Pd-containing Mono- and Bimetallic Nanoparticles Incorporated in Highly Porous Hypercrosslinked Polystyrene as Effective Catalysts of Suzuki Cross-coupling
This paper describes synthesis of Pd-containing catalysts of Suzuki cross-coupling based on non-functionalized hyper-crosslinked polystyrene (HPS) at variation of Pd precursor nature (PdCl2, PdCl2(CH3CN)2 or PdCl2(PhCN)2). Relatively low affinity of Pd species to the chosen polymeric support was sho...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
AIDIC Servizi S.r.l.
2019-05-01
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| Series: | Chemical Engineering Transactions |
| Online Access: | https://www.cetjournal.it/index.php/cet/article/view/9851 |
| _version_ | 1819284215457382400 |
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| author | Linda Nikoshvili Elena Bakhvalova Nadezhda Nemygina Esther Sulman Lioubov Kiwi-Minsker |
| author_facet | Linda Nikoshvili Elena Bakhvalova Nadezhda Nemygina Esther Sulman Lioubov Kiwi-Minsker |
| author_sort | Linda Nikoshvili |
| collection | DOAJ |
| description | This paper describes synthesis of Pd-containing catalysts of Suzuki cross-coupling based on non-functionalized hyper-crosslinked polystyrene (HPS) at variation of Pd precursor nature (PdCl2, PdCl2(CH3CN)2 or PdCl2(PhCN)2). Relatively low affinity of Pd species to the chosen polymeric support was shown to be responsible for in situ formation of Pd nanoparticles and their aggregates. During the investigation of aryl halide nature, catalytic activity was shown to decrease in the following order: Br > I > Cl. Best results were obtained for the preliminarily reduced HPS-based sample synthesized while using PdCl2 in the reaction between phenylboronic acid and 4-bromoanisole: more than 93% yield of cross-coupling product was achieved at mild reaction conditions (NaOH, 60oC, solvent ethanol-water mixture) using 0.8 mol.% of Pd. |
| first_indexed | 2024-12-24T01:43:50Z |
| format | Article |
| id | doaj.art-e4d957b5a0aa45c398baec0c304c4490 |
| institution | Directory Open Access Journal |
| issn | 2283-9216 |
| language | English |
| last_indexed | 2024-12-24T01:43:50Z |
| publishDate | 2019-05-01 |
| publisher | AIDIC Servizi S.r.l. |
| record_format | Article |
| series | Chemical Engineering Transactions |
| spelling | doaj.art-e4d957b5a0aa45c398baec0c304c44902022-12-21T17:21:55ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162019-05-017410.3303/CET1974086Pd-containing Mono- and Bimetallic Nanoparticles Incorporated in Highly Porous Hypercrosslinked Polystyrene as Effective Catalysts of Suzuki Cross-couplingLinda NikoshviliElena BakhvalovaNadezhda NemyginaEsther SulmanLioubov Kiwi-MinskerThis paper describes synthesis of Pd-containing catalysts of Suzuki cross-coupling based on non-functionalized hyper-crosslinked polystyrene (HPS) at variation of Pd precursor nature (PdCl2, PdCl2(CH3CN)2 or PdCl2(PhCN)2). Relatively low affinity of Pd species to the chosen polymeric support was shown to be responsible for in situ formation of Pd nanoparticles and their aggregates. During the investigation of aryl halide nature, catalytic activity was shown to decrease in the following order: Br > I > Cl. Best results were obtained for the preliminarily reduced HPS-based sample synthesized while using PdCl2 in the reaction between phenylboronic acid and 4-bromoanisole: more than 93% yield of cross-coupling product was achieved at mild reaction conditions (NaOH, 60oC, solvent ethanol-water mixture) using 0.8 mol.% of Pd.https://www.cetjournal.it/index.php/cet/article/view/9851 |
| spellingShingle | Linda Nikoshvili Elena Bakhvalova Nadezhda Nemygina Esther Sulman Lioubov Kiwi-Minsker Pd-containing Mono- and Bimetallic Nanoparticles Incorporated in Highly Porous Hypercrosslinked Polystyrene as Effective Catalysts of Suzuki Cross-coupling Chemical Engineering Transactions |
| title | Pd-containing Mono- and Bimetallic Nanoparticles Incorporated in Highly Porous Hypercrosslinked Polystyrene as Effective Catalysts of Suzuki Cross-coupling |
| title_full | Pd-containing Mono- and Bimetallic Nanoparticles Incorporated in Highly Porous Hypercrosslinked Polystyrene as Effective Catalysts of Suzuki Cross-coupling |
| title_fullStr | Pd-containing Mono- and Bimetallic Nanoparticles Incorporated in Highly Porous Hypercrosslinked Polystyrene as Effective Catalysts of Suzuki Cross-coupling |
| title_full_unstemmed | Pd-containing Mono- and Bimetallic Nanoparticles Incorporated in Highly Porous Hypercrosslinked Polystyrene as Effective Catalysts of Suzuki Cross-coupling |
| title_short | Pd-containing Mono- and Bimetallic Nanoparticles Incorporated in Highly Porous Hypercrosslinked Polystyrene as Effective Catalysts of Suzuki Cross-coupling |
| title_sort | pd containing mono and bimetallic nanoparticles incorporated in highly porous hypercrosslinked polystyrene as effective catalysts of suzuki cross coupling |
| url | https://www.cetjournal.it/index.php/cet/article/view/9851 |
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