High‐Resolution Mapping Nanoscale Hydrophobicity for Fine Structures and Dynamic Evolution of Nanomaterial Surface
Nanomaterial hydrophobicity plays a critical role in interfacial phenomena ranging from biological toxicity to chemical reactions. However, it is difficult to figure out the high‐resolution surface hydrophobicity at the nanoscale. Herein, a chemical force microscopy is demonstrated to profile in sit...
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Format: | Article |
Language: | English |
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Wiley-VCH
2024-01-01
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Series: | Small Structures |
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Online Access: | https://doi.org/10.1002/sstr.202300156 |
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author | Yuyao Zhang Xiaoying Zhu Bokai Zhu Chiheng Chu Baoliang Chen |
author_facet | Yuyao Zhang Xiaoying Zhu Bokai Zhu Chiheng Chu Baoliang Chen |
author_sort | Yuyao Zhang |
collection | DOAJ |
description | Nanomaterial hydrophobicity plays a critical role in interfacial phenomena ranging from biological toxicity to chemical reactions. However, it is difficult to figure out the high‐resolution surface hydrophobicity at the nanoscale. Herein, a chemical force microscopy is demonstrated to profile in situ hydrophobicity images with the nanoscale resolution, exhibiting order‐of‐magnitude gain than the traditional methods. This method is utilized to rapidly recognize the spatial fine structure hydrophobicity on Au, graphite, mica, and graphene oxides (GO), enabling the recognition of complicated substances and structures. It is found that the hydrophobicity of GO is opaque and is independent of stacking thickness, which is entirely different from the original graphene. Especially, the regions of wrinkles/edges are first proved to be generally less attractive to the hydrophobic probe than flat areas. This method is used to observe the dynamic evolution of GO hydrophobicity in different aqueous conditions, and is capable of detecting local oxidation variation during interfacial reactions. |
first_indexed | 2024-03-08T15:51:13Z |
format | Article |
id | doaj.art-e29beb3199844e1da7cfbb4ab9de30a1 |
institution | Directory Open Access Journal |
issn | 2688-4062 |
language | English |
last_indexed | 2024-03-08T15:51:13Z |
publishDate | 2024-01-01 |
publisher | Wiley-VCH |
record_format | Article |
series | Small Structures |
spelling | doaj.art-e29beb3199844e1da7cfbb4ab9de30a12024-01-09T05:33:21ZengWiley-VCHSmall Structures2688-40622024-01-0151n/an/a10.1002/sstr.202300156High‐Resolution Mapping Nanoscale Hydrophobicity for Fine Structures and Dynamic Evolution of Nanomaterial SurfaceYuyao Zhang0Xiaoying Zhu1Bokai Zhu2Chiheng Chu3Baoliang Chen4Faculty of Agriculture, Life, and Environmental Sciences Zhejiang University Hangzhou 310058 ChinaFaculty of Agriculture, Life, and Environmental Sciences Zhejiang University Hangzhou 310058 ChinaDepartment of Microbiology and Immunology School of Medicine Stanford University Stanford CA 94305 USAFaculty of Agriculture, Life, and Environmental Sciences Zhejiang University Hangzhou 310058 ChinaFaculty of Agriculture, Life, and Environmental Sciences Zhejiang University Hangzhou 310058 ChinaNanomaterial hydrophobicity plays a critical role in interfacial phenomena ranging from biological toxicity to chemical reactions. However, it is difficult to figure out the high‐resolution surface hydrophobicity at the nanoscale. Herein, a chemical force microscopy is demonstrated to profile in situ hydrophobicity images with the nanoscale resolution, exhibiting order‐of‐magnitude gain than the traditional methods. This method is utilized to rapidly recognize the spatial fine structure hydrophobicity on Au, graphite, mica, and graphene oxides (GO), enabling the recognition of complicated substances and structures. It is found that the hydrophobicity of GO is opaque and is independent of stacking thickness, which is entirely different from the original graphene. Especially, the regions of wrinkles/edges are first proved to be generally less attractive to the hydrophobic probe than flat areas. This method is used to observe the dynamic evolution of GO hydrophobicity in different aqueous conditions, and is capable of detecting local oxidation variation during interfacial reactions.https://doi.org/10.1002/sstr.202300156atomic force microscopychemical force microscopygraphene oxidesnanomaterialssurface hydrophobicity |
spellingShingle | Yuyao Zhang Xiaoying Zhu Bokai Zhu Chiheng Chu Baoliang Chen High‐Resolution Mapping Nanoscale Hydrophobicity for Fine Structures and Dynamic Evolution of Nanomaterial Surface Small Structures atomic force microscopy chemical force microscopy graphene oxides nanomaterials surface hydrophobicity |
title | High‐Resolution Mapping Nanoscale Hydrophobicity for Fine Structures and Dynamic Evolution of Nanomaterial Surface |
title_full | High‐Resolution Mapping Nanoscale Hydrophobicity for Fine Structures and Dynamic Evolution of Nanomaterial Surface |
title_fullStr | High‐Resolution Mapping Nanoscale Hydrophobicity for Fine Structures and Dynamic Evolution of Nanomaterial Surface |
title_full_unstemmed | High‐Resolution Mapping Nanoscale Hydrophobicity for Fine Structures and Dynamic Evolution of Nanomaterial Surface |
title_short | High‐Resolution Mapping Nanoscale Hydrophobicity for Fine Structures and Dynamic Evolution of Nanomaterial Surface |
title_sort | high resolution mapping nanoscale hydrophobicity for fine structures and dynamic evolution of nanomaterial surface |
topic | atomic force microscopy chemical force microscopy graphene oxides nanomaterials surface hydrophobicity |
url | https://doi.org/10.1002/sstr.202300156 |
work_keys_str_mv | AT yuyaozhang highresolutionmappingnanoscalehydrophobicityforfinestructuresanddynamicevolutionofnanomaterialsurface AT xiaoyingzhu highresolutionmappingnanoscalehydrophobicityforfinestructuresanddynamicevolutionofnanomaterialsurface AT bokaizhu highresolutionmappingnanoscalehydrophobicityforfinestructuresanddynamicevolutionofnanomaterialsurface AT chihengchu highresolutionmappingnanoscalehydrophobicityforfinestructuresanddynamicevolutionofnanomaterialsurface AT baoliangchen highresolutionmappingnanoscalehydrophobicityforfinestructuresanddynamicevolutionofnanomaterialsurface |