Thermodynamic investigations of the erbium tellurides by EMF method

The work presents the results of a thermodynamic study of the Er-Te system by the method of electromotive forces (EMF) in the temperature range of 300-450 K. From the EMF measurements of the concentration cells relative to the Er and ErTe electrodes, the partial thermodynamic functions of ErTe and E...

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Main Authors: S. Z. Imamaliyeva, I. F. Mehdiyeva, D. B. Taghiyev, M. B. Babanly
Format: Article
Language:English
Published: Vasyl Stefanyk Precarpathian National University 2020-06-01
Series:Фізика і хімія твердого тіла
Subjects:
Online Access:https://journals.pnu.edu.ua/index.php/pcss/article/view/3721
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author S. Z. Imamaliyeva
I. F. Mehdiyeva
D. B. Taghiyev
M. B. Babanly
author_facet S. Z. Imamaliyeva
I. F. Mehdiyeva
D. B. Taghiyev
M. B. Babanly
author_sort S. Z. Imamaliyeva
collection DOAJ
description The work presents the results of a thermodynamic study of the Er-Te system by the method of electromotive forces (EMF) in the temperature range of 300-450 K. From the EMF measurements of the concentration cells relative to the Er and ErTe electrodes, the partial thermodynamic functions of ErTe and Er in the alloys are determined, based on which the standard thermodynamic formation functions and the standard entropies of the intermediate compounds ErTe3, Er2Te3, and ErTe are calculated. A comparative analysis of the obtained data with the literature is carried out.
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spelling doaj.art-e2691d6ecbad4e53a28fcade0c4a012a2022-12-21T18:47:45ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892020-06-0121231231810.15330/pcss.21.2.312-3183721Thermodynamic investigations of the erbium tellurides by EMF methodS. Z. Imamaliyeva0I. F. Mehdiyeva1D. B. Taghiyev2M. B. Babanly3Institute of Catalysis and Inorganic ChemictryInstitute of Catalysis and Inorganic Chemistry named after acad.M.Nagiyev, Azerbaijan National Academy of SciencesInstitute of Catalysis and Inorganic Chemistry named after acad.M.Nagiyev, Azerbaijan National Academy of SciencesInstitute of Catalysis and Inorganic Chemistry named after acad.M.Nagiyev, Azerbaijan National Academy of SciencesThe work presents the results of a thermodynamic study of the Er-Te system by the method of electromotive forces (EMF) in the temperature range of 300-450 K. From the EMF measurements of the concentration cells relative to the Er and ErTe electrodes, the partial thermodynamic functions of ErTe and Er in the alloys are determined, based on which the standard thermodynamic formation functions and the standard entropies of the intermediate compounds ErTe3, Er2Te3, and ErTe are calculated. A comparative analysis of the obtained data with the literature is carried out.https://journals.pnu.edu.ua/index.php/pcss/article/view/3721phase diagramerbium telluridesemf methodthermodynamic functions
spellingShingle S. Z. Imamaliyeva
I. F. Mehdiyeva
D. B. Taghiyev
M. B. Babanly
Thermodynamic investigations of the erbium tellurides by EMF method
Фізика і хімія твердого тіла
phase diagram
erbium tellurides
emf method
thermodynamic functions
title Thermodynamic investigations of the erbium tellurides by EMF method
title_full Thermodynamic investigations of the erbium tellurides by EMF method
title_fullStr Thermodynamic investigations of the erbium tellurides by EMF method
title_full_unstemmed Thermodynamic investigations of the erbium tellurides by EMF method
title_short Thermodynamic investigations of the erbium tellurides by EMF method
title_sort thermodynamic investigations of the erbium tellurides by emf method
topic phase diagram
erbium tellurides
emf method
thermodynamic functions
url https://journals.pnu.edu.ua/index.php/pcss/article/view/3721
work_keys_str_mv AT szimamaliyeva thermodynamicinvestigationsoftheerbiumtelluridesbyemfmethod
AT ifmehdiyeva thermodynamicinvestigationsoftheerbiumtelluridesbyemfmethod
AT dbtaghiyev thermodynamicinvestigationsoftheerbiumtelluridesbyemfmethod
AT mbbabanly thermodynamicinvestigationsoftheerbiumtelluridesbyemfmethod