Investigating the potential of using solid waste generated from stone cutting factories for phenol removal from wastewater: A study of adsorption kinetics and isotherms
Remarkably toxic, phenol requires efficient elimination from water. This study investigates the utilization of solid waste generated by stone-cutting factories for extracting phenol from wastewater. The solid waste underwent thermal treatment at 105 °C for 3 h for characterization. Batch adsorption...
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Elsevier
2023-12-01
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Series: | Results in Engineering |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2590123023005315 |
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author | Nada Al-Ananzeh Khalid Bani-Melhem Hussam Elddin Khasawneh Muhammad Tawalbeh Zakaria Al-Qodah Ahmad Al-Bodour |
author_facet | Nada Al-Ananzeh Khalid Bani-Melhem Hussam Elddin Khasawneh Muhammad Tawalbeh Zakaria Al-Qodah Ahmad Al-Bodour |
author_sort | Nada Al-Ananzeh |
collection | DOAJ |
description | Remarkably toxic, phenol requires efficient elimination from water. This study investigates the utilization of solid waste generated by stone-cutting factories for extracting phenol from wastewater. The solid waste underwent thermal treatment at 105 °C for 3 h for characterization. Batch adsorption experiments systematically assessed parameters like phenol concentration, adsorbent mass, contact time, temperature, and pH. Optimal removal transpired at pH 7.5, reaching equilibrium within 4 h. Phenol uptake equilibrium values were 8.1, 13.3, 16.2, 20.2, and 28.1 mg/g for initial concentrations of 50, 100, 150, 200, and 300 mg/L, respectively using 1 g of adsorbent at ambient temperature. The Langmuir model fit acceptably, yet the Freundlich model surpassed it. The most suitable kinetics model for phenol adsorption was the pseudo-second-order. The nature of the adsorption process was endothermic. Importantly, this study pioneers the promising application of solid waste generated from stone-cutting factories as an adsorbent material for effective phenol removal, offering a sustainable approach. Notably, no previous study has been conducted on phenol removal from wastewater using this specific adsorbent, rendering this work pivotal in exploring its potential. This solid waste presents an economical, readily available, and environmentally benign material for the adsorption process, expected to exhibit substantial adsorption capacity. |
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id | doaj.art-e43d311d85844ff0983291f5fc6b51cd |
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issn | 2590-1230 |
language | English |
last_indexed | 2024-03-08T21:50:28Z |
publishDate | 2023-12-01 |
publisher | Elsevier |
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series | Results in Engineering |
spelling | doaj.art-e43d311d85844ff0983291f5fc6b51cd2023-12-20T07:35:34ZengElsevierResults in Engineering2590-12302023-12-0120101404Investigating the potential of using solid waste generated from stone cutting factories for phenol removal from wastewater: A study of adsorption kinetics and isothermsNada Al-Ananzeh0Khalid Bani-Melhem1Hussam Elddin Khasawneh2Muhammad Tawalbeh3Zakaria Al-Qodah4Ahmad Al-Bodour5Department of Chemical Engineering, Al-Huson University College, Al-Balqa Applied University, Al-Huson P.O. Box 50, Al-Huson, 21510, JordanWater Technology Unit (WTU), Center for Advanced Materials (CAM), Qatar University, P.O. Box 2713, Doha, Qatar; Corresponding author..Department of Chemical Engineering, Al-Huson University College, Al-Balqa Applied University, Al-Huson P.O. Box 50, Al-Huson, 21510, JordanSustainable and Renewable Energy Engineering Department, University of Sharjah, P.O. Box 27272, Sharjah, United Arab Emirates; Sustainable Energy & Power Systems Research Centre, RISE, University of Sharjah, P.O. Box 27272, Sharjah, United Arab EmiratesChemical Engineering Department, Faculty of Engineering Technology, Al-Balqa Applied University, Marka, P.O. Box 340558, Amman, 11134, JordanChemical and Paper Engineering Department, College of Engineering and Applied Sciences, Western Michigan University, Kalamazoo, MI, 49008-5462, USARemarkably toxic, phenol requires efficient elimination from water. This study investigates the utilization of solid waste generated by stone-cutting factories for extracting phenol from wastewater. The solid waste underwent thermal treatment at 105 °C for 3 h for characterization. Batch adsorption experiments systematically assessed parameters like phenol concentration, adsorbent mass, contact time, temperature, and pH. Optimal removal transpired at pH 7.5, reaching equilibrium within 4 h. Phenol uptake equilibrium values were 8.1, 13.3, 16.2, 20.2, and 28.1 mg/g for initial concentrations of 50, 100, 150, 200, and 300 mg/L, respectively using 1 g of adsorbent at ambient temperature. The Langmuir model fit acceptably, yet the Freundlich model surpassed it. The most suitable kinetics model for phenol adsorption was the pseudo-second-order. The nature of the adsorption process was endothermic. Importantly, this study pioneers the promising application of solid waste generated from stone-cutting factories as an adsorbent material for effective phenol removal, offering a sustainable approach. Notably, no previous study has been conducted on phenol removal from wastewater using this specific adsorbent, rendering this work pivotal in exploring its potential. This solid waste presents an economical, readily available, and environmentally benign material for the adsorption process, expected to exhibit substantial adsorption capacity.http://www.sciencedirect.com/science/article/pii/S2590123023005315Solid wasteStone cutting factoriesWastewater treatmentPhenol removalSolid characterizationAdsorption |
spellingShingle | Nada Al-Ananzeh Khalid Bani-Melhem Hussam Elddin Khasawneh Muhammad Tawalbeh Zakaria Al-Qodah Ahmad Al-Bodour Investigating the potential of using solid waste generated from stone cutting factories for phenol removal from wastewater: A study of adsorption kinetics and isotherms Results in Engineering Solid waste Stone cutting factories Wastewater treatment Phenol removal Solid characterization Adsorption |
title | Investigating the potential of using solid waste generated from stone cutting factories for phenol removal from wastewater: A study of adsorption kinetics and isotherms |
title_full | Investigating the potential of using solid waste generated from stone cutting factories for phenol removal from wastewater: A study of adsorption kinetics and isotherms |
title_fullStr | Investigating the potential of using solid waste generated from stone cutting factories for phenol removal from wastewater: A study of adsorption kinetics and isotherms |
title_full_unstemmed | Investigating the potential of using solid waste generated from stone cutting factories for phenol removal from wastewater: A study of adsorption kinetics and isotherms |
title_short | Investigating the potential of using solid waste generated from stone cutting factories for phenol removal from wastewater: A study of adsorption kinetics and isotherms |
title_sort | investigating the potential of using solid waste generated from stone cutting factories for phenol removal from wastewater a study of adsorption kinetics and isotherms |
topic | Solid waste Stone cutting factories Wastewater treatment Phenol removal Solid characterization Adsorption |
url | http://www.sciencedirect.com/science/article/pii/S2590123023005315 |
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