metal organic polyhedra as building blocks for porous extended networks |
| topic | gels membranes metal–organic frameworks metal–organic polyhedra porous networks reticular chemistry |
| url | https://doi.org/10.1002/advs.202104753 |
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