Poly[di-μ5-adipato-κ4O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8]tricobalt(II)]
In the title polymer, [Co3(C6H8O4)3(C19H12N4)2]n, two adipate dianions (C6H8O42−) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-chelate...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-05-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808010738 |
| Summary: | In the title polymer, [Co3(C6H8O4)3(C19H12N4)2]n, two adipate dianions (C6H8O42−) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-chelated CoII ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N—H...O hydrogen bonds. |
|---|---|
| ISSN: | 1600-5368 |