5,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione
Stille coupling of 5,5′-dichloro-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione (8) with 9-decyl-3-[5-(tributylstannyl)thien-2-yl]-9H-carbazole and Pd(Ph3P)2Cl2 in PhMe, at ca. 110 °C, for 2 h, gave 5,5′-bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione (7) i...
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| Format: | Article |
| Language: | English |
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MDPI AG
2018-03-01
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| Series: | Molbank |
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| Online Access: | http://www.mdpi.com/1422-8599/2018/1/M987 |
| _version_ | 1819010045483941888 |
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| author | Andreas S. Kalogirou Panayiotis A. Koutentis |
| author_facet | Andreas S. Kalogirou Panayiotis A. Koutentis |
| author_sort | Andreas S. Kalogirou |
| collection | DOAJ |
| description | Stille coupling of 5,5′-dichloro-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione (8) with 9-decyl-3-[5-(tributylstannyl)thien-2-yl]-9H-carbazole and Pd(Ph3P)2Cl2 in PhMe, at ca. 110 °C, for 2 h, gave 5,5′-bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione (7) in 51% yield. The latter is investigated as an oligomer donor for organic photovoltaics. |
| first_indexed | 2024-12-21T01:06:01Z |
| format | Article |
| id | doaj.art-e4cf56c5c825430ab4c8fe4f3c074e21 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-12-21T01:06:01Z |
| publishDate | 2018-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-e4cf56c5c825430ab4c8fe4f3c074e212022-12-21T19:21:02ZengMDPI AGMolbank1422-85992018-03-0120181M98710.3390/M987M9875,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dioneAndreas S. Kalogirou0Panayiotis A. Koutentis1Department of Pharmacy, School of Sciences, European University Cyprus, 6 Diogenis Str., Engomi, P.O. Box 22006, 1516 Nicosia, CyprusDepartment of Chemistry, University of Cyprus; P.O. Box 20537, 1678 Nicosia, CyprusStille coupling of 5,5′-dichloro-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione (8) with 9-decyl-3-[5-(tributylstannyl)thien-2-yl]-9H-carbazole and Pd(Ph3P)2Cl2 in PhMe, at ca. 110 °C, for 2 h, gave 5,5′-bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione (7) in 51% yield. The latter is investigated as an oligomer donor for organic photovoltaics.http://www.mdpi.com/1422-8599/2018/1/M987heterocycle1,2,6-thiadiazineoligomerphotovoltaics |
| spellingShingle | Andreas S. Kalogirou Panayiotis A. Koutentis 5,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione Molbank heterocycle 1,2,6-thiadiazine oligomer photovoltaics |
| title | 5,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione |
| title_full | 5,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione |
| title_fullStr | 5,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione |
| title_full_unstemmed | 5,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione |
| title_short | 5,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione |
| title_sort | 5 5 bis 5 9 decyl 9h carbazol 3 yl thien 2 yl 4h 4 h 3 3 bi 1 2 6 thiadiazine 4 4 dione |
| topic | heterocycle 1,2,6-thiadiazine oligomer photovoltaics |
| url | http://www.mdpi.com/1422-8599/2018/1/M987 |
| work_keys_str_mv | AT andreasskalogirou 55bis59decyl9hcarbazol3ylthien2yl4h4h33bi126thiadiazine44dione AT panayiotisakoutentis 55bis59decyl9hcarbazol3ylthien2yl4h4h33bi126thiadiazine44dione |