Reactivity in ion-neutral high density media
The recent development of hybrid traps technology has revolutionized the field of cold chemistry. Recently, new trap configurations have been built in order to explore more involve chemical processes, among them is the three-body recombination involving ions and neutrals. Different ion-neutral-neutr...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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EDP Sciences
2016-01-01
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| Series: | EPJ Web of Conferences |
| Online Access: | http://dx.doi.org/10.1051/epjconf/201611302004 |
| _version_ | 1818741265798266880 |
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| author | Pérez-Ríos J. Greene C. H. |
| author_facet | Pérez-Ríos J. Greene C. H. |
| author_sort | Pérez-Ríos J. |
| collection | DOAJ |
| description | The recent development of hybrid traps technology has revolutionized the field of cold chemistry. Recently, new trap configurations have been built in order to explore more involve chemical processes, among them is the three-body recombination involving ions and neutrals. Different ion-neutral-neutral reactions at low collision energies: 0.1 mK - 10 mK, are studied by means of a very recent method for classical trajectory calculations in hyperspherical coordinates for treating three-body collisions [J. Pérez-Ríos, S. Ragole, J. Wang and C. H. Greene, J. Chem. Phys. 140, 044307 (2014)]. On the other hand a classically derived threshold law is obtained and numerically confirmed. The derived threshold law predicts molecular ions should dominate over molecular neutrals as the most products formed. |
| first_indexed | 2024-12-18T01:53:53Z |
| format | Article |
| id | doaj.art-e2b959115ffa4db7af77c341ccdf29d9 |
| institution | Directory Open Access Journal |
| issn | 2100-014X |
| language | English |
| last_indexed | 2024-12-18T01:53:53Z |
| publishDate | 2016-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | EPJ Web of Conferences |
| spelling | doaj.art-e2b959115ffa4db7af77c341ccdf29d92022-12-21T21:24:58ZengEDP SciencesEPJ Web of Conferences2100-014X2016-01-011130200410.1051/epjconf/201611302004epjconf_fb2016_02004Reactivity in ion-neutral high density mediaPérez-Ríos J.0Greene C. H.1Department of Physics and Astronomy, Purdue UniversityDepartment of Physics and Astronomy, Purdue UniversityThe recent development of hybrid traps technology has revolutionized the field of cold chemistry. Recently, new trap configurations have been built in order to explore more involve chemical processes, among them is the three-body recombination involving ions and neutrals. Different ion-neutral-neutral reactions at low collision energies: 0.1 mK - 10 mK, are studied by means of a very recent method for classical trajectory calculations in hyperspherical coordinates for treating three-body collisions [J. Pérez-Ríos, S. Ragole, J. Wang and C. H. Greene, J. Chem. Phys. 140, 044307 (2014)]. On the other hand a classically derived threshold law is obtained and numerically confirmed. The derived threshold law predicts molecular ions should dominate over molecular neutrals as the most products formed.http://dx.doi.org/10.1051/epjconf/201611302004 |
| spellingShingle | Pérez-Ríos J. Greene C. H. Reactivity in ion-neutral high density media EPJ Web of Conferences |
| title | Reactivity in ion-neutral high density media |
| title_full | Reactivity in ion-neutral high density media |
| title_fullStr | Reactivity in ion-neutral high density media |
| title_full_unstemmed | Reactivity in ion-neutral high density media |
| title_short | Reactivity in ion-neutral high density media |
| title_sort | reactivity in ion neutral high density media |
| url | http://dx.doi.org/10.1051/epjconf/201611302004 |
| work_keys_str_mv | AT perezriosj reactivityinionneutralhighdensitymedia AT greenech reactivityinionneutralhighdensitymedia |