Application of the rhodamine derivative LPDQ fluorescent probe for the detection of zinc white in oil paints

By modifying the structure of pyridoxal phosphate, an “on–off” rhodamine fluorescent probe LPDQ with a new structure was synthesized. NMR, IR, and mass spectrometries characterized the structures of the probes. The LPDQ–Zn2+ system had been successfully constructed by the characteristic absorption p...

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Main Authors: Zhankun Wang, Zhixin Ren, Yuguang Lv
Format: Article
Language:English
Published: AIP Publishing LLC 2024-03-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/5.0182973
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author Zhankun Wang
Zhixin Ren
Yuguang Lv
author_facet Zhankun Wang
Zhixin Ren
Yuguang Lv
author_sort Zhankun Wang
collection DOAJ
description By modifying the structure of pyridoxal phosphate, an “on–off” rhodamine fluorescent probe LPDQ with a new structure was synthesized. NMR, IR, and mass spectrometries characterized the structures of the probes. The LPDQ–Zn2+ system had been successfully constructed by the characteristic absorption peaks of the ultraviolet spectrum, and the experiments were carried out to investigate the ion fluorescence selectivity, cell imaging, reversibility, ion concentration, linear range, precision, and accuracy. The LPDQ reached the detection limit of 0.8 × 10−6 mol/l at 1 × 10−5–8.5 × 10−5 mol/l. The content of Zn2+ in the zinc gluconate sample was determined. According to the experimental data, the fluorescent probe LPDQ in this experiment has good performance and can be used to detect Zn2+ in water and oil paintings.
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spelling doaj.art-e3f9dd75dabe49d1b6cf914e71f60b2b2024-04-02T20:29:17ZengAIP Publishing LLCAIP Advances2158-32262024-03-01143035022035022-1010.1063/5.0182973Application of the rhodamine derivative LPDQ fluorescent probe for the detection of zinc white in oil paintsZhankun Wang0Zhixin Ren1Yuguang Lv2Harbin University, 109 Zhongxing Dadao, Nangang District, Harbin City, Heilongjiang Province, ChinaCollege of Pharmacy, Jiamusi University, 258 Xuefu Street, Jiamusi City, Heilongjiang Province, ChinaCollege of Pharmacy, Jiamusi University, 258 Xuefu Street, Jiamusi City, Heilongjiang Province, ChinaBy modifying the structure of pyridoxal phosphate, an “on–off” rhodamine fluorescent probe LPDQ with a new structure was synthesized. NMR, IR, and mass spectrometries characterized the structures of the probes. The LPDQ–Zn2+ system had been successfully constructed by the characteristic absorption peaks of the ultraviolet spectrum, and the experiments were carried out to investigate the ion fluorescence selectivity, cell imaging, reversibility, ion concentration, linear range, precision, and accuracy. The LPDQ reached the detection limit of 0.8 × 10−6 mol/l at 1 × 10−5–8.5 × 10−5 mol/l. The content of Zn2+ in the zinc gluconate sample was determined. According to the experimental data, the fluorescent probe LPDQ in this experiment has good performance and can be used to detect Zn2+ in water and oil paintings.http://dx.doi.org/10.1063/5.0182973
spellingShingle Zhankun Wang
Zhixin Ren
Yuguang Lv
Application of the rhodamine derivative LPDQ fluorescent probe for the detection of zinc white in oil paints
AIP Advances
title Application of the rhodamine derivative LPDQ fluorescent probe for the detection of zinc white in oil paints
title_full Application of the rhodamine derivative LPDQ fluorescent probe for the detection of zinc white in oil paints
title_fullStr Application of the rhodamine derivative LPDQ fluorescent probe for the detection of zinc white in oil paints
title_full_unstemmed Application of the rhodamine derivative LPDQ fluorescent probe for the detection of zinc white in oil paints
title_short Application of the rhodamine derivative LPDQ fluorescent probe for the detection of zinc white in oil paints
title_sort application of the rhodamine derivative lpdq fluorescent probe for the detection of zinc white in oil paints
url http://dx.doi.org/10.1063/5.0182973
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