Ruthenium indenylidene “1st generation” olefin metathesis catalysts containing triisopropyl phosphite
The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1st generation” cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stab...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2015-09-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.11.166 |
| _version_ | 1823941674263379968 |
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| author | Stefano Guidone Fady Nahra Alexandra M. Z. Slawin Catherine S. J. Cazin |
| author_facet | Stefano Guidone Fady Nahra Alexandra M. Z. Slawin Catherine S. J. Cazin |
| author_sort | Stefano Guidone |
| collection | DOAJ |
| description | The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1st generation” cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stability and reactivity. Experimental data underline the importance of synergistic effects between phosphites and L-type ligands. |
| first_indexed | 2024-12-17T04:30:19Z |
| format | Article |
| id | doaj.art-e2bcf92bd9744a79b298f7611b576549 |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-17T04:30:19Z |
| publishDate | 2015-09-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-e2bcf92bd9744a79b298f7611b5765492022-12-21T22:03:34ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972015-09-011111520152710.3762/bjoc.11.1661860-5397-11-166Ruthenium indenylidene “1st generation” olefin metathesis catalysts containing triisopropyl phosphiteStefano Guidone0Fady Nahra1Alexandra M. Z. Slawin2Catherine S. J. Cazin3EaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK, KY16 9ST, UKEaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK, KY16 9ST, UKEaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK, KY16 9ST, UKEaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK, KY16 9ST, UKThe reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1st generation” cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stability and reactivity. Experimental data underline the importance of synergistic effects between phosphites and L-type ligands.https://doi.org/10.3762/bjoc.11.1661st generationindenylidenemetathesisphosphiteruthenium |
| spellingShingle | Stefano Guidone Fady Nahra Alexandra M. Z. Slawin Catherine S. J. Cazin Ruthenium indenylidene “1st generation” olefin metathesis catalysts containing triisopropyl phosphite Beilstein Journal of Organic Chemistry 1st generation indenylidene metathesis phosphite ruthenium |
| title | Ruthenium indenylidene “1st generation” olefin metathesis catalysts containing triisopropyl phosphite |
| title_full | Ruthenium indenylidene “1st generation” olefin metathesis catalysts containing triisopropyl phosphite |
| title_fullStr | Ruthenium indenylidene “1st generation” olefin metathesis catalysts containing triisopropyl phosphite |
| title_full_unstemmed | Ruthenium indenylidene “1st generation” olefin metathesis catalysts containing triisopropyl phosphite |
| title_short | Ruthenium indenylidene “1st generation” olefin metathesis catalysts containing triisopropyl phosphite |
| title_sort | ruthenium indenylidene 1st generation olefin metathesis catalysts containing triisopropyl phosphite |
| topic | 1st generation indenylidene metathesis phosphite ruthenium |
| url | https://doi.org/10.3762/bjoc.11.166 |
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