Bis[trans-difluoridotetrakis(pyridine-κN)chromium(III)] sodium tetrachloridozincate perchlorate from synchrotron data
The title salt, Na[CrF2(C5H5N)4]2[ZnCl4]ClO4, consists of two cationic CrIII complexes, an Na+ cation, one [ZnCl4]2− anion and one ClO4− anion. The CrIII atoms are coordinated by four pyridine (py) N atoms and two F atoms in a trans arrangement, displaying a distorted octahedral geometry. The mean C...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-07-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814014408 |
| _version_ | 1818914705524129792 |
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| author | Dohyun Moon Keon Sang Ryoo Jong-Ha Choi |
| author_facet | Dohyun Moon Keon Sang Ryoo Jong-Ha Choi |
| author_sort | Dohyun Moon |
| collection | DOAJ |
| description | The title salt, Na[CrF2(C5H5N)4]2[ZnCl4]ClO4, consists of two cationic CrIII complexes, an Na+ cation, one [ZnCl4]2− anion and one ClO4− anion. The CrIII atoms are coordinated by four pyridine (py) N atoms and two F atoms in a trans arrangement, displaying a distorted octahedral geometry. The mean Cr—N(py) and Cr—F bond lengths are 2.086 (8) and 1.864 (14) Å, respectively. The [ZnCl4]2− anion has a distorted tetrahedral geometry. The most notable feature of the crystal packing is the formation of weak pyridine–perchlorate C—H...O hydrogen bonds, resulting in supramolecular chains along the b-axis direction. The perchlorate anion was disordered over two sets of sites in a 0.868 (3):0.132 (3) ratio. |
| first_indexed | 2024-12-19T23:50:38Z |
| format | Article |
| id | doaj.art-e2682b07642a4481a67c11ebd5803585 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T23:50:38Z |
| publishDate | 2014-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e2682b07642a4481a67c11ebd58035852022-12-21T20:01:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-07-01707m280m28010.1107/S1600536814014408tk5321Bis[trans-difluoridotetrakis(pyridine-κN)chromium(III)] sodium tetrachloridozincate perchlorate from synchrotron dataDohyun Moon0Keon Sang Ryoo1Jong-Ha Choi2Pohang Accelerator Laboratory, POSTECH, Pohang 790-784, Republic of KoreaDepartment of Chemistry, Andong National University, Andong 760-749, Republic of KoreaDepartment of Chemistry, Andong National University, Andong 760-749, Republic of KoreaThe title salt, Na[CrF2(C5H5N)4]2[ZnCl4]ClO4, consists of two cationic CrIII complexes, an Na+ cation, one [ZnCl4]2− anion and one ClO4− anion. The CrIII atoms are coordinated by four pyridine (py) N atoms and two F atoms in a trans arrangement, displaying a distorted octahedral geometry. The mean Cr—N(py) and Cr—F bond lengths are 2.086 (8) and 1.864 (14) Å, respectively. The [ZnCl4]2− anion has a distorted tetrahedral geometry. The most notable feature of the crystal packing is the formation of weak pyridine–perchlorate C—H...O hydrogen bonds, resulting in supramolecular chains along the b-axis direction. The perchlorate anion was disordered over two sets of sites in a 0.868 (3):0.132 (3) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536814014408crystal structure |
| spellingShingle | Dohyun Moon Keon Sang Ryoo Jong-Ha Choi Bis[trans-difluoridotetrakis(pyridine-κN)chromium(III)] sodium tetrachloridozincate perchlorate from synchrotron data Acta Crystallographica Section E crystal structure |
| title | Bis[trans-difluoridotetrakis(pyridine-κN)chromium(III)] sodium tetrachloridozincate perchlorate from synchrotron data |
| title_full | Bis[trans-difluoridotetrakis(pyridine-κN)chromium(III)] sodium tetrachloridozincate perchlorate from synchrotron data |
| title_fullStr | Bis[trans-difluoridotetrakis(pyridine-κN)chromium(III)] sodium tetrachloridozincate perchlorate from synchrotron data |
| title_full_unstemmed | Bis[trans-difluoridotetrakis(pyridine-κN)chromium(III)] sodium tetrachloridozincate perchlorate from synchrotron data |
| title_short | Bis[trans-difluoridotetrakis(pyridine-κN)chromium(III)] sodium tetrachloridozincate perchlorate from synchrotron data |
| title_sort | bis trans difluoridotetrakis pyridine κn chromium iii sodium tetrachloridozincate perchlorate from synchrotron data |
| topic | crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814014408 |
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