Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities

The chemical reduction method was used to synthesize nickel oxide particles (NiO) and NiO supported on titanium dioxide (NiO/TiO2 nanocomposite). The composites were characterized through scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD) and Fourier transform...

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Main Authors: Tamanna Gul, Shujaat Ahmad, Idrees Khan, Ibrahim Khan, Mazen Almehmadi, Ahad Amer Alsaiari, Mamdouh Allahyani, Khalid Saeed
Format: Article
Language:English
Published: Elsevier 2023-07-01
Series:Journal of Saudi Chemical Society
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610323000583
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author Tamanna Gul
Shujaat Ahmad
Idrees Khan
Ibrahim Khan
Mazen Almehmadi
Ahad Amer Alsaiari
Mamdouh Allahyani
Khalid Saeed
author_facet Tamanna Gul
Shujaat Ahmad
Idrees Khan
Ibrahim Khan
Mazen Almehmadi
Ahad Amer Alsaiari
Mamdouh Allahyani
Khalid Saeed
author_sort Tamanna Gul
collection DOAJ
description The chemical reduction method was used to synthesize nickel oxide particles (NiO) and NiO supported on titanium dioxide (NiO/TiO2 nanocomposite). The composites were characterized through scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD) and Fourier transform infrared (FTIR) analysis. The morphological investigation showed that pseudocubic NiO are present in dispersed as well as agglomerated forms. Whereas NiO particles (<200 nm) are evenly deposited over the surface of TiO2 in NiO/TiO2 composite. The formation of NiO and NiO/TiO2 was also verified by XRD analysis. The synthesized NiO and NiO/TiO2 were used as photocatalysts for the degradation of Orange II (OII) dye. According to the degradation investigation, both NiO and NiO/TiO2 composite degraded OII dye more efficiently when exposed to UV light. The results indicated that NiO degraded 93% and NiO/TiO2 composites degraded approximately 96% of OII dye within 30 min. Both photocatalysts are highly sustainable and have significant OII dye degradation recyclability. Moreover, NiO and NiO/TiO2 exhibited promising bioactivities (antioxidant activity of 80%) against the pathogenic bacteria Citrobacter and Providencia, which is comparable with the standard ascorbic acid (88%).
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spelling doaj.art-e3518cec931f48e9b389d641226806252023-08-25T04:23:48ZengElsevierJournal of Saudi Chemical Society1319-61032023-07-01274101654Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activitiesTamanna Gul0Shujaat Ahmad1Idrees Khan2Ibrahim Khan3Mazen Almehmadi4Ahad Amer Alsaiari5Mamdouh Allahyani6Khalid Saeed7Department of Chemistry, Bacha Khan University, Charsadda, KP, PakistanDepartment of Pharmacy, Shaheed Benazir Bhutto University, Sheringal, KPK, PakistanDepartment of Chemistry, Bacha Khan University, Charsadda, KP, PakistanSchool of Chemical Engineering and Materials Science, Chung-Ang University, 84 Heukseok-ro, 06974 Seoul, South KoreaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Chemistry, Bacha Khan University, Charsadda, KP, Pakistan; Corresponding author.The chemical reduction method was used to synthesize nickel oxide particles (NiO) and NiO supported on titanium dioxide (NiO/TiO2 nanocomposite). The composites were characterized through scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD) and Fourier transform infrared (FTIR) analysis. The morphological investigation showed that pseudocubic NiO are present in dispersed as well as agglomerated forms. Whereas NiO particles (<200 nm) are evenly deposited over the surface of TiO2 in NiO/TiO2 composite. The formation of NiO and NiO/TiO2 was also verified by XRD analysis. The synthesized NiO and NiO/TiO2 were used as photocatalysts for the degradation of Orange II (OII) dye. According to the degradation investigation, both NiO and NiO/TiO2 composite degraded OII dye more efficiently when exposed to UV light. The results indicated that NiO degraded 93% and NiO/TiO2 composites degraded approximately 96% of OII dye within 30 min. Both photocatalysts are highly sustainable and have significant OII dye degradation recyclability. Moreover, NiO and NiO/TiO2 exhibited promising bioactivities (antioxidant activity of 80%) against the pathogenic bacteria Citrobacter and Providencia, which is comparable with the standard ascorbic acid (88%).http://www.sciencedirect.com/science/article/pii/S1319610323000583TiO2PhotodegradationOrange IIBioactivityAntioxidant activity
spellingShingle Tamanna Gul
Shujaat Ahmad
Idrees Khan
Ibrahim Khan
Mazen Almehmadi
Ahad Amer Alsaiari
Mamdouh Allahyani
Khalid Saeed
Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities
Journal of Saudi Chemical Society
TiO2
Photodegradation
Orange II
Bioactivity
Antioxidant activity
title Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities
title_full Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities
title_fullStr Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities
title_full_unstemmed Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities
title_short Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities
title_sort photodegradation of orange ii dye using p n junction nio tio2 composite and assessment of its biological activities
topic TiO2
Photodegradation
Orange II
Bioactivity
Antioxidant activity
url http://www.sciencedirect.com/science/article/pii/S1319610323000583
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