Stereoselective Synthesis of Multisubstituted Cyclohexanes by Reaction of Conjugated Enynones with Malononitrile in the Presence of LDA

Stereoselective Synthesis of Multisubstituted Cyclohexanes by Reaction of Conjugated Enynones with Malononitrile in the Presence of LDA

Reaction of linear conjugated enynones, 1,5-diarylpent-2-en-4-yn-1-ones, with malononitrile in the presence of lithium diisopropylamide LDA, as a base, in THF at room temperature for 3–7 h resulted in the formation of the product of dimerization, multisubstituted polyfunctional cyclohexanes, 4-aryl-...

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Bibliographic Details
Main Authors: Anastasiya V. Igushkina, Alexander A. Golovanov, Irina A. Boyarskaya, Ilya E. Kolesnikov, Aleksander V. Vasilyev
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Molecules
Subjects:
conjugated enynones
malononitrile
cyclohexanes
carbanionic reactions
photoluminescent compounds
Online Access:https://www.mdpi.com/1420-3049/25/24/5920

Internet

https://www.mdpi.com/1420-3049/25/24/5920

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