On the Klemm model for bistability of mixtures of interacting enantiomers
The solution of the Klemm model for spontaneous chiral stereoselection has been obtained. It is shown that a system whose time-evolution is described by the Klemm model, independently of the initial value of the enantiomeric excess, always reaches a racemic terminal state. In a system described by t...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2001-08-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol66/No8/V66-No8-03.pdf |
| _version_ | 1819203052296470528 |
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| author | IVAN GUTMAN |
| author_facet | IVAN GUTMAN |
| author_sort | IVAN GUTMAN |
| collection | DOAJ |
| description | The solution of the Klemm model for spontaneous chiral stereoselection has been obtained. It is shown that a system whose time-evolution is described by the Klemm model, independently of the initial value of the enantiomeric excess, always reaches a racemic terminal state. In a system described by the Klemm model bistability never occurs. |
| first_indexed | 2024-12-23T04:13:47Z |
| format | Article |
| id | doaj.art-e3c671185e924ab1b7109c9416fef29d |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-23T04:13:47Z |
| publishDate | 2001-08-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-e3c671185e924ab1b7109c9416fef29d2022-12-21T18:00:26ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392001-08-01668517521On the Klemm model for bistability of mixtures of interacting enantiomersIVAN GUTMANThe solution of the Klemm model for spontaneous chiral stereoselection has been obtained. It is shown that a system whose time-evolution is described by the Klemm model, independently of the initial value of the enantiomeric excess, always reaches a racemic terminal state. In a system described by the Klemm model bistability never occurs.http://www.shd.org.yu/HtDocs/SHD/Vol66/No8/V66-No8-03.pdfchiralityhomochiralitybistabilityKlemm modelFrank model |
| spellingShingle | IVAN GUTMAN On the Klemm model for bistability of mixtures of interacting enantiomers Journal of the Serbian Chemical Society chirality homochirality bistability Klemm model Frank model |
| title | On the Klemm model for bistability of mixtures of interacting enantiomers |
| title_full | On the Klemm model for bistability of mixtures of interacting enantiomers |
| title_fullStr | On the Klemm model for bistability of mixtures of interacting enantiomers |
| title_full_unstemmed | On the Klemm model for bistability of mixtures of interacting enantiomers |
| title_short | On the Klemm model for bistability of mixtures of interacting enantiomers |
| title_sort | on the klemm model for bistability of mixtures of interacting enantiomers |
| topic | chirality homochirality bistability Klemm model Frank model |
| url | http://www.shd.org.yu/HtDocs/SHD/Vol66/No8/V66-No8-03.pdf |
| work_keys_str_mv | AT ivangutman ontheklemmmodelforbistabilityofmixturesofinteractingenantiomers |