Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities
The chemical reduction method was used to synthesize nickel oxide particles (NiO) and NiO supported on titanium dioxide (NiO/TiO2 nanocomposite). The composites were characterized through scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD) and Fourier transform...
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Elsevier
2023-07-01
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Series: | Journal of Saudi Chemical Society |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S1319610323000583 |
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author | Tamanna Gul Shujaat Ahmad Idrees Khan Ibrahim Khan Mazen Almehmadi Ahad Amer Alsaiari Mamdouh Allahyani Khalid Saeed |
author_facet | Tamanna Gul Shujaat Ahmad Idrees Khan Ibrahim Khan Mazen Almehmadi Ahad Amer Alsaiari Mamdouh Allahyani Khalid Saeed |
author_sort | Tamanna Gul |
collection | DOAJ |
description | The chemical reduction method was used to synthesize nickel oxide particles (NiO) and NiO supported on titanium dioxide (NiO/TiO2 nanocomposite). The composites were characterized through scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD) and Fourier transform infrared (FTIR) analysis. The morphological investigation showed that pseudocubic NiO are present in dispersed as well as agglomerated forms. Whereas NiO particles (<200 nm) are evenly deposited over the surface of TiO2 in NiO/TiO2 composite. The formation of NiO and NiO/TiO2 was also verified by XRD analysis. The synthesized NiO and NiO/TiO2 were used as photocatalysts for the degradation of Orange II (OII) dye. According to the degradation investigation, both NiO and NiO/TiO2 composite degraded OII dye more efficiently when exposed to UV light. The results indicated that NiO degraded 93% and NiO/TiO2 composites degraded approximately 96% of OII dye within 30 min. Both photocatalysts are highly sustainable and have significant OII dye degradation recyclability. Moreover, NiO and NiO/TiO2 exhibited promising bioactivities (antioxidant activity of 80%) against the pathogenic bacteria Citrobacter and Providencia, which is comparable with the standard ascorbic acid (88%). |
first_indexed | 2024-03-12T13:27:56Z |
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id | doaj.art-e3518cec931f48e9b389d64122680625 |
institution | Directory Open Access Journal |
issn | 1319-6103 |
language | English |
last_indexed | 2024-03-12T13:27:56Z |
publishDate | 2023-07-01 |
publisher | Elsevier |
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series | Journal of Saudi Chemical Society |
spelling | doaj.art-e3518cec931f48e9b389d641226806252023-08-25T04:23:48ZengElsevierJournal of Saudi Chemical Society1319-61032023-07-01274101654Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activitiesTamanna Gul0Shujaat Ahmad1Idrees Khan2Ibrahim Khan3Mazen Almehmadi4Ahad Amer Alsaiari5Mamdouh Allahyani6Khalid Saeed7Department of Chemistry, Bacha Khan University, Charsadda, KP, PakistanDepartment of Pharmacy, Shaheed Benazir Bhutto University, Sheringal, KPK, PakistanDepartment of Chemistry, Bacha Khan University, Charsadda, KP, PakistanSchool of Chemical Engineering and Materials Science, Chung-Ang University, 84 Heukseok-ro, 06974 Seoul, South KoreaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Chemistry, Bacha Khan University, Charsadda, KP, Pakistan; Corresponding author.The chemical reduction method was used to synthesize nickel oxide particles (NiO) and NiO supported on titanium dioxide (NiO/TiO2 nanocomposite). The composites were characterized through scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD) and Fourier transform infrared (FTIR) analysis. The morphological investigation showed that pseudocubic NiO are present in dispersed as well as agglomerated forms. Whereas NiO particles (<200 nm) are evenly deposited over the surface of TiO2 in NiO/TiO2 composite. The formation of NiO and NiO/TiO2 was also verified by XRD analysis. The synthesized NiO and NiO/TiO2 were used as photocatalysts for the degradation of Orange II (OII) dye. According to the degradation investigation, both NiO and NiO/TiO2 composite degraded OII dye more efficiently when exposed to UV light. The results indicated that NiO degraded 93% and NiO/TiO2 composites degraded approximately 96% of OII dye within 30 min. Both photocatalysts are highly sustainable and have significant OII dye degradation recyclability. Moreover, NiO and NiO/TiO2 exhibited promising bioactivities (antioxidant activity of 80%) against the pathogenic bacteria Citrobacter and Providencia, which is comparable with the standard ascorbic acid (88%).http://www.sciencedirect.com/science/article/pii/S1319610323000583TiO2PhotodegradationOrange IIBioactivityAntioxidant activity |
spellingShingle | Tamanna Gul Shujaat Ahmad Idrees Khan Ibrahim Khan Mazen Almehmadi Ahad Amer Alsaiari Mamdouh Allahyani Khalid Saeed Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities Journal of Saudi Chemical Society TiO2 Photodegradation Orange II Bioactivity Antioxidant activity |
title | Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities |
title_full | Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities |
title_fullStr | Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities |
title_full_unstemmed | Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities |
title_short | Photodegradation of orange II dye using p-n junction NiO/TiO2 composite, and assessment of its biological activities |
title_sort | photodegradation of orange ii dye using p n junction nio tio2 composite and assessment of its biological activities |
topic | TiO2 Photodegradation Orange II Bioactivity Antioxidant activity |
url | http://www.sciencedirect.com/science/article/pii/S1319610323000583 |
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