Synthesis and luminescence investigation of mirror symmetric europium and dysprosium co-doped barium vanadate phosphor for optoelectronic applications

Over the past few decades, there has been a growing and insatiable demand for power consumption across the globe. In this multifaceted landscape of optoelectronic applications, the role of lighting, especially in the form of white-light LEDs stands as a vital component of our daily existence. These...

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Main Authors: N. Venkatesh Bharathi, K. Sakthipandi, S. Monisha
Format: Article
Language:English
Published: Elsevier 2024-06-01
Series:Chemical Physics Impact
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2667022424000501
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author N. Venkatesh Bharathi
K. Sakthipandi
S. Monisha
author_facet N. Venkatesh Bharathi
K. Sakthipandi
S. Monisha
author_sort N. Venkatesh Bharathi
collection DOAJ
description Over the past few decades, there has been a growing and insatiable demand for power consumption across the globe. In this multifaceted landscape of optoelectronic applications, the role of lighting, especially in the form of white-light LEDs stands as a vital component of our daily existence. These fourth-generation lighting devices have garnered significant attention from researchers due to their fundamental role in addressing the ever-increasing energy demands. This study investigates into the synthesis of phosphors Ba2V2O7:0.04Dy3+,0.03Eu3+ and Ba2V2O7:0.03Eu3+,0.04Dy3+ using the hydrothermal method, employing techniques such as X-ray diffraction and diffused reflectance spectra photoluminescence spectra for characterization. X-ray diffraction clearly affirms the successful integration/ incorporation of Dy3+ and Eu3+ ions within the Ba2+ lattice of the Ba2V2O7 host, without inducing any structural alterations. The diffused reflectance spectra reveal the emergence of a meta-stable state bridging the valence and conduction bands, a consequence of the Dy3+ and Eu3+ ion substitution in the Ba2V2O7 phosphor lattice. Photoluminescence spectra demonstrate that the synthesized phosphors emit a bluish-white color upon excitation. This study provides these groundbreaking lighting devices have demonstrated their spirit in a diverse array of applications.
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spelling doaj.art-e397d5b745b147a299b739cae61483022024-02-04T04:47:00ZengElsevierChemical Physics Impact2667-02242024-06-018100506Synthesis and luminescence investigation of mirror symmetric europium and dysprosium co-doped barium vanadate phosphor for optoelectronic applicationsN. Venkatesh Bharathi0K. Sakthipandi1S. Monisha2PG and Research Department of Physics, Mannar Thirumalai Naicker College, Madurai, Tamil Nadu 625 004, India; Corresponding authors.Department of Physics, SRM TRP Engineering College, Tiruchirappalli, Tamil Nadu 621 105, India; Corresponding authors.Department of Physics, Vel Tech Rangarajan Dr. Sagunthala R&D Institute of Science and Technology, Avadi, Chennai, Tamil Nadu 600 062, IndiaOver the past few decades, there has been a growing and insatiable demand for power consumption across the globe. In this multifaceted landscape of optoelectronic applications, the role of lighting, especially in the form of white-light LEDs stands as a vital component of our daily existence. These fourth-generation lighting devices have garnered significant attention from researchers due to their fundamental role in addressing the ever-increasing energy demands. This study investigates into the synthesis of phosphors Ba2V2O7:0.04Dy3+,0.03Eu3+ and Ba2V2O7:0.03Eu3+,0.04Dy3+ using the hydrothermal method, employing techniques such as X-ray diffraction and diffused reflectance spectra photoluminescence spectra for characterization. X-ray diffraction clearly affirms the successful integration/ incorporation of Dy3+ and Eu3+ ions within the Ba2+ lattice of the Ba2V2O7 host, without inducing any structural alterations. The diffused reflectance spectra reveal the emergence of a meta-stable state bridging the valence and conduction bands, a consequence of the Dy3+ and Eu3+ ion substitution in the Ba2V2O7 phosphor lattice. Photoluminescence spectra demonstrate that the synthesized phosphors emit a bluish-white color upon excitation. This study provides these groundbreaking lighting devices have demonstrated their spirit in a diverse array of applications.http://www.sciencedirect.com/science/article/pii/S2667022424000501PhosphorX-ray diffractionDiffused reflectance spectraPhotoluminescence spectra
spellingShingle N. Venkatesh Bharathi
K. Sakthipandi
S. Monisha
Synthesis and luminescence investigation of mirror symmetric europium and dysprosium co-doped barium vanadate phosphor for optoelectronic applications
Chemical Physics Impact
Phosphor
X-ray diffraction
Diffused reflectance spectra
Photoluminescence spectra
title Synthesis and luminescence investigation of mirror symmetric europium and dysprosium co-doped barium vanadate phosphor for optoelectronic applications
title_full Synthesis and luminescence investigation of mirror symmetric europium and dysprosium co-doped barium vanadate phosphor for optoelectronic applications
title_fullStr Synthesis and luminescence investigation of mirror symmetric europium and dysprosium co-doped barium vanadate phosphor for optoelectronic applications
title_full_unstemmed Synthesis and luminescence investigation of mirror symmetric europium and dysprosium co-doped barium vanadate phosphor for optoelectronic applications
title_short Synthesis and luminescence investigation of mirror symmetric europium and dysprosium co-doped barium vanadate phosphor for optoelectronic applications
title_sort synthesis and luminescence investigation of mirror symmetric europium and dysprosium co doped barium vanadate phosphor for optoelectronic applications
topic Phosphor
X-ray diffraction
Diffused reflectance spectra
Photoluminescence spectra
url http://www.sciencedirect.com/science/article/pii/S2667022424000501
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AT ksakthipandi synthesisandluminescenceinvestigationofmirrorsymmetriceuropiumanddysprosiumcodopedbariumvanadatephosphorforoptoelectronicapplications
AT smonisha synthesisandluminescenceinvestigationofmirrorsymmetriceuropiumanddysprosiumcodopedbariumvanadatephosphorforoptoelectronicapplications