Enhanced specific capacitance, structural, optical, and morphological study of carbon ions incorporated into the lattice of ZrCuO2 nanoparticle synthesized by hydrothermal method
In this study, ZrCuO2 nanoparticles were made using the hydrothermal method and potassium hydroxide as the precipitant. The material was irradiated with 500 keV carbon (C++) ions at doses of 1 × 1014, 1 × 1016, and 1 × 1018 ions/cm2. The ZrCuO2 nanoparticles exhibited cubic crystal structures with c...
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| Format: | Article |
| Language: | English |
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Elsevier
2024-04-01
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| Series: | Hybrid Advances |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2773207X24000319 |
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| author | Azmat Hussain Fawad Ali Hafiz Hammad Ahmed Abbas khan Jamil ur Rehman Siddiqi Imosobomeh L. Ikhioya |
| author_facet | Azmat Hussain Fawad Ali Hafiz Hammad Ahmed Abbas khan Jamil ur Rehman Siddiqi Imosobomeh L. Ikhioya |
| author_sort | Azmat Hussain |
| collection | DOAJ |
| description | In this study, ZrCuO2 nanoparticles were made using the hydrothermal method and potassium hydroxide as the precipitant. The material was irradiated with 500 keV carbon (C++) ions at doses of 1 × 1014, 1 × 1016, and 1 × 1018 ions/cm2. The ZrCuO2 nanoparticles exhibited cubic crystal structures with clear peaks on different orientation planes, both before and after being irradiated with carbon ions (C++). By incorporating carbon ions, the peak intensity and crystallinity of CuO nanostructures were enhanced. The non-irradiated micrographs display groups of tiny pebbles, whereas the carbon ion irradiated ZrCuO2 nanoparticles show flake-like structures. The material became denser because of carbon ion irradiation, which increased the carrier concentration. The absorption rate increase of the material reveals the impact of a carbon ion on irradiated ZrCuO2 nanoparticles. The absorbance of ZrCuO2 nanoparticles is enhanced through carbon ion implantation. The material has a bandgap energy of 1.95 eV without irradiation. The bandgap energy range of the irradiated material is 1.55–1.82 eV. The energy bandgap of the synthesized material was reduced because of carbon ion irradiation. The ZrCuO2 nanoparticle electrode with a specific capacitance value of 225 F/g. The electrodes prepared at 500 keV carbon (C++) ions with dosages of 1 × 1014, 1 × 1016, and 1 × 1018 ions/cm2 yielded specific capacitance values of 275 F/g, 300 F/g, and 312.5 F/g, respectively. |
| first_indexed | 2024-04-24T08:59:09Z |
| format | Article |
| id | doaj.art-e402f8edf8244f1fb05d4de070664250 |
| institution | Directory Open Access Journal |
| issn | 2773-207X |
| language | English |
| last_indexed | 2024-04-24T08:59:09Z |
| publishDate | 2024-04-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Hybrid Advances |
| spelling | doaj.art-e402f8edf8244f1fb05d4de0706642502024-04-16T04:10:09ZengElsevierHybrid Advances2773-207X2024-04-015100170Enhanced specific capacitance, structural, optical, and morphological study of carbon ions incorporated into the lattice of ZrCuO2 nanoparticle synthesized by hydrothermal methodAzmat Hussain0Fawad Ali1Hafiz Hammad Ahmed2 Abbas khan3Jamil ur Rehman Siddiqi4Imosobomeh L. Ikhioya5National Centre for Physics, Quaid-i-Azam University Campus, Islamabad, 44000, Pakistan; Department of Physics, Hazara University Mansehra, PakistanNational Centre for Physics, Quaid-i-Azam University Campus, Islamabad, 44000, Pakistan; National Institute of Vacuum Science and Technology, Islamabad, 44000, PakistanNational Centre for Physics, Quaid-i-Azam University Campus, Islamabad, 44000, Pakistan; Centre of Excellence in Solid State Physics, University of the Punjab, Lahore, PakistanNational Centre for Physics, Quaid-i-Azam University Campus, Islamabad, 44000, Pakistan; Department of Physics, Abbottabad University of Science and Technology, Abbottabad, PakistanNational Centre for Physics, Quaid-i-Azam University Campus, Islamabad, 44000, Pakistan; Department of Physics, Abbottabad University of Science and Technology, Abbottabad, PakistanNational Centre for Physics, Quaid-i-Azam University Campus, Islamabad, 44000, Pakistan; Department of Physics and Astronomy, University of Nigeria, Nsukka, 410001, Nigeria; Corresponding author. Department of Physics and Astronomy, University of Nigeria, Nsukka, 410001, Nigeria.In this study, ZrCuO2 nanoparticles were made using the hydrothermal method and potassium hydroxide as the precipitant. The material was irradiated with 500 keV carbon (C++) ions at doses of 1 × 1014, 1 × 1016, and 1 × 1018 ions/cm2. The ZrCuO2 nanoparticles exhibited cubic crystal structures with clear peaks on different orientation planes, both before and after being irradiated with carbon ions (C++). By incorporating carbon ions, the peak intensity and crystallinity of CuO nanostructures were enhanced. The non-irradiated micrographs display groups of tiny pebbles, whereas the carbon ion irradiated ZrCuO2 nanoparticles show flake-like structures. The material became denser because of carbon ion irradiation, which increased the carrier concentration. The absorption rate increase of the material reveals the impact of a carbon ion on irradiated ZrCuO2 nanoparticles. The absorbance of ZrCuO2 nanoparticles is enhanced through carbon ion implantation. The material has a bandgap energy of 1.95 eV without irradiation. The bandgap energy range of the irradiated material is 1.55–1.82 eV. The energy bandgap of the synthesized material was reduced because of carbon ion irradiation. The ZrCuO2 nanoparticle electrode with a specific capacitance value of 225 F/g. The electrodes prepared at 500 keV carbon (C++) ions with dosages of 1 × 1014, 1 × 1016, and 1 × 1018 ions/cm2 yielded specific capacitance values of 275 F/g, 300 F/g, and 312.5 F/g, respectively.http://www.sciencedirect.com/science/article/pii/S2773207X24000319HydrothermalCarbon ionsBandgapZirconiumCopper oxide |
| spellingShingle | Azmat Hussain Fawad Ali Hafiz Hammad Ahmed Abbas khan Jamil ur Rehman Siddiqi Imosobomeh L. Ikhioya Enhanced specific capacitance, structural, optical, and morphological study of carbon ions incorporated into the lattice of ZrCuO2 nanoparticle synthesized by hydrothermal method Hybrid Advances Hydrothermal Carbon ions Bandgap Zirconium Copper oxide |
| title | Enhanced specific capacitance, structural, optical, and morphological study of carbon ions incorporated into the lattice of ZrCuO2 nanoparticle synthesized by hydrothermal method |
| title_full | Enhanced specific capacitance, structural, optical, and morphological study of carbon ions incorporated into the lattice of ZrCuO2 nanoparticle synthesized by hydrothermal method |
| title_fullStr | Enhanced specific capacitance, structural, optical, and morphological study of carbon ions incorporated into the lattice of ZrCuO2 nanoparticle synthesized by hydrothermal method |
| title_full_unstemmed | Enhanced specific capacitance, structural, optical, and morphological study of carbon ions incorporated into the lattice of ZrCuO2 nanoparticle synthesized by hydrothermal method |
| title_short | Enhanced specific capacitance, structural, optical, and morphological study of carbon ions incorporated into the lattice of ZrCuO2 nanoparticle synthesized by hydrothermal method |
| title_sort | enhanced specific capacitance structural optical and morphological study of carbon ions incorporated into the lattice of zrcuo2 nanoparticle synthesized by hydrothermal method |
| topic | Hydrothermal Carbon ions Bandgap Zirconium Copper oxide |
| url | http://www.sciencedirect.com/science/article/pii/S2773207X24000319 |
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