On the Oxygen Transport Mechanism in Titanium Thin Films under Irradiation by Molecular Water Ions

<p>The behavior of oxygen atoms in (0.5<sub> </sub>–<sub> </sub>1.0) mm thick Ti films is investigated under high-flux, low-energy molecular water ion irradiation. The anomalously deep penetration of oxygen without formation of new compounds observable by XRD has been r...

Full description

Bibliographic Details
Main Authors: Simona TUČKUTĖ, Liudas PRANEVIČIUS, Liudvikas PRANEVIČIUS, Marius URBONAVIČIUS
Format: Article
Language:English
Published: Kaunas University of Technology 2013-03-01
Series:Medžiagotyra
Subjects:
Online Access:http://matsc.ktu.lt/index.php/MatSc/article/view/3822
_version_ 1818303201156268032
author Simona TUČKUTĖ
Liudas PRANEVIČIUS
Liudvikas PRANEVIČIUS
Marius URBONAVIČIUS
author_facet Simona TUČKUTĖ
Liudas PRANEVIČIUS
Liudvikas PRANEVIČIUS
Marius URBONAVIČIUS
author_sort Simona TUČKUTĖ
collection DOAJ
description <p>The behavior of oxygen atoms in (0.5<sub> </sub>–<sub> </sub>1.0) mm thick Ti films is investigated under high-flux, low-energy molecular water ion irradiation. The anomalously deep penetration of oxygen without formation of new compounds observable by XRD has been registered after 10 min of irradiation at room temperature using Auger Electron spectroscopy analysis.</p> The mechanism driving oxygen atoms from the surface into the bulk is discussed. It is based on the results of experimental studies of surface topography and assumption that the surface energy increases under ion irradiation, and relaxation processes minimizing the surface energy initiate the atomic redistribution  on the surface and in the bulk. Two processes minimizing the surface free energy are considered: (i) the mixing of atoms on the surface, and (ii) the annihilation of surface vacancies by the atoms transported from the bulk to the surface.<p>DOI: <a href="http://dx.doi.org/10.5755/j01.ms.19.1.3822">http://dx.doi.org/10.5755/j01.ms.19.1.3822</a></p>
first_indexed 2024-12-13T05:51:02Z
format Article
id doaj.art-e48d6193c11b424d8f79813ebe522cdb
institution Directory Open Access Journal
issn 1392-1320
2029-7289
language English
last_indexed 2024-12-13T05:51:02Z
publishDate 2013-03-01
publisher Kaunas University of Technology
record_format Article
series Medžiagotyra
spelling doaj.art-e48d6193c11b424d8f79813ebe522cdb2022-12-21T23:57:32ZengKaunas University of TechnologyMedžiagotyra1392-13202029-72892013-03-01191343710.5755/j01.ms.19.1.38222056On the Oxygen Transport Mechanism in Titanium Thin Films under Irradiation by Molecular Water IonsSimona TUČKUTĖ0Liudas PRANEVIČIUS1Liudvikas PRANEVIČIUS2Marius URBONAVIČIUS3Vytautas Magnus University, Lithuanian Energy InstituteVytautas Magnus UniversityVytautas Magnus UniversityVytautas Magnus University<p>The behavior of oxygen atoms in (0.5<sub> </sub>–<sub> </sub>1.0) mm thick Ti films is investigated under high-flux, low-energy molecular water ion irradiation. The anomalously deep penetration of oxygen without formation of new compounds observable by XRD has been registered after 10 min of irradiation at room temperature using Auger Electron spectroscopy analysis.</p> The mechanism driving oxygen atoms from the surface into the bulk is discussed. It is based on the results of experimental studies of surface topography and assumption that the surface energy increases under ion irradiation, and relaxation processes minimizing the surface energy initiate the atomic redistribution  on the surface and in the bulk. Two processes minimizing the surface free energy are considered: (i) the mixing of atoms on the surface, and (ii) the annihilation of surface vacancies by the atoms transported from the bulk to the surface.<p>DOI: <a href="http://dx.doi.org/10.5755/j01.ms.19.1.3822">http://dx.doi.org/10.5755/j01.ms.19.1.3822</a></p>http://matsc.ktu.lt/index.php/MatSc/article/view/3822hydrogenwater vaporplasmaion implantation
spellingShingle Simona TUČKUTĖ
Liudas PRANEVIČIUS
Liudvikas PRANEVIČIUS
Marius URBONAVIČIUS
On the Oxygen Transport Mechanism in Titanium Thin Films under Irradiation by Molecular Water Ions
Medžiagotyra
hydrogen
water vapor
plasma
ion implantation
title On the Oxygen Transport Mechanism in Titanium Thin Films under Irradiation by Molecular Water Ions
title_full On the Oxygen Transport Mechanism in Titanium Thin Films under Irradiation by Molecular Water Ions
title_fullStr On the Oxygen Transport Mechanism in Titanium Thin Films under Irradiation by Molecular Water Ions
title_full_unstemmed On the Oxygen Transport Mechanism in Titanium Thin Films under Irradiation by Molecular Water Ions
title_short On the Oxygen Transport Mechanism in Titanium Thin Films under Irradiation by Molecular Water Ions
title_sort on the oxygen transport mechanism in titanium thin films under irradiation by molecular water ions
topic hydrogen
water vapor
plasma
ion implantation
url http://matsc.ktu.lt/index.php/MatSc/article/view/3822
work_keys_str_mv AT simonatuckute ontheoxygentransportmechanismintitaniumthinfilmsunderirradiationbymolecularwaterions
AT liudaspranevicius ontheoxygentransportmechanismintitaniumthinfilmsunderirradiationbymolecularwaterions
AT liudvikaspranevicius ontheoxygentransportmechanismintitaniumthinfilmsunderirradiationbymolecularwaterions
AT mariusurbonavicius ontheoxygentransportmechanismintitaniumthinfilmsunderirradiationbymolecularwaterions