Synthetic Studies on Optically Active Schiff-base Ligands Derived from Condensation of 2-Hydroxyacetophenone and Chiral Diamines

Three optically active Schiff-base ligands have been prepared by condensation of 2-hydroxyacetophenone with (1R,2R)-(-)-1,2-diaminocyclohexane, (1S,2S)-(-)-1,2-diphenylethylenediamine or R-(+)-2,2’-diamino-1,1’-binaphthalene, respectively. The products have been characterized by their IR,...

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Main Authors: Zhuo Zheng, Wen Tao Gao
Format: Article
Language:English
Published: MDPI AG 2002-07-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/7/7/511/
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author Zhuo Zheng
Wen Tao Gao
author_facet Zhuo Zheng
Wen Tao Gao
author_sort Zhuo Zheng
collection DOAJ
description Three optically active Schiff-base ligands have been prepared by condensation of 2-hydroxyacetophenone with (1R,2R)-(-)-1,2-diaminocyclohexane, (1S,2S)-(-)-1,2-diphenylethylenediamine or R-(+)-2,2’-diamino-1,1’-binaphthalene, respectively. The products have been characterized by their IR, 1H- and 13C-NMR spectra.
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spelling doaj.art-e436f4a674da4d84b8b2892479ea1fd82022-12-21T21:14:38ZengMDPI AGMolecules1420-30492002-07-017751151610.3390/70700511Synthetic Studies on Optically Active Schiff-base Ligands Derived from Condensation of 2-Hydroxyacetophenone and Chiral DiaminesZhuo ZhengWen Tao GaoThree optically active Schiff-base ligands have been prepared by condensation of 2-hydroxyacetophenone with (1R,2R)-(-)-1,2-diaminocyclohexane, (1S,2S)-(-)-1,2-diphenylethylenediamine or R-(+)-2,2’-diamino-1,1’-binaphthalene, respectively. The products have been characterized by their IR, 1H- and 13C-NMR spectra.http://www.mdpi.com/1420-3049/7/7/511/Schiff-baseligands2-hydroxyacetophenonechiral diamines
spellingShingle Zhuo Zheng
Wen Tao Gao
Synthetic Studies on Optically Active Schiff-base Ligands Derived from Condensation of 2-Hydroxyacetophenone and Chiral Diamines
Molecules
Schiff-base
ligands
2-hydroxyacetophenone
chiral diamines
title Synthetic Studies on Optically Active Schiff-base Ligands Derived from Condensation of 2-Hydroxyacetophenone and Chiral Diamines
title_full Synthetic Studies on Optically Active Schiff-base Ligands Derived from Condensation of 2-Hydroxyacetophenone and Chiral Diamines
title_fullStr Synthetic Studies on Optically Active Schiff-base Ligands Derived from Condensation of 2-Hydroxyacetophenone and Chiral Diamines
title_full_unstemmed Synthetic Studies on Optically Active Schiff-base Ligands Derived from Condensation of 2-Hydroxyacetophenone and Chiral Diamines
title_short Synthetic Studies on Optically Active Schiff-base Ligands Derived from Condensation of 2-Hydroxyacetophenone and Chiral Diamines
title_sort synthetic studies on optically active schiff base ligands derived from condensation of 2 hydroxyacetophenone and chiral diamines
topic Schiff-base
ligands
2-hydroxyacetophenone
chiral diamines
url http://www.mdpi.com/1420-3049/7/7/511/
work_keys_str_mv AT zhuozheng syntheticstudiesonopticallyactiveschiffbaseligandsderivedfromcondensationof2hydroxyacetophenoneandchiraldiamines
AT wentaogao syntheticstudiesonopticallyactiveschiffbaseligandsderivedfromcondensationof2hydroxyacetophenoneandchiraldiamines