Bis[μ-3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole]bis[dichloridocopper(II)]

Bis[μ-3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole]bis[dichloridocopper(II)]

The asymmetric unit of the title compound, [Cu2Cl4(C15H14N4)2], contains two halves of two centrosymmetric dinuclear molecules, A and B. The conformations of the two crystallographically independent molecules are slightly different: in A, the Cu...Cu separation is 4.174 (9) &...

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Bibliographic Details
Main Authors: Zuoxiang Wang, Chunyi Liu, Xiaoming Zhang, Xiaoning Gong
Format: Article
Language:English
Published: International Union of Crystallography 2009-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680804035X
Description
Summary:The asymmetric unit of the title compound, [Cu2Cl4(C15H14N4)2], contains two halves of two centrosymmetric dinuclear molecules, A and B. The conformations of the two crystallographically independent molecules are slightly different: in A, the Cu...Cu separation is 4.174 (9) Å and the dihedral angle between the triazole and phenyl rings is 74.23 (11)°; these values are 4.137 (9) Å and 68.58 (13)°, respectively, in B. In each molecule, the copper(II) ions have a distorted trigonal–bipyramidal coordination geometry with a CuCl2NN′N′′ chromophore. The crystal packing exhibits weak intermolecular C—H...Cl interactions.
ISSN:1600-5368

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