Chirality transfer from a 3D macro shape to the molecular level by controlling asymmetric secondary flows
External physical forces can bias a spontaneous symmetry breaking process but whether the shape of a reactor plays a role in chiral symmetry breaking processes is an open question. Here, the authors demonstrate chirality transfer from the chiral shape of a 3D helical channel to chiral supramolecular...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-04-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-29425-y |
| _version_ | 1811311693791232000 |
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| author | Semih Sevim Alessandro Sorrenti João Pedro Vale Zoubir El-Hachemi Salvador Pané Andreas D. Flouris Tiago Sotto Mayor Josep Puigmartí-Luis |
| author_facet | Semih Sevim Alessandro Sorrenti João Pedro Vale Zoubir El-Hachemi Salvador Pané Andreas D. Flouris Tiago Sotto Mayor Josep Puigmartí-Luis |
| author_sort | Semih Sevim |
| collection | DOAJ |
| description | External physical forces can bias a spontaneous symmetry breaking process but whether the shape of a reactor plays a role in chiral symmetry breaking processes is an open question. Here, the authors demonstrate chirality transfer from the chiral shape of a 3D helical channel to chiral supramolecular aggregates whereby the handedness of the helical channel dictates the direction of enantioselection. |
| first_indexed | 2024-04-13T10:22:21Z |
| format | Article |
| id | doaj.art-e25c31b47f9046109993482f38fd4513 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-13T10:22:21Z |
| publishDate | 2022-04-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-e25c31b47f9046109993482f38fd45132022-12-22T02:50:27ZengNature PortfolioNature Communications2041-17232022-04-011311910.1038/s41467-022-29425-yChirality transfer from a 3D macro shape to the molecular level by controlling asymmetric secondary flowsSemih Sevim0Alessandro Sorrenti1João Pedro Vale2Zoubir El-Hachemi3Salvador Pané4Andreas D. Flouris5Tiago Sotto Mayor6Josep Puigmartí-Luis7Institute of Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH ZurichInstitute of Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH ZurichTransport Phenomena Research Centre (CEFT), Engineering Faculty of Porto University, Rua Dr. Roberto FriasDepartament de Química Inorgànica i Orgànica (Secció de Química Orgànica), University of Barcelona (UB)Multi-Scale Robotics Lab, ETH ZurichFAME Laboratory, Department of Exercise Science, University of ThessalyTransport Phenomena Research Centre (CEFT), Engineering Faculty of Porto University, Rua Dr. Roberto FriasInstitut de Química Teòrica i Computacional, University of Barcelona (UB)External physical forces can bias a spontaneous symmetry breaking process but whether the shape of a reactor plays a role in chiral symmetry breaking processes is an open question. Here, the authors demonstrate chirality transfer from the chiral shape of a 3D helical channel to chiral supramolecular aggregates whereby the handedness of the helical channel dictates the direction of enantioselection.https://doi.org/10.1038/s41467-022-29425-y |
| spellingShingle | Semih Sevim Alessandro Sorrenti João Pedro Vale Zoubir El-Hachemi Salvador Pané Andreas D. Flouris Tiago Sotto Mayor Josep Puigmartí-Luis Chirality transfer from a 3D macro shape to the molecular level by controlling asymmetric secondary flows Nature Communications |
| title | Chirality transfer from a 3D macro shape to the molecular level by controlling asymmetric secondary flows |
| title_full | Chirality transfer from a 3D macro shape to the molecular level by controlling asymmetric secondary flows |
| title_fullStr | Chirality transfer from a 3D macro shape to the molecular level by controlling asymmetric secondary flows |
| title_full_unstemmed | Chirality transfer from a 3D macro shape to the molecular level by controlling asymmetric secondary flows |
| title_short | Chirality transfer from a 3D macro shape to the molecular level by controlling asymmetric secondary flows |
| title_sort | chirality transfer from a 3d macro shape to the molecular level by controlling asymmetric secondary flows |
| url | https://doi.org/10.1038/s41467-022-29425-y |
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