Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds
Olefin metathesis using ruthenium carbene complexes is a useful method in synthetic organic chemistry. Enyne metathesis is also catalyzed by these complexes and various carbo- and heterocycles could be synthesized from the corresponding enynes. Dienyne metathesis, cross enyne metathesis and ring-ope...
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| Format: | Article |
| Language: | English |
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MDPI AG
2010-03-01
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| Series: | Materials |
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| Online Access: | http://www.mdpi.com/1996-1944/3/3/2087/ |
| _version_ | 1811281688113709056 |
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| author | Miwako Mori |
| author_facet | Miwako Mori |
| author_sort | Miwako Mori |
| collection | DOAJ |
| description | Olefin metathesis using ruthenium carbene complexes is a useful method in synthetic organic chemistry. Enyne metathesis is also catalyzed by these complexes and various carbo- and heterocycles could be synthesized from the corresponding enynes. Dienyne metathesis, cross enyne metathesis and ring-opening enyne metathesis have been further developed. Various complicated compounds, such as the natural products and the related biologically active substances, could be synthesized using these metatheses reactions. Skeletal reorganization using the transition metals and metallotropic rearrangement are also discussed. |
| first_indexed | 2024-04-13T01:38:08Z |
| format | Article |
| id | doaj.art-e4b2fb0ef09b45a8965ac28786774105 |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-04-13T01:38:08Z |
| publishDate | 2010-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-e4b2fb0ef09b45a8965ac287867741052022-12-22T03:08:17ZengMDPI AGMaterials1996-19442010-03-01332087214010.3390/ma3032087Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related CompoundsMiwako MoriOlefin metathesis using ruthenium carbene complexes is a useful method in synthetic organic chemistry. Enyne metathesis is also catalyzed by these complexes and various carbo- and heterocycles could be synthesized from the corresponding enynes. Dienyne metathesis, cross enyne metathesis and ring-opening enyne metathesis have been further developed. Various complicated compounds, such as the natural products and the related biologically active substances, could be synthesized using these metatheses reactions. Skeletal reorganization using the transition metals and metallotropic rearrangement are also discussed.http://www.mdpi.com/1996-1944/3/3/2087/enyne metathesisring-closing enyne metathesisdienyne metathesiscross metathesisring-opening metathesisnatural product |
| spellingShingle | Miwako Mori Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds Materials enyne metathesis ring-closing enyne metathesis dienyne metathesis cross metathesis ring-opening metathesis natural product |
| title | Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds |
| title_full | Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds |
| title_fullStr | Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds |
| title_full_unstemmed | Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds |
| title_short | Recent Progress on Enyne Metathesis: Its Application to Syntheses of Natural Products and Related Compounds |
| title_sort | recent progress on enyne metathesis its application to syntheses of natural products and related compounds |
| topic | enyne metathesis ring-closing enyne metathesis dienyne metathesis cross metathesis ring-opening metathesis natural product |
| url | http://www.mdpi.com/1996-1944/3/3/2087/ |
| work_keys_str_mv | AT miwakomori recentprogressonenynemetathesisitsapplicationtosynthesesofnaturalproductsandrelatedcompounds |