Fatty Acid Methyl Esters from the Herbal Industry Wastes as a Potential Feedstock for Biodiesel Production

Due to thegrowing awareness of fossil fuel depletion and environmental issues, biodiesel alternative fuel is currently of substantial interest. This research assessed herbal industry wastes as a potential resource for biodiesel production for the first time. Fatty acid methyl esters (FAMEs), obtaine...

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Main Authors: Aneta Sienkiewicz, Alicja Piotrowska-Niczyporuk, Andrzej Bajguz
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/13/14/3702
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author Aneta Sienkiewicz
Alicja Piotrowska-Niczyporuk
Andrzej Bajguz
author_facet Aneta Sienkiewicz
Alicja Piotrowska-Niczyporuk
Andrzej Bajguz
author_sort Aneta Sienkiewicz
collection DOAJ
description Due to thegrowing awareness of fossil fuel depletion and environmental issues, biodiesel alternative fuel is currently of substantial interest. This research assessed herbal industry wastes as a potential resource for biodiesel production for the first time. Fatty acid methyl esters (FAMEs), obtained in the transesterification reaction, were extracted from the herbal samples by ultrasound-assisted extraction and identified withgas chromatography-mass spectrometry in the selected ion monitoring mode. The presence of at least 20 (e.g., in chamomile and chicory) FAMEs, up to 31 in nettle and senna, was reported. The unsaturated FAMEs were found in higher amounts than saturated. Linoleic acidwas the major polyunsaturated FAME in herbal wastes, while palmitic acid was the major saturated FAME. The highest content of FAMEs was identified in rye bran, Figure tea, and chicory. According to the cetane number prediction, BS EN 14214:2012+A2:2019, and hierarchical clustering on principal components (HCPC)wastes from, e.g., nettle, sage, and senna, are the most suitable in biodiesel production with fuel properties acceptable by the EuropeanStandards.Principal component analysis and HCPC allowed to classify and groupsimilar plants according to their FAMEs content; however, additional studies of herbal biofuel properties are needed.
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spelling doaj.art-e390acac9ea14662b662a281281915202023-11-20T07:10:28ZengMDPI AGEnergies1996-10732020-07-011314370210.3390/en13143702Fatty Acid Methyl Esters from the Herbal Industry Wastes as a Potential Feedstock for Biodiesel ProductionAneta Sienkiewicz0Alicja Piotrowska-Niczyporuk1Andrzej Bajguz2Department of Agri-Food Engineering and Environmental Management, Bialystok University of Technology, Wiejska 45E Street, 15-351 Bialystok, PolandDepartment of Plant Biology and Ecology, University of Bialystok, Ciolkowskiego 1J Street, 15-245 Bialystok, PolandDepartment of Plant Biology and Ecology, University of Bialystok, Ciolkowskiego 1J Street, 15-245 Bialystok, PolandDue to thegrowing awareness of fossil fuel depletion and environmental issues, biodiesel alternative fuel is currently of substantial interest. This research assessed herbal industry wastes as a potential resource for biodiesel production for the first time. Fatty acid methyl esters (FAMEs), obtained in the transesterification reaction, were extracted from the herbal samples by ultrasound-assisted extraction and identified withgas chromatography-mass spectrometry in the selected ion monitoring mode. The presence of at least 20 (e.g., in chamomile and chicory) FAMEs, up to 31 in nettle and senna, was reported. The unsaturated FAMEs were found in higher amounts than saturated. Linoleic acidwas the major polyunsaturated FAME in herbal wastes, while palmitic acid was the major saturated FAME. The highest content of FAMEs was identified in rye bran, Figure tea, and chicory. According to the cetane number prediction, BS EN 14214:2012+A2:2019, and hierarchical clustering on principal components (HCPC)wastes from, e.g., nettle, sage, and senna, are the most suitable in biodiesel production with fuel properties acceptable by the EuropeanStandards.Principal component analysis and HCPC allowed to classify and groupsimilar plants according to their FAMEs content; however, additional studies of herbal biofuel properties are needed.https://www.mdpi.com/1996-1073/13/14/3702biofuelcetane number predictionFAMEHCPCherbal clusteringpostproduction plant wastes
spellingShingle Aneta Sienkiewicz
Alicja Piotrowska-Niczyporuk
Andrzej Bajguz
Fatty Acid Methyl Esters from the Herbal Industry Wastes as a Potential Feedstock for Biodiesel Production
Energies
biofuel
cetane number prediction
FAME
HCPC
herbal clustering
postproduction plant wastes
title Fatty Acid Methyl Esters from the Herbal Industry Wastes as a Potential Feedstock for Biodiesel Production
title_full Fatty Acid Methyl Esters from the Herbal Industry Wastes as a Potential Feedstock for Biodiesel Production
title_fullStr Fatty Acid Methyl Esters from the Herbal Industry Wastes as a Potential Feedstock for Biodiesel Production
title_full_unstemmed Fatty Acid Methyl Esters from the Herbal Industry Wastes as a Potential Feedstock for Biodiesel Production
title_short Fatty Acid Methyl Esters from the Herbal Industry Wastes as a Potential Feedstock for Biodiesel Production
title_sort fatty acid methyl esters from the herbal industry wastes as a potential feedstock for biodiesel production
topic biofuel
cetane number prediction
FAME
HCPC
herbal clustering
postproduction plant wastes
url https://www.mdpi.com/1996-1073/13/14/3702
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