LCST-UCST Transition Property of a Novel Retarding Swelling and Thermosensitive Particle Gel

Super absorbent resin particles used as profile control and water plugging agent remains a deficiency that the particles swells with high speed when absorbing water, resulting in low strength and limited depth of migration. To address this issue, we proposed a thermosensitive particle gel possessing...

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Main Authors: Liang Li, Jixiang Guo, Chuanhong Kang
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/7/2761
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author Liang Li
Jixiang Guo
Chuanhong Kang
author_facet Liang Li
Jixiang Guo
Chuanhong Kang
author_sort Liang Li
collection DOAJ
description Super absorbent resin particles used as profile control and water plugging agent remains a deficiency that the particles swells with high speed when absorbing water, resulting in low strength and limited depth of migration. To address this issue, we proposed a thermosensitive particle gel possessing the upper critical solution temperature (UCST), which was synthesized from hydrophobically modified poly(vinyl alcohol)s (PVA) with glutaraldehyde (GA) as a cross-linker. The structure of the hydrogel was characterized by Fourier transform infrared spectrophotometer (FTIR) and nuclear magnetic resonance (NMR). The thermosensitive-transparency measurement and swelling experiment show that the hydrophobic-modified PVA solutions and corresponding hydrogels exhibited thermosensitive phase transition behaviors with lower critical solution temperature (LCST) and UCST. The results indicated that the temperature-induced phase transition behavior of CHPVA hydrogels leads to their retarding swelling property and great potential as an efficient water plugging agent with excellent temperature and salt resistance.
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spelling doaj.art-e4b1a9dc8ab0434a8b329a08274249e62023-11-17T17:04:43ZengMDPI AGMaterials1996-19442023-03-01167276110.3390/ma16072761LCST-UCST Transition Property of a Novel Retarding Swelling and Thermosensitive Particle GelLiang Li0Jixiang Guo1Chuanhong Kang2Enhanced Oil Recovery Institute, China University of Petroleum, Beijing 102249, ChinaEnhanced Oil Recovery Institute, China University of Petroleum, Beijing 102249, ChinaEnhanced Oil Recovery Institute, China University of Petroleum, Beijing 102249, ChinaSuper absorbent resin particles used as profile control and water plugging agent remains a deficiency that the particles swells with high speed when absorbing water, resulting in low strength and limited depth of migration. To address this issue, we proposed a thermosensitive particle gel possessing the upper critical solution temperature (UCST), which was synthesized from hydrophobically modified poly(vinyl alcohol)s (PVA) with glutaraldehyde (GA) as a cross-linker. The structure of the hydrogel was characterized by Fourier transform infrared spectrophotometer (FTIR) and nuclear magnetic resonance (NMR). The thermosensitive-transparency measurement and swelling experiment show that the hydrophobic-modified PVA solutions and corresponding hydrogels exhibited thermosensitive phase transition behaviors with lower critical solution temperature (LCST) and UCST. The results indicated that the temperature-induced phase transition behavior of CHPVA hydrogels leads to their retarding swelling property and great potential as an efficient water plugging agent with excellent temperature and salt resistance.https://www.mdpi.com/1996-1944/16/7/2761water plugging agentretarding swellingthermosensitive particle gelthe upper critical solution temperature (UCST)hydrophobically modified poly(vinyl alcohol)
spellingShingle Liang Li
Jixiang Guo
Chuanhong Kang
LCST-UCST Transition Property of a Novel Retarding Swelling and Thermosensitive Particle Gel
Materials
water plugging agent
retarding swelling
thermosensitive particle gel
the upper critical solution temperature (UCST)
hydrophobically modified poly(vinyl alcohol)
title LCST-UCST Transition Property of a Novel Retarding Swelling and Thermosensitive Particle Gel
title_full LCST-UCST Transition Property of a Novel Retarding Swelling and Thermosensitive Particle Gel
title_fullStr LCST-UCST Transition Property of a Novel Retarding Swelling and Thermosensitive Particle Gel
title_full_unstemmed LCST-UCST Transition Property of a Novel Retarding Swelling and Thermosensitive Particle Gel
title_short LCST-UCST Transition Property of a Novel Retarding Swelling and Thermosensitive Particle Gel
title_sort lcst ucst transition property of a novel retarding swelling and thermosensitive particle gel
topic water plugging agent
retarding swelling
thermosensitive particle gel
the upper critical solution temperature (UCST)
hydrophobically modified poly(vinyl alcohol)
url https://www.mdpi.com/1996-1944/16/7/2761
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AT jixiangguo lcstucsttransitionpropertyofanovelretardingswellingandthermosensitiveparticlegel
AT chuanhongkang lcstucsttransitionpropertyofanovelretardingswellingandthermosensitiveparticlegel