Poly[di-μ5-adipato-κ4O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8]tricobalt(II)]
In the title polymer, [Co3(C6H8O4)3(C19H12N4)2]n, two adipate dianions (C6H8O42−) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-chelate...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808010738 |
| _version_ | 1818500192711737344 |
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| author | Seik Weng Ng Ge-Yang Wang Rui Zhou Mao-Liang Xu |
| author_facet | Seik Weng Ng Ge-Yang Wang Rui Zhou Mao-Liang Xu |
| author_sort | Seik Weng Ng |
| collection | DOAJ |
| description | In the title polymer, [Co3(C6H8O4)3(C19H12N4)2]n, two adipate dianions (C6H8O42−) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-chelated CoII ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N—H...O hydrogen bonds. |
| first_indexed | 2024-12-10T20:39:30Z |
| format | Article |
| id | doaj.art-e2c18e4946a34897bdced165a4c35a98 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:39:30Z |
| publishDate | 2008-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e2c18e4946a34897bdced165a4c35a982022-12-22T01:34:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m710m71110.1107/S1600536808010738Poly[di-μ5-adipato-κ4O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8]tricobalt(II)]Seik Weng NgGe-Yang WangRui ZhouMao-Liang XuIn the title polymer, [Co3(C6H8O4)3(C19H12N4)2]n, two adipate dianions (C6H8O42−) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-chelated CoII ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808010738 |
| spellingShingle | Seik Weng Ng Ge-Yang Wang Rui Zhou Mao-Liang Xu Poly[di-μ5-adipato-κ4O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8]tricobalt(II)] Acta Crystallographica Section E |
| title | Poly[di-μ5-adipato-κ4O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8]tricobalt(II)] |
| title_full | Poly[di-μ5-adipato-κ4O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8]tricobalt(II)] |
| title_fullStr | Poly[di-μ5-adipato-κ4O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8]tricobalt(II)] |
| title_full_unstemmed | Poly[di-μ5-adipato-κ4O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8]tricobalt(II)] |
| title_short | Poly[di-μ5-adipato-κ4O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8]tricobalt(II)] |
| title_sort | poly di 956 5 adipato 954 4o o 8242 o 8242 8242 o 8242 8242 8242 o 8242 8242 8242 956 4 adipato 954 4o o 8242 o 8242 8242 o 8242 8242 8242 bis 2 phenyl 1h 1 3 7 8 tetraazacyclopenta l phenanthrene 954 2n7 n8 tricobalt ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808010738 |
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