(Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I)
In the title compound, [Rh(C5H7O2)(C18H14BrP)(CO)], the RhI atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh—O = 2.077 (2) and 2.033 (2) Å] of the acetylacetonate ligand, one carbonyl C atom [Rh&...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812011944 |
| _version_ | 1819110909954490368 |
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| author | Wade L. Davis Reinout Meijboom |
| author_facet | Wade L. Davis Reinout Meijboom |
| author_sort | Wade L. Davis |
| collection | DOAJ |
| description | In the title compound, [Rh(C5H7O2)(C18H14BrP)(CO)], the RhI atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh—O = 2.077 (2) and 2.033 (2) Å] of the acetylacetonate ligand, one carbonyl C atom [Rh—C = 1.813 (2) Å] and one P atom [Rh—P = 2.242 (5) Å] of the PPh2(2-BrC6H4) phosphane ligand. Difference electron density maps indicate a disorder of the Br atom over two positions in an approximate 0.95:0.05 ratio. However, this disorder could not be resolved satisfactorily with the present data. |
| first_indexed | 2024-12-22T03:49:13Z |
| format | Article |
| id | doaj.art-e2b0e5334d9f4824aa605a95edbc1043 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T03:49:13Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e2b0e5334d9f4824aa605a95edbc10432022-12-21T18:40:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m482m48210.1107/S1600536812011944(Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I)Wade L. DavisReinout MeijboomIn the title compound, [Rh(C5H7O2)(C18H14BrP)(CO)], the RhI atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh—O = 2.077 (2) and 2.033 (2) Å] of the acetylacetonate ligand, one carbonyl C atom [Rh—C = 1.813 (2) Å] and one P atom [Rh—P = 2.242 (5) Å] of the PPh2(2-BrC6H4) phosphane ligand. Difference electron density maps indicate a disorder of the Br atom over two positions in an approximate 0.95:0.05 ratio. However, this disorder could not be resolved satisfactorily with the present data.http://scripts.iucr.org/cgi-bin/paper?S1600536812011944 |
| spellingShingle | Wade L. Davis Reinout Meijboom (Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I) Acta Crystallographica Section E |
| title | (Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I) |
| title_full | (Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I) |
| title_fullStr | (Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I) |
| title_full_unstemmed | (Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I) |
| title_short | (Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I) |
| title_sort | acetylacetonato amp 954 2o o amp 8242 2 bromophenyl diphenylphosphane amp 954 p carbonylrhodium i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812011944 |
| work_keys_str_mv | AT wadeldavis acetylacetonatoamp9542ooamp82422bromophenyldiphenylphosphaneamp954pcarbonylrhodiumi AT reinoutmeijboom acetylacetonatoamp9542ooamp82422bromophenyldiphenylphosphaneamp954pcarbonylrhodiumi |