Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate
The title compound {systematic name: bis[2-(1,3-dioxoisoindol-2-yl)ethyl]azanium chloride dihydrate}, C20H18N3O4+·Cl−·2H2O, is a phthalimide-protected polyamine that was synthesized by a previous method. It was characterized by ESI–MS, 1H NMR, and FT–IR. Crystals were grown from a solution of H2O an...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-06-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989023004565 |
| _version_ | 1797692292825350144 |
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| author | Barry S. Young Jamie L. Lee Milan Gembicky Jake Bailey Gary L. N. Smith |
| author_facet | Barry S. Young Jamie L. Lee Milan Gembicky Jake Bailey Gary L. N. Smith |
| author_sort | Barry S. Young |
| collection | DOAJ |
| description | The title compound {systematic name: bis[2-(1,3-dioxoisoindol-2-yl)ethyl]azanium chloride dihydrate}, C20H18N3O4+·Cl−·2H2O, is a phthalimide-protected polyamine that was synthesized by a previous method. It was characterized by ESI–MS, 1H NMR, and FT–IR. Crystals were grown from a solution of H2O and 0.1 M HCl. The central nitrogen atom is protonated and forms hydrogen bonds with the chloride ion and a water molecule. The two phthalimide units make a dihedral angle of 22.07 (3)°. The crystal packing features a hydrogen-bond network, two-coordinated chloride, and off-set π–π stacking. |
| first_indexed | 2024-03-12T02:26:29Z |
| format | Article |
| id | doaj.art-e4916cd7d169417a8fc8ec9e1d524fd5 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-03-12T02:26:29Z |
| publishDate | 2023-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-e4916cd7d169417a8fc8ec9e1d524fd52023-09-05T13:04:47ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902023-06-0179657557710.1107/S2056989023004565ex2070Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrateBarry S. Young0Jamie L. Lee1Milan Gembicky2Jake Bailey3Gary L. N. Smith4Department of Chemistry, San Diego Miramar College, San Diego, CA 92126, USADepartment of Chemistry, San Diego Miramar College, San Diego, CA 92126, USADepartment of Chemistry, University of California-San Diego, La Jolla, CA 92093, USADepartment of Chemistry, University of California-San Diego, La Jolla, CA 92093, USADepartment of Chemistry, San Diego Miramar College, San Diego, CA 92126, USAThe title compound {systematic name: bis[2-(1,3-dioxoisoindol-2-yl)ethyl]azanium chloride dihydrate}, C20H18N3O4+·Cl−·2H2O, is a phthalimide-protected polyamine that was synthesized by a previous method. It was characterized by ESI–MS, 1H NMR, and FT–IR. Crystals were grown from a solution of H2O and 0.1 M HCl. The central nitrogen atom is protonated and forms hydrogen bonds with the chloride ion and a water molecule. The two phthalimide units make a dihedral angle of 22.07 (3)°. The crystal packing features a hydrogen-bond network, two-coordinated chloride, and off-set π–π stacking.http://scripts.iucr.org/cgi-bin/paper?S2056989023004565crystal structurephthalimidesπ–π interactionstripodal ligand |
| spellingShingle | Barry S. Young Jamie L. Lee Milan Gembicky Jake Bailey Gary L. N. Smith Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate Acta Crystallographica Section E: Crystallographic Communications crystal structure phthalimides π–π interactions tripodal ligand |
| title | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_full | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_fullStr | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_full_unstemmed | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_short | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_sort | synthesis and crystal structure of bis 2 phthalimidoethyl ammonium chloride dihydrate |
| topic | crystal structure phthalimides π–π interactions tripodal ligand |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989023004565 |
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