Ruthenium indenylidene “1st generation” olefin metathesis catalysts containing triisopropyl phosphite

The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1st generation” cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stab...

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Bibliographic Details
Main Authors: Stefano Guidone, Fady Nahra, Alexandra M. Z. Slawin, Catherine S. J. Cazin
Format: Article
Language:English
Published: Beilstein-Institut 2015-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.11.166