Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions
The processing of a polyelectrolyte (whose functionality is derived from its ionized functional groups) into a nanofiber may improve its functionality and yield multiple functionalities. However, the electrospinning of nanofibers from polyelectrolytes is imperfect because polyelectrolytes differ con...
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Format: | Article |
Language: | English |
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Taylor & Francis Group
2012-01-01
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Series: | Science and Technology of Advanced Materials |
Online Access: | http://iopscience.iop.org/1468-6996/13/1/015003 |
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author | Dohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka Hanagata |
author_facet | Dohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka Hanagata |
author_sort | Dohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka Hanagata |
collection | DOAJ |
description | The processing of a polyelectrolyte (whose functionality is derived from its ionized functional groups) into a nanofiber may improve its functionality and yield multiple functionalities. However, the electrospinning of nanofibers from polyelectrolytes is imperfect because polyelectrolytes differ considerably from neutral polymers in their rheological properties. In our study, we attempt to solve this problem by applying a voltage of opposite polarity to charges on a polyelectrolyte. The application of this 'countervoltage' can temporarily mask or screen a specific rheological property of the polyelectrolyte, making it behave as a neutral polymer. This approach can significantly contribute to the development of new functional nanofiber materials. |
first_indexed | 2024-12-11T23:42:13Z |
format | Article |
id | doaj.art-e2f9ab8a2d034b5b86713b874138a584 |
institution | Directory Open Access Journal |
issn | 1468-6996 1878-5514 |
language | English |
last_indexed | 2024-12-11T23:42:13Z |
publishDate | 2012-01-01 |
publisher | Taylor & Francis Group |
record_format | Article |
series | Science and Technology of Advanced Materials |
spelling | doaj.art-e2f9ab8a2d034b5b86713b874138a5842022-12-22T00:45:43ZengTaylor & Francis GroupScience and Technology of Advanced Materials1468-69961878-55142012-01-01131015003Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutionsDohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka HanagataThe processing of a polyelectrolyte (whose functionality is derived from its ionized functional groups) into a nanofiber may improve its functionality and yield multiple functionalities. However, the electrospinning of nanofibers from polyelectrolytes is imperfect because polyelectrolytes differ considerably from neutral polymers in their rheological properties. In our study, we attempt to solve this problem by applying a voltage of opposite polarity to charges on a polyelectrolyte. The application of this 'countervoltage' can temporarily mask or screen a specific rheological property of the polyelectrolyte, making it behave as a neutral polymer. This approach can significantly contribute to the development of new functional nanofiber materials.http://iopscience.iop.org/1468-6996/13/1/015003 |
spellingShingle | Dohiko Terada, Hisatoshi Kobayashi, Kun Zhang, Ashutosh Tiwari, Chiaki Yoshikawa and Nobutaka Hanagata Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions Science and Technology of Advanced Materials |
title | Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions |
title_full | Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions |
title_fullStr | Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions |
title_full_unstemmed | Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions |
title_short | Transient charge-masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions |
title_sort | transient charge masking effect of applied voltage on electrospinning of pure chitosan nanofibers from aqueous solutions |
url | http://iopscience.iop.org/1468-6996/13/1/015003 |
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