Performance and Ethanol Crossover of Passive Direct Ethanol Fuel Cell Stack

A dual-cell passive direct ethanol fuel cell (DEFC) stack with single ethanol tank was designed and tested to obtain the voltage requirement of electronics and to reduce weight and volume for practical applications. Ethanol crossover and cell performance were determined at different ethanol feed con...

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Main Author: Ekdharmasuit Panuwat
Format: Article
Language:English
Published: EDP Sciences 2020-01-01
Series:E3S Web of Conferences
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/01/e3sconf_ri2c2019_01008.pdf
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author Ekdharmasuit Panuwat
author_facet Ekdharmasuit Panuwat
author_sort Ekdharmasuit Panuwat
collection DOAJ
description A dual-cell passive direct ethanol fuel cell (DEFC) stack with single ethanol tank was designed and tested to obtain the voltage requirement of electronics and to reduce weight and volume for practical applications. Ethanol crossover and cell performance were determined at different ethanol feed concentrations. Characterization techniques were used, including a cell polarization tests, a long-term steady voltage discharging measurement, and an electrochemical impedance spectroscopy (EIS). It was found that, before long-term steady voltage test, the optimum ethanol feed concentration was 2 M. The ethanol crossover increases with ethanol concentration increment over 2 M and the ethanol crossover exhibited a negative effect on the open circuit voltage (OCV) and the cell performance. However, after a long-term steady voltage test, the best ethanol feed concentration was changed to 3 M. It was due to the difference of current density discharged during long-term operation. It can also be found that, after long-term steady voltage test, the cell resistance was apparently reduced. It may be explained that the mass transport of both liquid fuel and air as a reactant in the cell structure reached equilibrium during long-term operation.
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spelling doaj.art-e347174d208e4c87bc1ecd2d8d840b3a2022-12-21T21:31:24ZengEDP SciencesE3S Web of Conferences2267-12422020-01-011410100810.1051/e3sconf/202014101008e3sconf_ri2c2019_01008Performance and Ethanol Crossover of Passive Direct Ethanol Fuel Cell StackEkdharmasuit PanuwatA dual-cell passive direct ethanol fuel cell (DEFC) stack with single ethanol tank was designed and tested to obtain the voltage requirement of electronics and to reduce weight and volume for practical applications. Ethanol crossover and cell performance were determined at different ethanol feed concentrations. Characterization techniques were used, including a cell polarization tests, a long-term steady voltage discharging measurement, and an electrochemical impedance spectroscopy (EIS). It was found that, before long-term steady voltage test, the optimum ethanol feed concentration was 2 M. The ethanol crossover increases with ethanol concentration increment over 2 M and the ethanol crossover exhibited a negative effect on the open circuit voltage (OCV) and the cell performance. However, after a long-term steady voltage test, the best ethanol feed concentration was changed to 3 M. It was due to the difference of current density discharged during long-term operation. It can also be found that, after long-term steady voltage test, the cell resistance was apparently reduced. It may be explained that the mass transport of both liquid fuel and air as a reactant in the cell structure reached equilibrium during long-term operation.https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/01/e3sconf_ri2c2019_01008.pdf
spellingShingle Ekdharmasuit Panuwat
Performance and Ethanol Crossover of Passive Direct Ethanol Fuel Cell Stack
E3S Web of Conferences
title Performance and Ethanol Crossover of Passive Direct Ethanol Fuel Cell Stack
title_full Performance and Ethanol Crossover of Passive Direct Ethanol Fuel Cell Stack
title_fullStr Performance and Ethanol Crossover of Passive Direct Ethanol Fuel Cell Stack
title_full_unstemmed Performance and Ethanol Crossover of Passive Direct Ethanol Fuel Cell Stack
title_short Performance and Ethanol Crossover of Passive Direct Ethanol Fuel Cell Stack
title_sort performance and ethanol crossover of passive direct ethanol fuel cell stack
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/01/e3sconf_ri2c2019_01008.pdf
work_keys_str_mv AT ekdharmasuitpanuwat performanceandethanolcrossoverofpassivedirectethanolfuelcellstack