(2,2′-Bipyrazine-κ2N1,N1′)[1,2-bis(diphenylphosphanyl)methane-κP]tricarbonylrhenium(I) trifluoromethanesulfonate monohydrate
The title compound, [Re(C8H6N4)(C25H22P2)(CO)3]CF3SO3·H2O, crystallizes with one [Re(C8N4H6){P(Ph)2CH2P(Ph)2}(CO)3]+ cation, where Ph is a phenyl group, one CF3SO3− anion and one water molecule of hydration. The three C atoms of the facial oriented carbonyl groups, two N atoms from the bipyrazine li...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-06-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461700935X |
| _version_ | 1819059834871349248 |
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| author | D. Paul Rillema Venugopal Komreddy Nilmini K. Senaratne David M. Eichhorn |
| author_facet | D. Paul Rillema Venugopal Komreddy Nilmini K. Senaratne David M. Eichhorn |
| author_sort | D. Paul Rillema |
| collection | DOAJ |
| description | The title compound, [Re(C8H6N4)(C25H22P2)(CO)3]CF3SO3·H2O, crystallizes with one [Re(C8N4H6){P(Ph)2CH2P(Ph)2}(CO)3]+ cation, where Ph is a phenyl group, one CF3SO3− anion and one water molecule of hydration. The three C atoms of the facial oriented carbonyl groups, two N atoms from the bipyrazine ligand and one P atom from the (bis)diphenylphosphanylmethane ligand define a distorted octahedral coordination environment about the central ReI atom. The Re—Ccarbonyl bond length trans to the P atom is longer than the the two Re—Ccarbonyl bond lengths in the plane with the bipyrazine ligand. Hydrogen-bonding interactions between the solvent water molecule and the cation, as well as weak C—H...O interactions, consolidate a three-dimensional network structure. |
| first_indexed | 2024-12-21T14:17:24Z |
| format | Article |
| id | doaj.art-e24bd60e420b4f6e8f0e45ff97a67075 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-21T14:17:24Z |
| publishDate | 2017-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-e24bd60e420b4f6e8f0e45ff97a670752022-12-21T19:00:53ZengInternational Union of CrystallographyIUCrData2414-31462017-06-0126x17093510.1107/S241431461700935Xwm4050(2,2′-Bipyrazine-κ2N1,N1′)[1,2-bis(diphenylphosphanyl)methane-κP]tricarbonylrhenium(I) trifluoromethanesulfonate monohydrateD. Paul Rillema0Venugopal Komreddy1Nilmini K. Senaratne2David M. Eichhorn3Department of Chemistry, Wichita State University, Wichita, KS 67260, USADepartment of Chemistry, Wichita State University, Wichita, KS 67260, USADepartment of Chemistry, Wichita State University, Wichita, KS 67260, USADepartment of Chemistry, Wichita State University, Wichita, KS 67260, USAThe title compound, [Re(C8H6N4)(C25H22P2)(CO)3]CF3SO3·H2O, crystallizes with one [Re(C8N4H6){P(Ph)2CH2P(Ph)2}(CO)3]+ cation, where Ph is a phenyl group, one CF3SO3− anion and one water molecule of hydration. The three C atoms of the facial oriented carbonyl groups, two N atoms from the bipyrazine ligand and one P atom from the (bis)diphenylphosphanylmethane ligand define a distorted octahedral coordination environment about the central ReI atom. The Re—Ccarbonyl bond length trans to the P atom is longer than the the two Re—Ccarbonyl bond lengths in the plane with the bipyrazine ligand. Hydrogen-bonding interactions between the solvent water molecule and the cation, as well as weak C—H...O interactions, consolidate a three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S241431461700935Xcrystal structurebipyrazinecoordination complexrhenium(I) |
| spellingShingle | D. Paul Rillema Venugopal Komreddy Nilmini K. Senaratne David M. Eichhorn (2,2′-Bipyrazine-κ2N1,N1′)[1,2-bis(diphenylphosphanyl)methane-κP]tricarbonylrhenium(I) trifluoromethanesulfonate monohydrate IUCrData crystal structure bipyrazine coordination complex rhenium(I) |
| title | (2,2′-Bipyrazine-κ2N1,N1′)[1,2-bis(diphenylphosphanyl)methane-κP]tricarbonylrhenium(I) trifluoromethanesulfonate monohydrate |
| title_full | (2,2′-Bipyrazine-κ2N1,N1′)[1,2-bis(diphenylphosphanyl)methane-κP]tricarbonylrhenium(I) trifluoromethanesulfonate monohydrate |
| title_fullStr | (2,2′-Bipyrazine-κ2N1,N1′)[1,2-bis(diphenylphosphanyl)methane-κP]tricarbonylrhenium(I) trifluoromethanesulfonate monohydrate |
| title_full_unstemmed | (2,2′-Bipyrazine-κ2N1,N1′)[1,2-bis(diphenylphosphanyl)methane-κP]tricarbonylrhenium(I) trifluoromethanesulfonate monohydrate |
| title_short | (2,2′-Bipyrazine-κ2N1,N1′)[1,2-bis(diphenylphosphanyl)methane-κP]tricarbonylrhenium(I) trifluoromethanesulfonate monohydrate |
| title_sort | 2 2 bipyrazine κ2n1 n1 1 2 bis diphenylphosphanyl methane κp tricarbonylrhenium i trifluoromethanesulfonate monohydrate |
| topic | crystal structure bipyrazine coordination complex rhenium(I) |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461700935X |
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