Rock-Forming (Biotite and Plagioclase) and Accessory (Zircon) Minerals Geochemistry as an Indicator of the Metal Fertility of Magmas by the Example of Au-Cu-Fe-Skarn Deposits in Eastern Transbaikalia

Many gold and gold-bearing complex deposits related to the Late Jurassic and Early Cretaceous magmatism are known in Eastern Transbaikalia. The largest deposits are the Lugokan, the Kultuma and the Bystrinsky. These deposits are in a paragenetic relationship with the Late Jurassic magmatic rocks of...

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Main Authors: Yury O. Redin, Anna A. Redina, Viktor P. Mokrushnikov, Alexandra V. Malyutina, Vladislav F. Dultsev
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/12/1/50
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author Yury O. Redin
Anna A. Redina
Viktor P. Mokrushnikov
Alexandra V. Malyutina
Vladislav F. Dultsev
author_facet Yury O. Redin
Anna A. Redina
Viktor P. Mokrushnikov
Alexandra V. Malyutina
Vladislav F. Dultsev
author_sort Yury O. Redin
collection DOAJ
description Many gold and gold-bearing complex deposits related to the Late Jurassic and Early Cretaceous magmatism are known in Eastern Transbaikalia. The largest deposits are the Lugokan, the Kultuma and the Bystrinsky. These deposits are in a paragenetic relationship with the Late Jurassic magmatic rocks of the Shakhtama complex. According to the available data, the total resources of gold in these three deposits are estimated to be approximately 443 tons: the Lugokan, Au~53 tons, Cu~302 thousand tons; the Kultuma, Au~121 tons, Cu~587 thousand tons, Fe~33 mln t; the Bystrinsky, Au~269 tons, Cu~2070 thousand tons, Fe~67 mln t. One of the main aims of this work was to reveal the criteria of fertility for the classical porphyry type, based on the specific geochemical features of rock-forming and accessory minerals. A comparison of the obtained results with other data on the large porphyry and skarn deposits of the world showed that the magmatic rocks of the Bystrinsky massif, specifically porphyry species dated 159.6–158.6 Ma, are potentially ore-bearing for the porphyry type mineralization. The magmatic rocks that widely occur at the Lugokan and Kultuma deposits are most close to the Fe-skarn deposits. The best indicators of the magma fertility for the porphyry rocks are Ce/Ce*, Eu/Eu*, Yb/Dy, (Ce/Nd)/Y in zircons. Thus, magmatic rocks characterized by Ce/Ce* > 100, Eu/Eu* > 0.4, Yb/Dy > 5.0 and (Ce/Nd)/Y > 0.01 may be classified as high fertile for the classical porphyry mineralization in Eastern Transbaikalia. The plagioclase and biotite chemistry data also showed that the magmatic rocks that occurred at the Bystrinsky deposit are the most fertile for the porphyry type mineralization. The magmatic rocks classified as ore-bearing porphyry type have Al* > 1 in plagioclase, high values of IV(F) and IV(F/Cl) and low ratios of X(F)/X(OH) in biotites. The assessment of the metal fertility of magmatic rocks is most effective in combination with data on both the composition of rock-forming and accessory minerals. The obtained data may be used to develop the methods of prediction and search for gold, copper and iron mineralization.
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spelling doaj.art-e25c408322d9426084542f34e57f394a2023-11-23T14:49:32ZengMDPI AGMinerals2075-163X2021-12-011215010.3390/min12010050Rock-Forming (Biotite and Plagioclase) and Accessory (Zircon) Minerals Geochemistry as an Indicator of the Metal Fertility of Magmas by the Example of Au-Cu-Fe-Skarn Deposits in Eastern TransbaikaliaYury O. Redin0Anna A. Redina1Viktor P. Mokrushnikov2Alexandra V. Malyutina3Vladislav F. Dultsev4Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Akademika Koptyuga Avenue 3, 630090 Novosibirsk, RussiaSobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Akademika Koptyuga Avenue 3, 630090 Novosibirsk, RussiaSobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Akademika Koptyuga Avenue 3, 630090 Novosibirsk, RussiaSobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Akademika Koptyuga Avenue 3, 630090 Novosibirsk, RussiaSobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Akademika Koptyuga Avenue 3, 630090 Novosibirsk, RussiaMany gold and gold-bearing complex deposits related to the Late Jurassic and Early Cretaceous magmatism are known in Eastern Transbaikalia. The largest deposits are the Lugokan, the Kultuma and the Bystrinsky. These deposits are in a paragenetic relationship with the Late Jurassic magmatic rocks of the Shakhtama complex. According to the available data, the total resources of gold in these three deposits are estimated to be approximately 443 tons: the Lugokan, Au~53 tons, Cu~302 thousand tons; the Kultuma, Au~121 tons, Cu~587 thousand tons, Fe~33 mln t; the Bystrinsky, Au~269 tons, Cu~2070 thousand tons, Fe~67 mln t. One of the main aims of this work was to reveal the criteria of fertility for the classical porphyry type, based on the specific geochemical features of rock-forming and accessory minerals. A comparison of the obtained results with other data on the large porphyry and skarn deposits of the world showed that the magmatic rocks of the Bystrinsky massif, specifically porphyry species dated 159.6–158.6 Ma, are potentially ore-bearing for the porphyry type mineralization. The magmatic rocks that widely occur at the Lugokan and Kultuma deposits are most close to the Fe-skarn deposits. The best indicators of the magma fertility for the porphyry rocks are Ce/Ce*, Eu/Eu*, Yb/Dy, (Ce/Nd)/Y in zircons. Thus, magmatic rocks characterized by Ce/Ce* > 100, Eu/Eu* > 0.4, Yb/Dy > 5.0 and (Ce/Nd)/Y > 0.01 may be classified as high fertile for the classical porphyry mineralization in Eastern Transbaikalia. The plagioclase and biotite chemistry data also showed that the magmatic rocks that occurred at the Bystrinsky deposit are the most fertile for the porphyry type mineralization. The magmatic rocks classified as ore-bearing porphyry type have Al* > 1 in plagioclase, high values of IV(F) and IV(F/Cl) and low ratios of X(F)/X(OH) in biotites. The assessment of the metal fertility of magmatic rocks is most effective in combination with data on both the composition of rock-forming and accessory minerals. The obtained data may be used to develop the methods of prediction and search for gold, copper and iron mineralization.https://www.mdpi.com/2075-163X/12/1/50Au-Cu-Fe-skarn depositsporphyry depositsEastern Transbaikaliaplagioclase geochemistrybiotite geochemistryzircon geochemistry
spellingShingle Yury O. Redin
Anna A. Redina
Viktor P. Mokrushnikov
Alexandra V. Malyutina
Vladislav F. Dultsev
Rock-Forming (Biotite and Plagioclase) and Accessory (Zircon) Minerals Geochemistry as an Indicator of the Metal Fertility of Magmas by the Example of Au-Cu-Fe-Skarn Deposits in Eastern Transbaikalia
Minerals
Au-Cu-Fe-skarn deposits
porphyry deposits
Eastern Transbaikalia
plagioclase geochemistry
biotite geochemistry
zircon geochemistry
title Rock-Forming (Biotite and Plagioclase) and Accessory (Zircon) Minerals Geochemistry as an Indicator of the Metal Fertility of Magmas by the Example of Au-Cu-Fe-Skarn Deposits in Eastern Transbaikalia
title_full Rock-Forming (Biotite and Plagioclase) and Accessory (Zircon) Minerals Geochemistry as an Indicator of the Metal Fertility of Magmas by the Example of Au-Cu-Fe-Skarn Deposits in Eastern Transbaikalia
title_fullStr Rock-Forming (Biotite and Plagioclase) and Accessory (Zircon) Minerals Geochemistry as an Indicator of the Metal Fertility of Magmas by the Example of Au-Cu-Fe-Skarn Deposits in Eastern Transbaikalia
title_full_unstemmed Rock-Forming (Biotite and Plagioclase) and Accessory (Zircon) Minerals Geochemistry as an Indicator of the Metal Fertility of Magmas by the Example of Au-Cu-Fe-Skarn Deposits in Eastern Transbaikalia
title_short Rock-Forming (Biotite and Plagioclase) and Accessory (Zircon) Minerals Geochemistry as an Indicator of the Metal Fertility of Magmas by the Example of Au-Cu-Fe-Skarn Deposits in Eastern Transbaikalia
title_sort rock forming biotite and plagioclase and accessory zircon minerals geochemistry as an indicator of the metal fertility of magmas by the example of au cu fe skarn deposits in eastern transbaikalia
topic Au-Cu-Fe-skarn deposits
porphyry deposits
Eastern Transbaikalia
plagioclase geochemistry
biotite geochemistry
zircon geochemistry
url https://www.mdpi.com/2075-163X/12/1/50
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