Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions

The processing of a polyelectrolyte (whose functionality is derived from its ionized functional groups) into a nanofiber may improve its functionality and yield multiple functionalities. However, the electrospinning of nanofibers from polyelectrolytes is imperfect because polyelectrolytes differ con...

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Main Author: Dohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka Hanagata
Format: Article
Language:English
Published: Taylor & Francis Group 2012-01-01
Series:Science and Technology of Advanced Materials
Online Access:http://iopscience.iop.org/1468-6996/13/1/015003
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author Dohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka Hanagata
author_facet Dohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka Hanagata
author_sort Dohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka Hanagata
collection DOAJ
description The processing of a polyelectrolyte (whose functionality is derived from its ionized functional groups) into a nanofiber may improve its functionality and yield multiple functionalities. However, the electrospinning of nanofibers from polyelectrolytes is imperfect because polyelectrolytes differ considerably from neutral polymers in their rheological properties. In our study, we attempt to solve this problem by applying a voltage of opposite polarity to charges on a polyelectrolyte. The application of this 'countervoltage' can temporarily mask or screen a specific rheological property of the polyelectrolyte, making it behave as a neutral polymer. This approach can significantly contribute to the development of new functional nanofiber materials.
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spelling doaj.art-e2f9ab8a2d034b5b86713b874138a5842022-12-22T00:45:43ZengTaylor & Francis GroupScience and Technology of Advanced Materials1468-69961878-55142012-01-01131015003Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutionsDohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka HanagataThe processing of a polyelectrolyte (whose functionality is derived from its ionized functional groups) into a nanofiber may improve its functionality and yield multiple functionalities. However, the electrospinning of nanofibers from polyelectrolytes is imperfect because polyelectrolytes differ considerably from neutral polymers in their rheological properties. In our study, we attempt to solve this problem by applying a voltage of opposite polarity to charges on a polyelectrolyte. The application of this 'countervoltage' can temporarily mask or screen a specific rheological property of the polyelectrolyte, making it behave as a neutral polymer. This approach can significantly contribute to the development of new functional nanofiber materials.http://iopscience.iop.org/1468-6996/13/1/015003
spellingShingle Dohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka Hanagata
Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions
Science and Technology of Advanced Materials
title Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions
title_full Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions
title_fullStr Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions
title_full_unstemmed Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions
title_short Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions
title_sort transient charge masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions
url http://iopscience.iop.org/1468-6996/13/1/015003
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