[μ-Bis(diphenylarsino)methane-1:2κ2As:As′][(4-bromophenyl)diphenylphosphine-3κP]nonacarbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0) chloroform 0.3-solvate
The asymmetric unit of the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C18H14BrP)(CO)9]·0.3CHCl3, contains one molecule of the triangulo-triruthenium complex and one partially occupied disordered chloroform solvent molecule. The bis(diphenylarsino)methane ligand bridges an Ru...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809055287 |
| _version_ | 1818887061902458880 |
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| author | Omar bin Shawkataly Imthyaz Ahmed Khan Chin Sing Yeap Hoong-Kun Fun |
| author_facet | Omar bin Shawkataly Imthyaz Ahmed Khan Chin Sing Yeap Hoong-Kun Fun |
| author_sort | Omar bin Shawkataly |
| collection | DOAJ |
| description | The asymmetric unit of the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C18H14BrP)(CO)9]·0.3CHCl3, contains one molecule of the triangulo-triruthenium complex and one partially occupied disordered chloroform solvent molecule. The bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru3 triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The phosphine-substituted benzene rings make dihedral angles of 67.5 (3), 76.1 (3) and 78.1 (3)° with each other. The dihedral angles between the two benzene rings are 79.0 (4) and 81.4 (3)° for the two diphenylarsino groups. In the crystal packing, the molecules are linked into chains along the a axis by intermolecular C—H...O hydrogen bonds. |
| first_indexed | 2024-12-19T16:31:15Z |
| format | Article |
| id | doaj.art-e47cb9a9b457421c97f6be607c6f2632 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:31:15Z |
| publishDate | 2010-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e47cb9a9b457421c97f6be607c6f26322022-12-21T20:14:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m178m17910.1107/S1600536809055287[μ-Bis(diphenylarsino)methane-1:2κ2As:As′][(4-bromophenyl)diphenylphosphine-3κP]nonacarbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0) chloroform 0.3-solvateOmar bin ShawkatalyImthyaz Ahmed KhanChin Sing YeapHoong-Kun FunThe asymmetric unit of the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C18H14BrP)(CO)9]·0.3CHCl3, contains one molecule of the triangulo-triruthenium complex and one partially occupied disordered chloroform solvent molecule. The bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru3 triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The phosphine-substituted benzene rings make dihedral angles of 67.5 (3), 76.1 (3) and 78.1 (3)° with each other. The dihedral angles between the two benzene rings are 79.0 (4) and 81.4 (3)° for the two diphenylarsino groups. In the crystal packing, the molecules are linked into chains along the a axis by intermolecular C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809055287 |
| spellingShingle | Omar bin Shawkataly Imthyaz Ahmed Khan Chin Sing Yeap Hoong-Kun Fun [μ-Bis(diphenylarsino)methane-1:2κ2As:As′][(4-bromophenyl)diphenylphosphine-3κP]nonacarbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0) chloroform 0.3-solvate Acta Crystallographica Section E |
| title | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′][(4-bromophenyl)diphenylphosphine-3κP]nonacarbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0) chloroform 0.3-solvate |
| title_full | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′][(4-bromophenyl)diphenylphosphine-3κP]nonacarbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0) chloroform 0.3-solvate |
| title_fullStr | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′][(4-bromophenyl)diphenylphosphine-3κP]nonacarbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0) chloroform 0.3-solvate |
| title_full_unstemmed | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′][(4-bromophenyl)diphenylphosphine-3κP]nonacarbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0) chloroform 0.3-solvate |
| title_short | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′][(4-bromophenyl)diphenylphosphine-3κP]nonacarbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0) chloroform 0.3-solvate |
| title_sort | amp 956 bis diphenylarsino methane 1 2 amp 954 2as as amp 8242 4 bromophenyl diphenylphosphine 3 amp 954 p nonacarbonyl 1 amp 954 3c 2 amp 954 3c 3 amp 954 3c triangulo triruthenium 0 chloroform 0 3 solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809055287 |
| work_keys_str_mv | AT omarbinshawkataly amp956bisdiphenylarsinomethane12amp9542asasamp82424bromophenyldiphenylphosphine3amp954pnonacarbonyl1amp9543c2amp9543c3amp9543ctriangulotriruthenium0chloroform03solvate AT imthyazahmedkhan amp956bisdiphenylarsinomethane12amp9542asasamp82424bromophenyldiphenylphosphine3amp954pnonacarbonyl1amp9543c2amp9543c3amp9543ctriangulotriruthenium0chloroform03solvate AT chinsingyeap amp956bisdiphenylarsinomethane12amp9542asasamp82424bromophenyldiphenylphosphine3amp954pnonacarbonyl1amp9543c2amp9543c3amp9543ctriangulotriruthenium0chloroform03solvate AT hoongkunfun amp956bisdiphenylarsinomethane12amp9542asasamp82424bromophenyldiphenylphosphine3amp954pnonacarbonyl1amp9543c2amp9543c3amp9543ctriangulotriruthenium0chloroform03solvate |