Structural and Raman spectroscopic characterization of tetrapyridinesilver(I) perrhenate, [Agpy4]ReO4
Tetrapyridinesilver(I) perrhenate [Agpy4]ReO4 was synthesized, and its crystal structure and Raman spectra were elucidated at low temperatures. The crystal lattice is constructed from isolated tetrahedral cations and anions having no argentophilic interactions. Weak hydrogen bonds are formed betwee...
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| Format: | Article |
| Language: | English |
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Society of Chemists and Technologists of Macedonia
2022-05-01
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| Series: | Macedonian Journal of Chemistry and Chemical Engineering |
| Subjects: | |
| Online Access: | https://mjcce.org.mk/index.php/MJCCE/article/view/2490 |
| _version_ | 1811236219949940736 |
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| author | Vladimir M. Petrushevski Kende Attila Béres Petra Bombicz Attila Farkas László Kótai Laura Bereczki |
| author_facet | Vladimir M. Petrushevski Kende Attila Béres Petra Bombicz Attila Farkas László Kótai Laura Bereczki |
| author_sort | Vladimir M. Petrushevski |
| collection | DOAJ |
| description |
Tetrapyridinesilver(I) perrhenate [Agpy4]ReO4 was synthesized, and its crystal structure and Raman spectra were elucidated at low temperatures. The crystal lattice is constructed from isolated tetrahedral cations and anions having no argentophilic interactions. Weak hydrogen bonds are formed between the oxygens of the disordered perrhenate anions and the ortho-hydrogens of the pyridine ligands. No parallel π…π stacking interactions are observed, but C-H…π interactions of the pyridine ligands within columns of cations and between the columns appeared. Correlation analysis for Ag+, pyridine ligands, and perrhenate ions was performed, and the perrhenate ion and some of the AgN4 skeleton vibrational modes and pyridine ligand modes in the Raman spectrum of [Agpy4]ReO4 were assigned.
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| first_indexed | 2024-04-12T12:05:10Z |
| format | Article |
| id | doaj.art-e1e6ef1317a34c5e8218863d1f91a0ad |
| institution | Directory Open Access Journal |
| issn | 1857-5552 1857-5625 |
| language | English |
| last_indexed | 2024-04-12T12:05:10Z |
| publishDate | 2022-05-01 |
| publisher | Society of Chemists and Technologists of Macedonia |
| record_format | Article |
| series | Macedonian Journal of Chemistry and Chemical Engineering |
| spelling | doaj.art-e1e6ef1317a34c5e8218863d1f91a0ad2022-12-22T03:33:44ZengSociety of Chemists and Technologists of MacedoniaMacedonian Journal of Chemistry and Chemical Engineering1857-55521857-56252022-05-01411Structural and Raman spectroscopic characterization of tetrapyridinesilver(I) perrhenate, [Agpy4]ReO4Vladimir M. Petrushevski0Kende Attila Béres1Petra Bombicz2Attila Farkas3László Kótai4Laura Bereczki5Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Ss. Cyril and Methodius University in SkopjeResearch Centre for Natural Sciences, Magyar Tudósok krt. 2., Budapest and Institute of Chemistry, ELTE Eötvös Loránd University, Pázmány Péter s. 1/A, 1117 BudapestResearch Centre for Natural Sciences, Magyar Tudósok krt. 2., BudapestBudapest University of Technology and Economics, Department of Organic Chemistry and Technology, BudapestResearch Centre for Natural Sciences, Magyar Tudósok krt. 2., Budapest and Deuton-X Ltd, H-2030, ÉrdResearch Centre for Natural Sciences, Magyar Tudósok krt. 2., Budapest Tetrapyridinesilver(I) perrhenate [Agpy4]ReO4 was synthesized, and its crystal structure and Raman spectra were elucidated at low temperatures. The crystal lattice is constructed from isolated tetrahedral cations and anions having no argentophilic interactions. Weak hydrogen bonds are formed between the oxygens of the disordered perrhenate anions and the ortho-hydrogens of the pyridine ligands. No parallel π…π stacking interactions are observed, but C-H…π interactions of the pyridine ligands within columns of cations and between the columns appeared. Correlation analysis for Ag+, pyridine ligands, and perrhenate ions was performed, and the perrhenate ion and some of the AgN4 skeleton vibrational modes and pyridine ligand modes in the Raman spectrum of [Agpy4]ReO4 were assigned. https://mjcce.org.mk/index.php/MJCCE/article/view/2490crystal structureRaman spectra rhenium compoundspyridine complexesperrhenates |
| spellingShingle | Vladimir M. Petrushevski Kende Attila Béres Petra Bombicz Attila Farkas László Kótai Laura Bereczki Structural and Raman spectroscopic characterization of tetrapyridinesilver(I) perrhenate, [Agpy4]ReO4 Macedonian Journal of Chemistry and Chemical Engineering crystal structure Raman spectra rhenium compounds pyridine complexes perrhenates |
| title | Structural and Raman spectroscopic characterization of tetrapyridinesilver(I) perrhenate, [Agpy4]ReO4 |
| title_full | Structural and Raman spectroscopic characterization of tetrapyridinesilver(I) perrhenate, [Agpy4]ReO4 |
| title_fullStr | Structural and Raman spectroscopic characterization of tetrapyridinesilver(I) perrhenate, [Agpy4]ReO4 |
| title_full_unstemmed | Structural and Raman spectroscopic characterization of tetrapyridinesilver(I) perrhenate, [Agpy4]ReO4 |
| title_short | Structural and Raman spectroscopic characterization of tetrapyridinesilver(I) perrhenate, [Agpy4]ReO4 |
| title_sort | structural and raman spectroscopic characterization of tetrapyridinesilver i perrhenate agpy4 reo4 |
| topic | crystal structure Raman spectra rhenium compounds pyridine complexes perrhenates |
| url | https://mjcce.org.mk/index.php/MJCCE/article/view/2490 |
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