Electrospun Conducting Polymers: Approaches and Applications

Inherently conductive polymers (CPs) can generally be switched between two or more stable oxidation states, giving rise to changes in properties including conductivity, color, and volume. The ability to prepare CP nanofibers could lead to applications including water purification, sensors, separatio...

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Main Authors: Mariana Acosta, Marvin D. Santiago, Jennifer A. Irvin
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/24/8820
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author Mariana Acosta
Marvin D. Santiago
Jennifer A. Irvin
author_facet Mariana Acosta
Marvin D. Santiago
Jennifer A. Irvin
author_sort Mariana Acosta
collection DOAJ
description Inherently conductive polymers (CPs) can generally be switched between two or more stable oxidation states, giving rise to changes in properties including conductivity, color, and volume. The ability to prepare CP nanofibers could lead to applications including water purification, sensors, separations, nerve regeneration, wound healing, wearable electronic devices, and flexible energy storage. Electrospinning is a relatively inexpensive, simple process that is used to produce polymer nanofibers from solution. The nanofibers have many desirable qualities including high surface area per unit mass, high porosity, and low weight. Unfortunately, the low molecular weight and rigid rod nature of most CPs cannot yield enough chain entanglement for electrospinning, instead yielding polymer nanoparticles via an electrospraying process. Common workarounds include co-extruding with an insulating carrier polymer, coaxial electrospinning, and coating insulating electrospun polymer nanofibers with CPs. This review explores the benefits and drawbacks of these methods, as well as the use of these materials in sensing, biomedical, electronic, separation, purification, and energy conversion and storage applications.
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spelling doaj.art-e23268d99f344f718154dd0b7ed29cf22023-11-24T16:22:12ZengMDPI AGMaterials1996-19442022-12-011524882010.3390/ma15248820Electrospun Conducting Polymers: Approaches and ApplicationsMariana Acosta0Marvin D. Santiago1Jennifer A. Irvin2Materials Science, Engineering and Commercialization Program, Texas State University, San Marcos, TX 78666, USADepartment of Chemistry and Biochemistry, Texas State University, San Marcos, TX 78666, USAMaterials Science, Engineering and Commercialization Program, Texas State University, San Marcos, TX 78666, USAInherently conductive polymers (CPs) can generally be switched between two or more stable oxidation states, giving rise to changes in properties including conductivity, color, and volume. The ability to prepare CP nanofibers could lead to applications including water purification, sensors, separations, nerve regeneration, wound healing, wearable electronic devices, and flexible energy storage. Electrospinning is a relatively inexpensive, simple process that is used to produce polymer nanofibers from solution. The nanofibers have many desirable qualities including high surface area per unit mass, high porosity, and low weight. Unfortunately, the low molecular weight and rigid rod nature of most CPs cannot yield enough chain entanglement for electrospinning, instead yielding polymer nanoparticles via an electrospraying process. Common workarounds include co-extruding with an insulating carrier polymer, coaxial electrospinning, and coating insulating electrospun polymer nanofibers with CPs. This review explores the benefits and drawbacks of these methods, as well as the use of these materials in sensing, biomedical, electronic, separation, purification, and energy conversion and storage applications.https://www.mdpi.com/1996-1944/15/24/8820conducting polymerselectrospinningnanocompositenanofibers
spellingShingle Mariana Acosta
Marvin D. Santiago
Jennifer A. Irvin
Electrospun Conducting Polymers: Approaches and Applications
Materials
conducting polymers
electrospinning
nanocomposite
nanofibers
title Electrospun Conducting Polymers: Approaches and Applications
title_full Electrospun Conducting Polymers: Approaches and Applications
title_fullStr Electrospun Conducting Polymers: Approaches and Applications
title_full_unstemmed Electrospun Conducting Polymers: Approaches and Applications
title_short Electrospun Conducting Polymers: Approaches and Applications
title_sort electrospun conducting polymers approaches and applications
topic conducting polymers
electrospinning
nanocomposite
nanofibers
url https://www.mdpi.com/1996-1944/15/24/8820
work_keys_str_mv AT marianaacosta electrospunconductingpolymersapproachesandapplications
AT marvindsantiago electrospunconductingpolymersapproachesandapplications
AT jenniferairvin electrospunconductingpolymersapproachesandapplications