Facile Synthesis of Nano-Flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> Heterojunction as Photocatalyst for Degradation RhB

Photocatalysis is a hopeful technology to solve various environmental problems, but it is still a technical task to produce large-scale photocatalysts in a simple and sustainable way. Here, nano-flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composites were...

Full description

Bibliographic Details
Main Authors: Mingjun Wang, Che Li, Bingfang Liu, Wenzhen Qin, Yu Xie
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/2/882
_version_ 1827622851125968896
author Mingjun Wang
Che Li
Bingfang Liu
Wenzhen Qin
Yu Xie
author_facet Mingjun Wang
Che Li
Bingfang Liu
Wenzhen Qin
Yu Xie
author_sort Mingjun Wang
collection DOAJ
description Photocatalysis is a hopeful technology to solve various environmental problems, but it is still a technical task to produce large-scale photocatalysts in a simple and sustainable way. Here, nano-flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composites were prepared via a facile solvothermal method, and the photocatalytic performances of β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composites with different Bi/Ti molar ratios were studied. The nano-flower Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composites were studied by SEM, XRD, XPS, BET, and PL. The PL result proved that the construction of staggered heterojunction enhanced the separation efficiency of carriers. The degradation RhB was applied to study the photocatalytic performances of prepared materials. The results showed that the degradation efficiency of RhB increased from 61.2% to 99.6% when the molar ratio of Bi/Ti was 2.1%. It is a mesoporous approach to enhance photocatalytic properties by forming heterojunction in Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composites, which increases the separation efficiency of the generated carriers and improves photocatalytic properties. The photoactivity of the Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> has no evident changes after the fifth recovery, indicating that the Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composite has distinguished stability.
first_indexed 2024-03-09T11:33:58Z
format Article
id doaj.art-e31ed08863af4990b1d0d25074e6d80b
institution Directory Open Access Journal
issn 1420-3049
language English
last_indexed 2024-03-09T11:33:58Z
publishDate 2023-01-01
publisher MDPI AG
record_format Article
series Molecules
spelling doaj.art-e31ed08863af4990b1d0d25074e6d80b2023-11-30T23:46:17ZengMDPI AGMolecules1420-30492023-01-0128288210.3390/molecules28020882Facile Synthesis of Nano-Flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> Heterojunction as Photocatalyst for Degradation RhBMingjun Wang0Che Li1Bingfang Liu2Wenzhen Qin3Yu Xie4Academy of Art & Design, Nanchang Institute of Technology, Nanchang 330044, ChinaCollege of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, ChinaAcademy of Art & Design, Nanchang Institute of Technology, Nanchang 330044, ChinaCollege of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, ChinaCollege of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, ChinaPhotocatalysis is a hopeful technology to solve various environmental problems, but it is still a technical task to produce large-scale photocatalysts in a simple and sustainable way. Here, nano-flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composites were prepared via a facile solvothermal method, and the photocatalytic performances of β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composites with different Bi/Ti molar ratios were studied. The nano-flower Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composites were studied by SEM, XRD, XPS, BET, and PL. The PL result proved that the construction of staggered heterojunction enhanced the separation efficiency of carriers. The degradation RhB was applied to study the photocatalytic performances of prepared materials. The results showed that the degradation efficiency of RhB increased from 61.2% to 99.6% when the molar ratio of Bi/Ti was 2.1%. It is a mesoporous approach to enhance photocatalytic properties by forming heterojunction in Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composites, which increases the separation efficiency of the generated carriers and improves photocatalytic properties. The photoactivity of the Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> has no evident changes after the fifth recovery, indicating that the Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> composite has distinguished stability.https://www.mdpi.com/1420-3049/28/2/882Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub>heterojunctionphotocatalystsdegradation RhB
spellingShingle Mingjun Wang
Che Li
Bingfang Liu
Wenzhen Qin
Yu Xie
Facile Synthesis of Nano-Flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> Heterojunction as Photocatalyst for Degradation RhB
Molecules
Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub>
heterojunction
photocatalysts
degradation RhB
title Facile Synthesis of Nano-Flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> Heterojunction as Photocatalyst for Degradation RhB
title_full Facile Synthesis of Nano-Flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> Heterojunction as Photocatalyst for Degradation RhB
title_fullStr Facile Synthesis of Nano-Flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> Heterojunction as Photocatalyst for Degradation RhB
title_full_unstemmed Facile Synthesis of Nano-Flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> Heterojunction as Photocatalyst for Degradation RhB
title_short Facile Synthesis of Nano-Flower β-Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> Heterojunction as Photocatalyst for Degradation RhB
title_sort facile synthesis of nano flower β bi sub 2 sub o sub 3 sub tio sub 2 sub heterojunction as photocatalyst for degradation rhb
topic Bi<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub>
heterojunction
photocatalysts
degradation RhB
url https://www.mdpi.com/1420-3049/28/2/882
work_keys_str_mv AT mingjunwang facilesynthesisofnanoflowerbbisub2subosub3subtiosub2subheterojunctionasphotocatalystfordegradationrhb
AT cheli facilesynthesisofnanoflowerbbisub2subosub3subtiosub2subheterojunctionasphotocatalystfordegradationrhb
AT bingfangliu facilesynthesisofnanoflowerbbisub2subosub3subtiosub2subheterojunctionasphotocatalystfordegradationrhb
AT wenzhenqin facilesynthesisofnanoflowerbbisub2subosub3subtiosub2subheterojunctionasphotocatalystfordegradationrhb
AT yuxie facilesynthesisofnanoflowerbbisub2subosub3subtiosub2subheterojunctionasphotocatalystfordegradationrhb