Conductance Current and Space Charge Characteristics of SiO<sub>2</sub>/MMT/LDPE Micro-Nano Composites

Low-density polyethylene (LDPE) is one of the most comprehensive products used as insulation materials in power equipment. How to improve its dielectric properties by doping inorganic particles in LDPE has always been the focus of many researchers. In this paper, silica (SiO<sub>2</sub>)...

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Main Authors: Hongtao Jiang, Xiaohong Zhang, Junguo Gao, Ning Guo
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/18/4119
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author Hongtao Jiang
Xiaohong Zhang
Junguo Gao
Ning Guo
author_facet Hongtao Jiang
Xiaohong Zhang
Junguo Gao
Ning Guo
author_sort Hongtao Jiang
collection DOAJ
description Low-density polyethylene (LDPE) is one of the most comprehensive products used as insulation materials in power equipment. How to improve its dielectric properties by doping inorganic particles in LDPE has always been the focus of many researchers. In this paper, silica (SiO<sub>2</sub>) particles and montmorillonite (MMT) particles were added to LDPE, the order of adding particles was changed, and different micro-nano composites was made. The crystallization characteristics of composites were analyzed, the curves of the conductance current with the change of field intensity were analyzed, and the space charge distribution of each material were investigated. The results of crystallization show that the crystalline properties and crystallinity of the composites are higher than the matrix LDPE, the addition of SiO<sub>2</sub> particles increases the composites’ crystallinity significantly, and the intercellular spacing of micro-nano composites is the smallest among all materials. The curve of conductance current versus electric field intensity shows that the tightness of the crystal structure can effectively hinder the movement of the molecular chain, inhibit carrier migration, while shortening the free travel of electrons, thereby reducing the electric conduction current of the material. The experimental results of the space charge accumulation curve further show that the compact crystal structure of the material is beneficial to the dissipation of space charge in the dielectric.
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spelling doaj.art-e406e9700c764951adf4f72c1ee8c7942023-11-20T13:57:54ZengMDPI AGMaterials1996-19442020-09-011318411910.3390/ma13184119Conductance Current and Space Charge Characteristics of SiO<sub>2</sub>/MMT/LDPE Micro-Nano CompositesHongtao Jiang0Xiaohong Zhang1Junguo Gao2Ning Guo3Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, ChinaKey Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, ChinaKey Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, ChinaKey Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, ChinaLow-density polyethylene (LDPE) is one of the most comprehensive products used as insulation materials in power equipment. How to improve its dielectric properties by doping inorganic particles in LDPE has always been the focus of many researchers. In this paper, silica (SiO<sub>2</sub>) particles and montmorillonite (MMT) particles were added to LDPE, the order of adding particles was changed, and different micro-nano composites was made. The crystallization characteristics of composites were analyzed, the curves of the conductance current with the change of field intensity were analyzed, and the space charge distribution of each material were investigated. The results of crystallization show that the crystalline properties and crystallinity of the composites are higher than the matrix LDPE, the addition of SiO<sub>2</sub> particles increases the composites’ crystallinity significantly, and the intercellular spacing of micro-nano composites is the smallest among all materials. The curve of conductance current versus electric field intensity shows that the tightness of the crystal structure can effectively hinder the movement of the molecular chain, inhibit carrier migration, while shortening the free travel of electrons, thereby reducing the electric conduction current of the material. The experimental results of the space charge accumulation curve further show that the compact crystal structure of the material is beneficial to the dissipation of space charge in the dielectric.https://www.mdpi.com/1996-1944/13/18/4119micro- and nanoparticlesadding ordercrystallizationconduction currentspace charge
spellingShingle Hongtao Jiang
Xiaohong Zhang
Junguo Gao
Ning Guo
Conductance Current and Space Charge Characteristics of SiO<sub>2</sub>/MMT/LDPE Micro-Nano Composites
Materials
micro- and nanoparticles
adding order
crystallization
conduction current
space charge
title Conductance Current and Space Charge Characteristics of SiO<sub>2</sub>/MMT/LDPE Micro-Nano Composites
title_full Conductance Current and Space Charge Characteristics of SiO<sub>2</sub>/MMT/LDPE Micro-Nano Composites
title_fullStr Conductance Current and Space Charge Characteristics of SiO<sub>2</sub>/MMT/LDPE Micro-Nano Composites
title_full_unstemmed Conductance Current and Space Charge Characteristics of SiO<sub>2</sub>/MMT/LDPE Micro-Nano Composites
title_short Conductance Current and Space Charge Characteristics of SiO<sub>2</sub>/MMT/LDPE Micro-Nano Composites
title_sort conductance current and space charge characteristics of sio sub 2 sub mmt ldpe micro nano composites
topic micro- and nanoparticles
adding order
crystallization
conduction current
space charge
url https://www.mdpi.com/1996-1944/13/18/4119
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AT xiaohongzhang conductancecurrentandspacechargecharacteristicsofsiosub2submmtldpemicronanocomposites
AT junguogao conductancecurrentandspacechargecharacteristicsofsiosub2submmtldpemicronanocomposites
AT ningguo conductancecurrentandspacechargecharacteristicsofsiosub2submmtldpemicronanocomposites