Bis[N,N′-bis[(1H-pyrrol-2-yl)methylene]cyclohexane-1,2-diamine]titanium(IV) tetrahydrofuran solvate
In the title compound, [Ti(C16H18N4)2]·C4H8O, the TiIV ion is chelated by two Schiff base dianions with a TiN8 distorted square-antiprismatic coordination geometry. The two cyclohexane rings assume the typical chair conformation. No hydrogen bonding is observed in the crystal structure.
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808002870 |
| _version_ | 1818907429277007872 |
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| author | Wu Li Ya-Hong Li Bin Xu Xue-Qin Zhang |
| author_facet | Wu Li Ya-Hong Li Bin Xu Xue-Qin Zhang |
| author_sort | Wu Li |
| collection | DOAJ |
| description | In the title compound, [Ti(C16H18N4)2]·C4H8O, the TiIV ion is chelated by two Schiff base dianions with a TiN8 distorted square-antiprismatic coordination geometry. The two cyclohexane rings assume the typical chair conformation. No hydrogen bonding is observed in the crystal structure. |
| first_indexed | 2024-12-19T21:54:59Z |
| format | Article |
| id | doaj.art-e256bbceedd947b6bd0496f334ce4e69 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:54:59Z |
| publishDate | 2008-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e256bbceedd947b6bd0496f334ce4e692022-12-21T20:04:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m437m43710.1107/S1600536808002870Bis[N,N′-bis[(1H-pyrrol-2-yl)methylene]cyclohexane-1,2-diamine]titanium(IV) tetrahydrofuran solvateWu LiYa-Hong LiBin XuXue-Qin ZhangIn the title compound, [Ti(C16H18N4)2]·C4H8O, the TiIV ion is chelated by two Schiff base dianions with a TiN8 distorted square-antiprismatic coordination geometry. The two cyclohexane rings assume the typical chair conformation. No hydrogen bonding is observed in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808002870 |
| spellingShingle | Wu Li Ya-Hong Li Bin Xu Xue-Qin Zhang Bis[N,N′-bis[(1H-pyrrol-2-yl)methylene]cyclohexane-1,2-diamine]titanium(IV) tetrahydrofuran solvate Acta Crystallographica Section E |
| title | Bis[N,N′-bis[(1H-pyrrol-2-yl)methylene]cyclohexane-1,2-diamine]titanium(IV) tetrahydrofuran solvate |
| title_full | Bis[N,N′-bis[(1H-pyrrol-2-yl)methylene]cyclohexane-1,2-diamine]titanium(IV) tetrahydrofuran solvate |
| title_fullStr | Bis[N,N′-bis[(1H-pyrrol-2-yl)methylene]cyclohexane-1,2-diamine]titanium(IV) tetrahydrofuran solvate |
| title_full_unstemmed | Bis[N,N′-bis[(1H-pyrrol-2-yl)methylene]cyclohexane-1,2-diamine]titanium(IV) tetrahydrofuran solvate |
| title_short | Bis[N,N′-bis[(1H-pyrrol-2-yl)methylene]cyclohexane-1,2-diamine]titanium(IV) tetrahydrofuran solvate |
| title_sort | bis n n 8242 bis 1h pyrrol 2 yl methylene cyclohexane 1 2 diamine titanium iv tetrahydrofuran solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808002870 |
| work_keys_str_mv | AT wuli bisnn8242bis1hpyrrol2ylmethylenecyclohexane12diaminetitaniumivtetrahydrofuransolvate AT yahongli bisnn8242bis1hpyrrol2ylmethylenecyclohexane12diaminetitaniumivtetrahydrofuransolvate AT binxu bisnn8242bis1hpyrrol2ylmethylenecyclohexane12diaminetitaniumivtetrahydrofuransolvate AT xueqinzhang bisnn8242bis1hpyrrol2ylmethylenecyclohexane12diaminetitaniumivtetrahydrofuransolvate |