(Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I)
In the title compound, [Rh(C5H7O2)(C18H14BrP)(CO)], the RhI atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh—O = 2.077 (2) and 2.033 (2) Å] of the acetylacetonate ligand, one carbonyl C atom [Rh&...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-04-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812011944 |
| Summary: | In the title compound, [Rh(C5H7O2)(C18H14BrP)(CO)], the RhI atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh—O = 2.077 (2) and 2.033 (2) Å] of the acetylacetonate ligand, one carbonyl C atom [Rh—C = 1.813 (2) Å] and one P atom [Rh—P = 2.242 (5) Å] of the PPh2(2-BrC6H4) phosphane ligand. Difference electron density maps indicate a disorder of the Br atom over two positions in an approximate 0.95:0.05 ratio. However, this disorder could not be resolved satisfactorily with the present data. |
|---|---|
| ISSN: | 1600-5368 |