Impact of Solid Hydrocarbon on the Composition of Fluid Phase at the Subduction (Experimental Simulation)

Experiments conducted in the olivine–serpentine–anthracene–metal (FeNi) system have shown that the recrystallization of olivines occurs under substantially reduced conditions with active participation of hydrocarbons, especially paraffins; moreover, their amount increases with increasing pressure an...

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Bibliographic Details
Main Authors: Anatoly Tomilenko, Valeriy Sonin, Taras Bul’bak, Egor Zhimulev, Tatiana Timina, Aleksey Chepurov, Elena Shaparenko, Anatoly Chepurov
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Minerals
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Online Access:https://www.mdpi.com/2075-163X/13/5/618
Description
Summary:Experiments conducted in the olivine–serpentine–anthracene–metal (FeNi) system have shown that the recrystallization of olivines occurs under substantially reduced conditions with active participation of hydrocarbons, especially paraffins; moreover, their amount increases with increasing pressure and temperature. During the decomposition of serpentine, a large amount of water is released; therefore, the fluid at relatively low P-T parameters (2 GPa, 1100 °C) has mainly water–hydrocarbon composition. With an increase in pressure up to 3–4.5 GPa and temperature up to 1300–1400 °C, the composition of the fluid changes greatly towards an increase in the relative amount of hydrocarbons, while the main share is occupied by light (C1–C4) aliphatic hydrocarbons. Therefore, a biogenic material with a carbon–hydrogen composition can make a certain contribution to the carbon budget in subduction processes when falling into the subduction zones and may affect the oxygen fugitivity in the subducted slab.
ISSN:2075-163X